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New phenomena in the adsorption of alkali metals on Al surfaces

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Abstract

Recent studies of the adsorption and co-adsorption of alkali metals on Al surfaces have revealed a wealth of hitherto unexpected phenomena, including: order-preserving phase transformations between metastable and stable structures; reconstruction of the substrate by adsorption at room temperature; and formation of binary and ternary surface alloys. The results of experimental structural determinations are reviewed, with the major emphasis on Low-Energy Electron Diffraction (LEED) studies of the ordered structures formed by adsorption of the alkalis on Al(111). The experimental results are compared where possible with corresponding results of ab initio calculations of total energy by Scheffler and co-workers. The experiment-theory comparisons provide valuable insight into the adsorption mechanisms, including the possible role of surface steps as both sources and sinks.

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References

  1. A. Schmalz, S. Aminpirooz, L. Becker, J. Haase, J. Neugebauer, M. Scheffler, D.R. Batchelor, D.L. Adams, E. Bogh: Phys. Rev. Lett.67, 2163 (1991)

    Google Scholar 

  2. C. Stampfl, M. Scheffler, H. Over, J. Burchhardt, M.M. Nielsen, D.L. Adams, W. Moritz: Phys. Rev. Lett.69, 1532 (1992)

    Google Scholar 

  3. C. Stampfl, M. Scheffler, H. Over, J. Burchhardt, M.M. Nielsen, D.L. Adams, W. Moritz: Phys. Rev. B49, 4959 (1994)

    Google Scholar 

  4. M.M. Nielsen, J. Burchhardt, D.L. Adams. E. Lundgren, J.N. Andersen: Phys. Rev. Lett.72, 3370 (1994)

    Google Scholar 

  5. A. Schmalz, S. Aminpirooz, J. Haase, D.R. Batchelor, M.M. Nielsen, E. Bogh, D.L. Adams: Surf. Sci.301, L211 (1994)

    Google Scholar 

  6. J. Burchhardt, M.M. Nielsen, D.L. Adams, E. Lundgren, J.N. Andersen: Phys. Rev. B50, 4718 (1994)

    Google Scholar 

  7. J. Burchhardt, M.M. Nielsen, D.L. Adams, E. Lundgren, J.N. Andersen, C. Stampfl, M. Scheffler, A. Scmalz, S. Aminpirooz, J. Haase: Phys. Rev. Lett.74, 1617 (1995)

    Google Scholar 

  8. J. Neugebauer, M. Scheffler: Phys. Rev. B46, 16067 (1992)

    Google Scholar 

  9. J. Neugebauer, M. Scheffler: Phys. Rev. Lett.71, 577 (1993)

    Google Scholar 

  10. B. Wenzien, J. Bormet, J. Neugebauer, M. Scheffler: Surf. Sci.287/288, 559 (1993)

    Google Scholar 

  11. J. Bormet, J. Neugebauer, M. Scheffler: Phys. Rev. B49, 17242 (1994)

    Google Scholar 

  12. C. Stampfl, M. Scheffler: Surf. Sci.319, L23 (1994)

    Google Scholar 

  13. C. Stampfl, M. Scheffler: Surf. Rev. Lett.2, 317 (1995)

    Google Scholar 

  14. S. Aminpirooz, A. Schmalz, L. Becker, N. Pangher, J. Haase, M.M. Nielsen, D.R. Batchelor, E. Bøgh, D.L. Adams: Phys. Rev. B46, 15594 (1992)

    Google Scholar 

  15. W. Berndt, D. Weick, C. Stampft, A.M. Bradshaw, M. Scheffler: Surf. Sci. (in press)

  16. C. Stampfl, J. Neugebauer, M. Schefller: Surf. Sci.307/309, 8 (1994); Surf. Rev. Lett.1, 222 (1994)

    Google Scholar 

  17. J.N. Andersen, M. Qvarford, R. Nyholm, J.F. van Acker, E. Lundgren: Phys. Rev. Lett.68, 94 (1992)

    Google Scholar 

  18. J.N. Andersen, E. Lundgren, R. Nyholm, M. Qvarford: Phys. Rev. B46, 12784 (1992)

    Google Scholar 

  19. J.N. Andersen, E. Lundgren, R. Nyholm, M. Qvarford: Surf. Sci.289, 307 (1993)

    Google Scholar 

  20. J.N. Andersen: Surf. Rev. Lett.2, 345 (1995)

    Google Scholar 

  21. An excellent source of references and reviews of many aspects of alkali-metal adsorption can be found in: H.P. Bonzel, A.M. Bradshaw, G. Ertl:Physics and Chemistry of Alkali Metal Adsorption (Elsevier, Amsterdam 1989)

