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129I-Mössbauer spectroscopic study of iodide-containing chalcogenide glasses

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Abstract

129I-Mössbauer spectroscopy was used to study the short-range order in I-containing chalcogenide glasses. It was found that AsXI glasses, where X=S or Se, are molecular solids composed from molecular units of arsenic iodide and arsenic chalcogenide. The local environment of iodide ions in ternary superionic conducting glasses AgI−Ag2S−As2S3 is similar to that in the crystalline superionic conductor Ag3SI and differs distinctly from iodide local order in binary vitreous alloys AgI−As2S3 and crystalline AgI.129I-Mössbauer spectra of all glasses were fitted satisfactory, when a distribution of the electric-quadrupole coupling constant is taken into account.

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References

  1. W.J. Bresser, P. Boolchand, P. Suranyi and J.P. de Neufville. Phys. Rev. Lett. 46 (1981) 1689.

    Article  ADS  Google Scholar 

  2. P. Boolchand, W.J. Bresser and P. Suranyi, Hyp. Int. 27 (1986) 385.

    Article  Google Scholar 

  3. Yu.S. Grushko, L.I. Molkanov, K.Ya. Mishin and G.A. Grigor’eva, Zh. Eksp. Teor. Fiz. 90 (1986) 437.

    Google Scholar 

  4. G. Wortmann, M. Tiedtke, E. Bychkov and Yu. Grushko, this conference.

  5. C. Wivel and S. Morup, J. Phys. E 14 (1981) 605.

    Article  ADS  Google Scholar 

  6. G. Le Caer and J.M. Dubois, J. Phys. E 12 (1979) 1083.

    Article  ADS  Google Scholar 

  7. E.A. Bychkov, Yu.G. Vlasov, V.A. Dravin and V.G. Semenov, Fizika Tverdogo Tela 29 (1987) 3241.

    Google Scholar 

  8. K. Wuyts, G. Langouche and R.E. Silverans, this conference.

  9. H. Sakai, J. Sci. Hiroshima Univ. A 36 (1972) 47.

    Google Scholar 

  10. L. Koudelka and M. Pisarcik, J. Non-Cryst. Solids 64 (1984) 87.

    Article  Google Scholar 

  11. P. Fornasini, G. Dalba, F. Rocca, E. Bernieri and E. Burattini, in:EXAFS and Near Edge Structure III, eds. K.O. Hodgson, B. Hedman and J.E. Penner-Hahn (Springer Verlag. 19840, p. 314.

  12. G. Licheri, A. Musinu, G. Pashina, G. Piccaluga, G. Pinna and A. Magistris, J. Chem. Phys. 85 (1986) 500.

    Article  ADS  Google Scholar 

Download references

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Author notes

  1. G. Wortmann

    Present address: Fachbereich Physik, Universität Paderborn, D-4790, Paderborn, Germany

Authors and Affiliations

  1. Department of Chemistry, Leningrad University, 199034, Leningrad, USSR

    E. A. Bychkov & Yu. G. Vlasov

  2. Leningrad Institute of Nuclear Physics, Leningrad, Gatchina, USSR

    Yu. V. Ganzha, Yu. S. Grushko, M. F. Kovalev & L. I. Molkanov

  3. Fachbereich Physik, Freie Universität Berlin, D-1000, Berlin 33, Germany

    G. Wortmann

Authors
  1. E. A. Bychkov
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  2. Yu. V. Ganzha
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  3. Yu. S. Grushko
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  4. M. F. Kovalev
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  5. L. I. Molkanov
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  6. Yu. G. Vlasov
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  7. G. Wortmann
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Bychkov, E.A., Ganzha, Y.V., Grushko, Y.S. et al. 129I-Mössbauer spectroscopic study of iodide-containing chalcogenide glasses. Hyperfine Interact 55, 921–925 (1990). https://doi.org/10.1007/BF02397100

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  • DOI: https://doi.org/10.1007/BF02397100

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