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Effect of the state of vanadium cations on the IR spectra of adsorbed carbon monoxide

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Abstract

ESR and IR-spectrosocpic studies of the effect of the state of vanadium ions on the IR-spectra of adsorbed CO have revealed complex formation of CO with V4+ (vCO at 2192 and 2205 cm−1) and V3+ (vCO at 2178 and 2185 cm−1) ions.

Abstract

Методами ЭПР и-ИК-спектроскопии изучеио влияние состояния ионов ванадия на ИК-спектры адсорбированной CO. Обнаружено комплексообразование CO с ионами V4+ (vCO 2192, 2205 cm−1) и V3+ (vCO 2178, 2185 cm−1).

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Davydov, A.A., Budneva, A.A. & Maksimov, N.G. Effect of the state of vanadium cations on the IR spectra of adsorbed carbon monoxide. React Kinet Catal Lett 20, 93–98 (1982). https://doi.org/10.1007/BF02063591

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  • DOI: https://doi.org/10.1007/BF02063591

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