Abstract
Fuji Photo Film Co. recently announced the development of lithium batteries employing oxide negative electrodes. Under near-equilibrium conditions these oxides are converted to lithium alloys during the first charging cycle. Thereafter, the properties should be essentially those of the resulting binary lithium alloys.
The basic principles involved in the use of alloys as negative electrodes, as well as the conversion of oxides to alloys, are presented. Available data on the behavior of a number of lithium alloys and binary oxides as negative electrodes in lithium systems are also included. The lithiumtin system is discussed in some detail as it is a particularly relevant example.
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12. References
Fujifilm, Internet: http://www.fujifilm.co.jp/eng/news_e/nr079.html, (1996).
N.P. Yao, L.A. Heredy and R.C. Saunders, J. Electrochem. Soc.118, 1039 (1971).
E.C. Gay, et al., J. Electrochem. Soc.123, 1591 (1976).
S.C. Lai, J. Electrochem. Soc.123, 1196 (1976).
R.A. Sharma and R.N. Seefurth, J. Electrochem Soc.123, 1763 (1976).
R.N. Seefurth and R.A. Sharma, J. Electrochem. Soc.124, 1207 (1977).
H. Ogawa, inProceedings of 2nd International Meeting on Lithium Batteries, Elsevier Sequoia (1984), p. 259.
R. Yazami and P. Touzain, J. Power Sources9, 365 (1983).
I.A. Courtney and J.R. Dahn, submitted for publication in J. Electrochem. Soc., (1997).
W. Weppner and R.A. Huggins, inProc. of the Symposium on Electrode Materials and Processes for Energy Conversion and Storage, J.D.E. McIntyre, S. Srinivasan and F.G. Will, Eds., Electrochem. Society (1977), p. 833.
W. Weppner and R.A. Huggins, Z. Phys. Chem. N.F.108, 105 (1977).
W. Weppner and R.A. Huggins, J. Electrochem. Soc.125, 7 (1978).
C.M. Luedecke, J.P. Doench and R.A. Huggins, inProc. of Symp. on High Temperature Materials Chemistry, Z. A. Munir and D. Cubicciotti, Eds., Electrochem. Soc. (1983), p. 105.
J.P. Doench and R.A. Huggins, inProc. of Symp. on High Temperature Materials Chemistry, Z.A. Munir and D. Cubicciotti, Eds., Electrochem. Soc. (1983), p. 115.
A. Anani and R.A. Huggins, inProc. of Symp. on Primary and Secondary Ambient Temperature Lithium Batteries, J-P. Gabano, Z. Takehara and P. Bro, Eds., Electrochem. Soc. (1988), p. 635.
A. Anani and R.A. Huggins, J. Power Sources38, 351 (1992).
R.A. Huggins, inFast Ion Transport in Solids, P. Vashishta, J.N. Mundy and G.K. Shenoy, Eds., North-Holland (1979), p. 53.
C.J. Wen, Ph.D. Dissertation, Stanford University, (1980).
I.D. Raistrick and R.A. Huggins, Mat. Res. Bull.18, 337 (1983).
I.D. Raistrick, A.J. Mark and R.A. Huggins, Solid State Ionics5, 351 (1981).
W. Weppner and R.A. Huggins, J. Electrochem. Soc.124, 1569 (1977).
W. Weppner and R.A. Huggins, inAnnual Review of Materials Science, R. A. Huggins, Ed., Annual Reviews, Inc. (1978), p. 269.
C.J. Wen et al., International Metals Reviews5, 253 (1981).
C.J. Wen et al., J. Electrochem. Soc.126, 2258 (1979).
C.J. Wen et al., Met. Trans. B11B, 131 (1980).
C.J. Wen and R.A. Huggins, J. Solid State Chem.37, 271 (1981).
C.J. Wen and R.A. Huggins, J. Electrochem. Soc.128, 1181 (1981).
C. J. Wen and R.A. Huggins, J. Solid State Chem.35, 376 (1980).
J.P. Doench and R.A. Huggins, J. Electrochem. Soc.129, 341 (1982).
J. Wang, I.D. Raistrick and R.A. Huggins, J. Electrochem. Soc.133, 457 (1986).
J. Wang, P. King and R.A. Huggins, Solid State Ionics20, 185 (1986).
A. Anani, S. Crouch-Baker and R.A. Huggins, inProc. Symp. on Lithium Batteries, ed. by A.N. Dey, Electrochem. Soc. (1987), p. 365
B.A. Boukamp, G.C. Lesh and R.A. Huggins, J. Electrochem. Soc.128, 725 (1981).
B.A. Boukamp, G.C. Lesh and R.A. Huggins, inProc. Symp. on Lithium Batteries, H. V. Venkatasetty, Ed., Electrochem. Soc. (1981), p. 467.
R.A. Huggins and B.A. Boukamp, U.S. Patent 4,436,796 (1984).
A. Anani, S. Crouch-Baker and R.A. Huggins, inProc. of Symp. on Lithium Batteries, A. N. Dey, Ed., Electrochem. Soc. (1987), p. 382.
A. Anani, S. Crouch-Baker and R.A. Huggins, J. Electrochem. Soc.135, 2103 (1988).
C. J. Wen and R.A. Huggins, Mat. Res. Bull.15, 1225 (1980).
M.L. Saboungi, et al., J. Electrochem. Soc.126, 322 (1979).
C.J. Wen and R.A. Huggins, J. Electrochem. Soc.128, 1636 (1981).
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Huggins, R.A. Alloy negative electrodes for lithium batteries formed in-situ from oxides. Ionics 3, 245–255 (1997). https://doi.org/10.1007/BF02375624
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DOI: https://doi.org/10.1007/BF02375624