Abstract
A comprehensive literature survey on the radiation stability of ion exchangers resulted in the publication of an extensive data compilation on the effects of ionizing radiation on synthetic organic ion exchangers in this journal (Vol. 97, No. 1). This paper is a brief review of the majorfindings of this literature survey along with similar information on synthetic inorganic ion exchangers. The primary goal of this literature survey is to review present knowledge on the effects of ionizing radiations on synthetic ion exchange materials used in radiochemical processing. Although there are gaps in our knowledge of the mechanisms of radiolytic changes in ion exchangers, the information available in the literature shows some general trends and similarities in observed qualitative effects by different types of organic and inorganic ion exchange materials. These trends and observations have been formulated into a set of qualitative and semi-quantitative statements that can be useful to potential users of ion exchange materials in nuclear material processing and radioactive waste management. Present knowledge, of the behavior of ion exchangers under the influence of ionizing radiations is too limited to justify quantitative predictive modeling.
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H. S. THOMPSON, Royal Agr. Soc. Journal, 11 (1850) 68.
J. T. WAY, Royal agr. Soc. J., 11 (1850) 313; 13 (1852) 123.
B. A. ADAMS, E. L. HOLMES, British Patent No. 450, 308/9, 1934.
R. M. MILTON, U. S. Patent No. 2,882,244, 1959.
K. K. S. PILLAY, J. Radional. Nucl. Chem., 97 (1986) 135.
I. A. E. A. Technical Report Series No. 78, Operation and Control of Ion Exchange Processes for Treatment of Radioactive Wastes, International Atomic Energy Agency, Vienna, 1967.
J. BARGHUSEN, A.A. JONKE, Reactor Fuel Process, 7 (1964) No. 4, 297.
J. BARGHUSEN, A. A. JONKE, Reactor Fuel Process, 7 (1964) No. 4, 303.
J. BARGHUSEN, A. A. JONKE, Reactor Fuel Process, 8 (1965) No. 2, 135.
J. BARGHUSEN, A. A. JONKE, Reactor Fuel Process, 8 (1965) No. 1, 65.
P., TICHLER, L. BAKER, R. ISLER, and D. MATZ, Investigating Committee Report on the Nitrate Resin Bed Accident at the Brookhaven High Flux Beam Reactor, Brookhaven National Laboratory, Upton, New York, BNL-12460, 1965.
W. J. VAN SLYKE, G. JANSEN, JR., and W. H. SWIFT, Thermal Effects in Anion Exchange Resin-Nitric Acid Systems, Battelle Pacific Northwest Laboratories, Richland, Washington, BNWL-114, August 1965.
Nitrated Anion Exchange Bed Reacts Violently with Nitric Acid, Serious Accidents, Issue No. 266, US Atomic Energy Commission, June 3, 1966.
J. BARGHUSEN, A. A. JONKE, Reactor Fuel Process, 9 (1966) No. 2, 132.
W. J. VAN SLYKE, Final Report of Chemical Safety for Technicium-99 Recovery by Anion Exchange, Battelle Pacific Northwest Laboratories, Richland, Washington, BNWL-476, January 1967.
F. W. MILES, Nuclear Safety, 9 (5) (1968) 394.
R. W. POWELL, Nuclear Safety, 10 (1969) 84 (Letter to the Editor).
H. T. FULLAM, G. JANSEN, JUN, W. J. VAN SLYKE, Thermochemical Instabilities in Anion-Exchange Processing, Proceedings of the 1969 Ion Exchange Industries Conference of the Society of Chemical Industries, London, 1969, p. 71.
Investigation of the Chemical Explosion of an Ion Exchange Resin Column and Resulting Americium Contamination of Personnel in the 242-Z Building, Aug. 30, 1976, ERDA, Richland Operations Office, Oct. 1976.
E. V. EGOROV, P. D. NOVIKOV, Action of Ionizing Radiation on Ion-Exchange Materials, Atomizdat, Moscow, 1965, Israel Program for Scientific Translations, Jerusalem, 1967.
