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Some analytical aspects of the chromatographic headspace concentration method using a porous polymer

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Summary

Compounds of different chemical type can be concentrated on a precolumn containing thermostable 2,6-diphenyl-p-phenylene oxide porous polymer and transferred to a gas chromatographic column. The representation of trapped organics in a high-resolution chromatogram can be explained primarily on the basis of frontal chromatography, displacement, and irreversible-adsorption phenomena. The effect of sampling variables is demonstrated with complex chromatograms of sage leaf headspace.

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Author notes

  1. K. D. Bartle

    Present address: Department of Physical Chemistry, University of Leeds, Leeds, England

Authors and Affiliations

  1. Department of Chemistry, Indiana University, 47401, Bloomington, Indiana, U.S.A.

    M. Novotny, M. L. Lee & K. D. Bartle

Authors
  1. M. Novotny
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  2. M. L. Lee
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  3. K. D. Bartle
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Novotny, M., Lee, M.L. & Bartle, K.D. Some analytical aspects of the chromatographic headspace concentration method using a porous polymer. Chromatographia 7, 333–338 (1974). https://doi.org/10.1007/BF02269346

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  • DOI: https://doi.org/10.1007/BF02269346

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