    Google Scholar 

  22. I. Langmuir, K.H. Kingdon: Science57, 58 (1923)

    Google Scholar 

  23. I. Langmuir: J. Am. Chem. Soc.54, 2798 (1932)

    Google Scholar 

  24. J.B. Taylor, I. Langmuir: Phys. Rev.44, 423 (1933)

    Google Scholar 

  25. J. Topping: Proc. R. Soc. London A114, 67 (1927)

    Google Scholar 

  26. R.W. Gurney: Phys. Rev.47, 479 (1935)

    Google Scholar 

  27. N.D. Lang, A.R. Williams: Phys. Rev. B16, 2408 (1977); Phys. Rev. B18, 616 (1978)

    Google Scholar 

  28. E.W. Plummer, R.D. Young: Phys. Rev. B1, 2088 (1970)

    Google Scholar 

  29. H. Ishida, K. Terakura: Phys. Rev. B38, 5752 (1988)

    Google Scholar 

  30. H. Ishida: Phys. Rev. B39, 5492 (1989); Surf. Sci.242, 341 (1991)

    Google Scholar 

  31. N. Lang: In Ref. [21]p. 11

    Google Scholar 

  32. K. Horn, A. Hohlfeld, J. Somers, Th. Lindner, P. Hollins, A.M. Bradshaw: Phys. Rev. Lett.61, 2488 (1988)

    Google Scholar 

  33. D. Heskett, K.-H. Frank, E.-E. Koch, H.-J. Freund: Phys. Rev. B36, 1276 (1987)

    Google Scholar 

  34. D. Heskett, K.-H. Frank, K. Horn, E.-E. Koch, H.-J. Freund, A. Baddorf, K.-D. Tsuei, E.W. Plummer: Phys. Rev. B37, 10387 (1988)