T. E. GANGWER, M. GOLDSTEIN, K. K. S. PILLAY, Radiation Effects on Ion-Exchange Materials, Brookhaven National Laboratory, Upton, New York, BNL-50781, 1977.
K. K. S. PILLAY, Radiation Efects on Ion Exchangers Used in Radioactive Waste Management, The Pennsylvania State University, University, Park, Pennsylvania, NE/RWM-80-3, 1980.
D. R. KALKARF, Safety Evaluation of Cation, Exchange Resins, Battelle Pacific Northwest Laboratories, Richland, Washington, BNWL No. 2391, August 1977.
G. P. SIMON, Stability of Ion Exchangers in Ionizing Radiation in Ion Exchange in Pollution Control, Vol. 1, C. CALMON, H. GOLD (Eds), C. R. C. Press, Boca Raton, Florida, 1979, Chap. 5, p. 55.
IUPAC, Pure Appl. Chem. 29 (1972) 619.
R. E. WEDEMEYER, The Stability of Ion Exchange Resins to X-Rays, Ph. D. thesis submitted to faculty of graduate school of Vanderbilt University, Nashville, Tennessee, September 1953.
G. I. CATHERS, Radiation Damage to Radioachemical Processing Reagents, Progress in Nuclear Energy, Seris III, Process Chemistry, Vol 1, Pergmon, Press, New York, 1956, p. 68.
K. M. SEMUSHIN, I. P. GALITSKAYA, I. A. KUZIN, Translation from Zh. Prikl. Khim. 44 (1971) No. 9. 2035.
E. D. KISELEVA, K. V. CHMUTOV, M. M. KLIENTOVSKAYA, V. P. LI, Russian J. Phys. Chem. [English Translation], 41 (1967) No. 7, 850.
T. ICHIKAWA, Z. HAGIWARA, J. Nucl. Sci. Tech., 10 (1973) 746.
P. E. TULUPOV, A. M. BUTAEV, V. P. GREBEN, and A. I., KASPEROVICH, Russian J. Phys. Chem. [English Translation], 47 (1973) No. 4, 551.
W. C. YEE, W. DAVIS, JR., Nucl. Sci. Eng., 24 (1966) 1.
A. NAREBSKA, B. MAZURKIEWICZ, Nukleonika, 17 (1972) Nos. 3–4, 169 (in Polish)
L. L. SMITH, H. J. GROH, The Effect of Gamma Radiation on Ion Exchange Resins, U. S. AEC, Savannah River, Laboratory, Aiken, South Carolina, DP-549, 1961.
A. R. KAZANJIAN, D. R. HORRELL, Radiation Effects on Ion-Exchange Resins—I. Gamma Irradiation of Dowex 50W, U. S. AEC, Rocky Flats Division, Golden, Colorado, RFP-2140, 1974.
R. H. WILEY, G. DAVENUTO, J. Appl. Polym. Sci., 9 (1965) 2001.
J. PAYNE, Investigation of the Mechanism of the X-Ray Degradation, of Dowex-50 Ion-Exchange Resin, M. A. Thesis submitted to the faculty of the graduate school of Vanderbilt University, Nashville, Tennessee, March 1956.
J. W. UTLEY, The Chemical Effects of Low Energy X-Radiation on Ion-Exchange Resins, Part I of PhD thesis submitted to the faculty of the graduate school of Vanderbilt University, Nashville, Tennessee, June 1959.
G. H. FISHER, W. D. THREADGILL, Terminal Report on an Applied Research Program on Radiation Stability and Inorganic Radiochemistry, US Atomic Energy Agency, TID-21385, September 1964.
R. H. WILEY, R. M. DYER, J. Polymer Sci., Part A, 2 (1964) 3153.
R. H. WILEY, T. K. VENKATACHALAM, J. Polymer Sci., Part A, 3 (1965) 1063.
E. D. KISELEVA, K. V. CHMUTOV, V. N. KRUPNOVA, Russ. J. Phys. Chem. (English Translation) 35 (1961), No. 8. 892.
E. D. KISELEVA, K. V. CHMUTOV, V. N. KRUPNOVA, Russ. J. Phys. Chem., (English Translation) 35 (1961), No. 8, 895.
A. R. KAZANJIAN, D. R. HORRELL, Radiation Effects on Ion-Exchange Resins—III. Alpha Irradiation of Dowex 50W, U. S. AEC, Rocky Flats Divison, Golden, Colorado, RFP-2298, 1975.
