Abstract
The problem of the superexchange interaction between orbitally degenerate ions in magnetic insulators is considered using the tensor operator formalism. The exchange Hamiltonian is derived for ions described in different representations. The number of parameters can be substantially reduced by symmetry considerations and by specifying the exchange mechanism as it is shown on the example of KCoF3.
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The author is indebted to Dr. J.Loos, CSc., and Ing. P.Novák, CSc., for many valuable discussions on the subject and for reading the manuscript.
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Veltruský, I. On superexchange interaction between orbitally degenerate ions. Czech J Phys 25, 101–114 (1975). https://doi.org/10.1007/BF01589677
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DOI: https://doi.org/10.1007/BF01589677