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Interaction of nitric acid and tetravalent actinides with uranium in TBP-phase

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Abstract

Infrared absorption spectra of HNO3 solutions in UO2(NO3)2(TBP)2 have been taken. The formation of a hydrogen bond between HNO3 and nitrate or phosphoryl group in UO2(NO3)2(TBP)2 has been established. On extracting Pu(IV) and Np(IV) by 30% TBP-dodecane, dependence of the distribution coefficients on concentration has been found at UO2(NO3)2 concentrations in the aqueous phase upwards from 0.4M. This dependence appeared in the temperature interval 0–60°C. Such effects may be caused by ordered structure of saturated uranyl nitrate solutions in TBP.

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References

  1. Yu. S. FEDOROV, B. Ya. ZILBERMAN, Radiokhimiya, 28 (1986) 36.

    Google Scholar 

  2. Yu. S. FEDOROV, B. Ya. ZILBERMAN, Radiokhimiya, 30 (1988) 572.

    Google Scholar 

  3. B. Ya. ZILBERMAN, Yu. S. FEDOROV, Proc. Intern. Solvent Extraction Conference (ISEC '88) Vol. 1, Moscow, 1988, p. 206.

    Google Scholar 

  4. A. S. SOLOVKIN, N. S. POVITSKY, K. P. LUNICHKINA, Zh. Neorg. Khim., 5 (1960) 2115.

    Google Scholar 

  5. T. A. DIK, N. N. KOSTYUK, M. V. NIKANOVICH, Zh. Prik. Spektr. 47 (1987) 436.

    Google Scholar 

  6. V. M. VDOVENKO, T. A. DEMYANOVA, M. T. KUZINA et al., Radiokhimiya 6 (1964) 49.

    Google Scholar 

  7. C. K. INGOLD, D. J. MILLEN, H. G. POOLE, J. Chem. Soc. oct. (1950) 2576.

  8. E. N. MOISEENKO, A. M. ROZEN, Radiokhimiya, 2 (1960) 274.

    Google Scholar 

  9. V. E. VERESHCHAGIN, E. V. RENARD, Atomn. Energ., 44 (1978) 422.

    Google Scholar 

  10. L. PETPIC, Z. KOLARIK, Report KfK-3080, 1981.

  11. A. M. ROZEN, M. Ya. ZELVENSKY, Radiokhimiya, 18 (1976) 572.

    Google Scholar 

  12. J. MIHALCZYK, J. HURWIC, Nukleonika, 6 (1961) 503.

    Google Scholar 

  13. J. HURWIC, S. JARZYNSKA, J. MICHALCZYK, Nukleonika, 9 (1964) 484.

    Google Scholar 

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Authors and Affiliations

  1. Khlopin Radium Institute, 197022, Leningrad, USSR

    B. Ya. Zilberman & Yu. S. Fedorov

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  1. B. Ya. Zilberman
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  2. Yu. S. Fedorov
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Zilberman, B.Y., Fedorov, Y.S. Interaction of nitric acid and tetravalent actinides with uranium in TBP-phase. Journal of Radioanalytical and Nuclear Chemistry, Articles 143, 373–379 (1990). https://doi.org/10.1007/BF02039605

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  • DOI: https://doi.org/10.1007/BF02039605

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