G. MOHORCIC, V. KRAMER, J. Polymer, Sci. Part C, (1968) No. 16, 4185.
G. MOHORCIC, V. KRAMER, M. PREGELJ, Intern. J. Appl. Radiation Isotopes, 25 (1974) 177.
K. J. SWYLER, C. E. DODGE, R. DAYAL, Irradiation Effects on the Storage and Disposal of Radioactive Ion Exchange Media, Brookhaven National Laboratory, Upton, New York, NUREG/CR-3383, BNL-NUREG-51691, 1983.
V. DORNOW, S. SECHT, W. WEINLANDER, H. J. BORN, J. Radianal. Chem., 24 (1975) 393.
S. SPECHT, V. DORNOW, W. WEINLANDER, J. BORN, J. Radioanal. 26 (1975) 17 (in German).
A. R. KAZANJIAN, D. R. HORRELL, Radiation Effects on Ion-Exchange Resins—II. Gamma Irradiation of Dowex 1, U. S. AEC, Rocky Flats Division, Golden, Colorado, RFP-2354, 1975.
K. J. SWYLER, C. J. DODGE, R. DAYAL, Assessment of Irradiation Effects of Radwaste Containing Ion Exchange Media, Brookhaven National Laboratory, Upton, New York, NUREG/CR-3812, BNL-NUREG-51774, 1984.
M. PESEK, Z. SPURNEY, Jad. Energ. 8 (1968) No. 14, 313.
I. R. HIGGINS, Radiation Damage to Organic Ion Exchange Materials, US Atomic Energy Commission, ORNL-1325, February 1953.
M. A. ASKAROV, A. T. DZHALILOV, R. A. NAZIROVA, G. S. TSVESHKO, Zh. Prikl. Khim. 46 (1973) No. 9 2115 (in Russian).
T. SHIGEMATSU, T. OSHIO, Bull. Inst. Chem. Research, Kyoto University, Japan, 37 (1959) 349.
S. A. FISHER, Effect of Gamma Radiation on Ion Exchange Resins, U. S. AEC, RMO-2528, 1954.
E. D. KISELEVA, K. V. CHMUTOV, M. M. KLIENTOVSKAYA, Russian J. Phys. Chem. (English Translation), 42 (1968) No. 11, 1518.
P. E. TULUPOV, A. I. KASPEROVICH, Russian J. Phys. Chem. (English Translation), 42 (1968) No. 8, 1040.
E. D. KISELEVA, K. V. CHMUTOV, M. M. KLIENTOVSKAYA, Russ. J. Phys. Chem. (English Translation), 39 (1965), No. 3, 406.
E. D. KISELEVA, K. V. CHMUTOV, V. N. KRUPNOVA, Russ. J. Phys. Chem., (English Translation) 36 (1962), No. 11. 1331.
N. V. KULIGINA, E. D. KISELEVA, K. V. CHMUTOV, Russ. J. Phys. Chem., (English Translation) 50 (1976), No. 1. 87.
E. D. KISELEVA, K. V. CHMUTOV, N. V. KULIGINA, Russian J. Phys. Chem. (English Translation), 44 (1970) No. 2, 264.
O. R. SKOROKHOD and I. B. STANKEVICH, Russian J. Phys. Chem. (English Translation), 42 (1968), No. 2, 271.
S. V. TAVAKOVA, E. D. KISELEVA, K. V. CHMUTOV, Russ. J. Phys. Chem. (English Translation), 49 (1975), No. 2, 279.
N. V. KULIGINA, E. D. KISELEVA, K. V. CHMUTOV, Russ. J. Phys. Chem., 50 (1976), No. 1, 85.
R. S. SHETIYA, V. K. P. UNNY, D. G. VARTAK, Indian J. Chem., 16A (1978) 24.
E. W. BAUMAN, Radiolysis of Ion Exchange Resins Used in the Purification System of Savannah River Reactors, U. S. AEC, Savannah River Laboratory, Aiken, South Carolina, DP-977, July 1965.
