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Anchored palladium-tin complexes as telomerization catalysts

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Abstract

The telomerization of butadiene with diethylamine in the presence of palladium-tin complexes obtained through interaction between palladium π-allyl compounds and tin acetate has been studied. Palladium-tin complexes are characterized by high activity and low solubility in the diethylamine-butadiene mixture. Very active supported telomerization catalysts with high palladium concentrations are obtained by means of anchoring palladium-tin complexes to an SiO2 surface.

Abstract

Исследована теломеризация бутадиена с диэтиламином под влиянием палладийоловянных коиплексов, полученных при взаимодействии π-аллильных соединений палладия и ацетата олова. Палладийоловянные комплексы характеризуются значительной активностью, но плохо растворимы в смеси диэтиламин-бытадиен. Закреплением таких комплексов на поверхности SiO2 получены высокоактивные нанесенные катализаторы теломеризации с высоким содержанием палладия.

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Authors and Affiliations

  1. Institute of Catalysis, Novosibirsk, USSR

    A. M. Lazutkin, A. I. Lazutkina & Yu. I. Yermakov

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  1. A. M. Lazutkin
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  2. A. I. Lazutkina
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  3. Yu. I. Yermakov
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Lazutkin, A.M., Lazutkina, A.I. & Yermakov, Y.I. Anchored palladium-tin complexes as telomerization catalysts. React Kinet Catal Lett 8, 353–357 (1978). https://doi.org/10.1007/BF02068178

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  • DOI: https://doi.org/10.1007/BF02068178

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