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Tetrahydrothiophene as intermediate in the hydrodesulfurization of thiophene

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Abstract

The amounts of tetrahydrothiophene and octane have been determined in the hydrodesulfurization product of thiophene on molybdenum catalysts under various conditions. The results are interpreted as evidence for a consecutive reaction mechanism consisting of ring hydrogenation followed by decomposition of the saturated sulfur compound.

Abstract

Было определено количество тетрагидротиофена и октана в продуктах гидродесуль-фирования тиофена на молибденовых катализаторах при различных условиях. Результаты интерпретируются как доказательство механизма последовательных реакций гидрирования кольца с последующим разложением насыщенного серного соединения.

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Authors and Affiliations

  1. Institute of Chemical Process Fundamentals, Czechoslovak Academy of Sciences, 165 02, Praha 6, Suchdol

    J. Kraus & M. Zdražil

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  1. J. Kraus
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  2. M. Zdražil
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Kraus, J., Zdražil, M. Tetrahydrothiophene as intermediate in the hydrodesulfurization of thiophene. React Kinet Catal Lett 6, 475–480 (1977). https://doi.org/10.1007/BF02078731

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  • DOI: https://doi.org/10.1007/BF02078731

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