A. BASINSKI, A. NAREBSKA, M. TEMPCZYK, Nukleonika (English Translation), 14 (1969) No. 5, 77.
A. NAREBSKA, A. BASINSKI, M. LITOWSKA, Nukleonika (English Translation), 15 (1970) No. 2, 30.
M. LITOWSKA, A. BASINSKI Nukleonika (English Translation), 18 (1973) No. 5, 1.
M. LITOWSKA, A. NAREBSKA, J. OSTOWSKA, Nukleonika (English Translation), 19 (1974) No. 1, 19.
G. R. HALL, M. STREAT J. Chem. Soc. B (1963) 5205.
M. T. AHMED, P. G. CLAY, G. R. HALL, J. Chem. Soc. B (1966) 1155.
E. D. KISELEVA, K. V. CHMUTOV, V. M. KHASANOVA, Z. A. MARKOVA, Russian J. Phys. Chem. (English Translation), 45 (1971) No. 4, 499.
E. D. KISELEVA, V. M. KHASANOVA, K. V. CHMUTOV, Russian J. Phys. Chem. (English Translation), 45 (1971) No. 5, 667.
V. M. KHASANOVA, E. D. KISELEVA, K. V. CHMUTOV, Russian J. Phys. Chem. (English Translation), 45 (1971) No. 5, 725.
E. D. KISELEVA, K. V. CHMUTOV, N. V. KULIGINA, Russian J. Phys. Chem. (English Translation), 44 (1970), No. 2, 261.
E. D. KISELEVA, K. V. CHMUTOV, N. V. FILATORA, Russian J. Phys. Chem. (English Translation), 36 (1962), No. 11, 1335.
E. D. KISELEVA, S. V. TABAKOVA, K. V. CHMUTOV, Russian J. Phys. Chem. (English Translation), 50 (1976), No. 9, 149.
E. D. KISELEVA, S. V. TABAKOVA, K. V. CHMUTOV, Russian J. Phys. Chem. (English Translation), 50 (1976), No. 9, 1421.
A. R. KAZANJIAN, J. R. STEVENS, Radiation Effects onn MSC-1, Amberlite 252, and Duolite C-264 Ion Exchange Resins, Rockwell International Energy Systems Group, Rocky Flats, Colorado, RFP-3541, 1983.
A. R. KAZANJIAN, M. E. KILLION, Radiation Effects on Amberlite IRA-938 and Bio-Rad AG-MP-50 Ion Exchange Resins, Rockwell International Energy Systems Group, Rocky, Flats, Colorado, RFP-3167, 1982.
I. N. GRIBANOVA, I. D. KHOL'KINA, Yu. N. POLIVINKIN, A. V. NIKOLAEV, Russian J. Phys. Chem. [English Translation], 44 (1970) No. 7, 983.
R. C. McFARLAND, Analysis of Irradiated Ion Exchange Materials, Final Research Report on Project A60-611, Georgia Institute of Technology, 1981.
C. B. AMPHLETT, Inorganic Ion Exchangers, Elsevier Publishing Co., New York, New York, 1964.
V. VESELEY, V. PEKAREK, Talanta, 19 (1972) 219.
V. PEKAREK, V. VESELY, Talanta, 19 (1972) 1245.
B. P. ROBINSON, Ion Exchange Minerals and Disposal of Radioactive Wastes—A Survey of Literure, Geoligcal Survey Water—Supply Paper 1616, US Government Printing Office, Washington, DC, 1962.
R. L. HEMMINGS, New Materials for Ion Exchange—A literature Survey to 1965, Whiteshell Nuclear Research Establishment Report, AECL-2546, March 1966.
I. A. E. A. Technical Document. 337, “Inorganic Ion Exchangers and Absorbers for Chemical Processing in Nuclear Fuel Cycle,” International Atomic Energy Agency, Vienna, 1985.
I. A. E. A. Technical Report, Series No. 136, Use of Local Minerals in the Treatment of Radioactive Waste, International Atomic Energy Agency, Vienna, 1972.
L. L. AMES, Jr., Cation Exchange Properties of Heulandite—Clinoptilolite Series Members in BNWL-481, Part 3, Eds. D. W. Pearce and M. R. Compton, Pacific Northwest Laboratory, Richland, Washington, 1968.
J. W. RODDY, A Survey: Utilization of Zeolites for the Removal of Radioactivity from Liquid Waste Steams, Oak Ridge National Laboratory Report, ORNL/TM-7782 August 1981.
L. P. HATCH, Ultimate Disposal of Radioactive Wastes, US Atomic Energy Commission Report, WASH-129, Sept. 1952.
B. W. MERCER, W. C. SCHMIDT Storage of Long-Lived Fission Products on Alumino-Silicate Zeolites, Handford Atomic Products Operation, General Electric Co., Richland, Washington Report, RL-SA-58, Dec. 1965.
R. FULLERTON, The Effect of Gamma Radiation of Clinoptilolite, Hanford Atomic Products Operation, General Electric Company, Richland, Washington Report, HW-69256, April 1961.
R. M. WALLACE, N. E. BIBLER, private communications, Feb. 1981.
K. K. S. PILLAY, G. PALAU, Radiolytic Effects on Ion Exchangers During the Storage of Radioactive Wastes, Proceedings of International Conference on Radioactive Waste Management, Winnipeg, Canada, Canadian Nuclear Society, Ontario, 1982, p. 204.
G. L. PALAU, Investigation of the Consequences of Radiation Effects on Inorganic Ion Exchangers, M. S Thesis, The Pennsylvania State University, University Park, Pennsylvania 1986.
Evaluation of Increased Cesium Loadings on Submerged Demineralizer System (SDS) Zeolite Beds, DOE-SDS Task Force Report, DOE/NE-0012, May, 1981.
B. T. KENNA, Radiation Stability of Sodium Titanate Ion Exchange Materials, SAND-79-0199, Sandia Laboratories, Albuquerque, New Mexico, 1980.
J. S. GILL, S. N. TANDON, J. Radioanal. Chem., 20 (1974) 5.
J. MATHEWS, S. N. TANDON, J. S. GILL, Radiochem. Radioanal. Letters, 30 (1977) 381.
S. E. ERMATOV, Izvestia Akad, Nauk. Kazakh SSR, Physical and Mathematical, Series, (1967) No. 4, 48.
N. J. SINGH, S. N. TANDON, J. S. GILL, Radiochem. Letters, 41 (1979) No. 1, 79.
N. J. SINGH, S. N. TANDON, J. Radioanal. Chem., 49 (1979) 195.
L. ZSINKA, L. SZIRTES, V. STENGER, Radiochem. Radional. Letters, 4 (1970) No. 5, 257.
L. ZSINKA, L. SZIRTES, J. MINK, A. KÁLMÁN, J. Inorg. Nucl. Chem., 36 (1974) 1147.
K. K. S. PILLAY, Radiation Effects on Ion Exchange Materials Used in Waste Management, in Three-Mile Island Cleanup: Experiences, Waste Disposal and Environmental Impact, AIChE Symposium Series 213, 1982, p. 33.
T. E. GANGWER, K. K. S. PILLAY, Nucl. Technol., 58 (1982) 548.
S. KOMARNENI, R. ROY, Nucl. Chem. Waste Managem., 2, (1981) 259.
H. MIMURA, T. KANNO, J. At. Energy Soc. Japan, 18 (1976) 518 (in Japanese).
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Pillay, K.K.S. A review of the radiation stability of ion exchange materials. Journal of Radioanalytical and Nuclear Chemistry, Articles 102, 247–268 (1986). https://doi.org/10.1007/BF02037966
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DOI: https://doi.org/10.1007/BF02037966