    Google Scholar 

  35. K.-H. Frank, H.-J. Sagner, D. Heskett: Phys. Rev. B40, 2767 (1989)

    Google Scholar 

  36. L.M. Khan, S.C. Ying: Surf. Sci.59, 333 (1976)

    Google Scholar 

  37. R.L. Gerlach, T.N. Rhodin: Surf. Sci.17, 32 (1969)

    Google Scholar 

  38. W.C. Fan, A. Ignatiev: Phys. Rev. B38, 366 (1988)

    Google Scholar 

  39. S. Chandavarkar, R.D. Diehl, A. Fake, J. Jupille: Surf. Sci.211/212, 432 (1989)

    Google Scholar 

  40. B. E. Hayden, K.C. Prince, P.J. Davie, G. Paolucci, A. M. Bradshaw: Solid State Commun.48, 325 (1983)

    Google Scholar 

  41. R.J. Behm: In Ref. [21] p. 111

    Google Scholar 

  42. K.W. Jakobsen, J. K. Norskov: Phys. Rev. Lett.60, 2496 (1988)

    Google Scholar 

  43. J.E. Demuth, D.W. Jepsen, P.M. Marcus: J. Phys. (Paris) C8, L25 (1975)

    Google Scholar 

  44. B.A. Hutchins, T.N. Rhodin, J.E. Demuth: Surf. Sci.54, 419 (1976)

    Google Scholar 

  45. S.Å. Lindgren, L. Walldén, J. Rundgren, P. Westrin, J. Neve: Phys. Rev. B28, 6707 (1983)

    Google Scholar 

  46. G. von Eggeling, G. Schmidt, G. Besold, L. Hammer, K. Heinz, K. Müller: Surf. Sci.221, 11 (1989)

    Google Scholar 

  47. G.M. Lamble, R.S. Brooks, D.A. King, D. Norman: Phys. Rev. Lett.61, 1112 (1988)

    Google Scholar 

  48. S.V. Christensen, J. Nerlov, K. Nielsen, J. Burchhardt, M.M. Nielsen, D.L. Adams: Phys. Rev. Lett.

  49. J.O. Porteus: Surf. Sci.41, 515 (1974)

    Google Scholar 

  50. A. Hohlfeld, M. Sunjic, K. Horn: J. Vac. Sci. Technol. A5, 679 (1987)

    Google Scholar 

  51. A. Hohlfeld, K. Horn: Surf. Sci.211, 844 (1989)

    Google Scholar 

  52. M.M. Nielsen, J. Burchhardt, D.L. Adams, J.N. Andersen: Unpublished

  53. SAES Getters, Milan, Italy

  54. D.L. Adams, S.P. Andersen, J. Burchhardt: InThe Structure of Surfaces III, ed. by S.Y. Tong, M.A. Van Hove, X. Xide, K. Takayanagi, Springer, Ser. Surf. Sci., Vol. 24 (Springer, Berlin, Heidelberg 1991) p. 156

    Google Scholar 

  55. M.M. Nielsen, J. Burchhardt, D.L. Adams: Phys. Rev. B50, 7851 (1994)

    Google Scholar 

  56. J.B. Pendry:Low-Energy Electron Diffraction (Academic, London 1974)

    Google Scholar 

  57. M.A. Van Hove, S.Y. Tong:Surface Crystallography by LEED, Springer Ser. Chem. Phys., Vol. 2 (Springer, Berlin,, Heidelberg 1979)

    Google Scholar 

  58. V.L. Moruzzi, J.F. Janak, A.R. Williams:Calculated Electronic Properties of Metals (Pergamon, New York 1978)

    Google Scholar 

  59. N.E. Christensen: Private communication

  60. D.L. Adams, V. Jensen, X.F. Sun, J.H. Vollesen: Phys. Rev. B38, 7913 (1988)

    Google Scholar 

  61. D.L. Adams, H.B. Nielsen, M.A. Van Hove: Phys. Rev. B20, 4789 (1979)

    Google Scholar 

  62. D.L. Adams, S.P. Andersen: InThe Structure of Surfaces III, ed. by S.Y. Tong, M.A. Van Hove, X. Xide, K. Takayanagi, Springer Ser. Surf. Sci., Vol. 24 (Springer, Berlin, Heidelberg 1991) p. 395

    Google Scholar 

  63. J.B. Pendry: J. Phys. (Paris) C13, 937 (1980)

    Google Scholar 

  64. E. Zanazzi, F. Jona: Surf. Sci.62, 61 (1977)

    Google Scholar 

  65. M. Kerkar, D. Fisher, D.P. Woodruff, R.G. Jones, R.D. Diehl, B. Cowie: Phys. Rev. Lett.68, 3204 (1992)

    Google Scholar 

  66. M. Kerkar, D. Fisher, D. P. Woodruff, R. G. Jones, R. D. Diehl, B. Cowie: Surf. Sci.278, 246 (1992)

    Google Scholar 

  67. H.V. Jørgensen: unpublished

  68. H.V. Jørgensen, E. Bogh: Unpublished

  69. H.B. Nielsen, D.L. Adams: Unpublished

  70. J. Wang, Z.C. Ying, E.W. Plummer: Phys. Rev. B51, 5590 (1995)

    Google Scholar 

  71. M. Kerkar, D. Fisher, D.P. Woodruff, R.G. Jones, R.D. Diehl, C.F. McConville, B. Cowie: J. Vac. Sci. Technol. A10, 2148 (1992)

    Google Scholar 

  72. M.M. Nielsen, J. Burchhardt, D.L. Adams, J.N. Andersen: Unpublished

  73. A. Taylor, B.J. Kagle:Crystallographic Data on Metal and Alloy Structures (Dover, New York 1963)

    Google Scholar 

  74. CRC Handbook of Chemistry and Physics, 68th edn. (CRC, Boca Raton, FL 1987/1988) p. F-159

  75. U. Löfller, R. Doll. K. Heinz, J.B. Pendry: Surf. Sci. (in press)

  76. J. Burchhardt, M.M. Nielsen, D.L. Adams, E. Lundgren, J.N. Andersen: Unpublished

  77. Th. Laloyaux, M. Scheffler: Verhandl.DPG 29, 1342 (1994)

    Google Scholar 

  78. M. Scheffler: Private communication

  79. Th. Laloyaux, M. Scheffler: Unpublished

  80. H. Brune: Unpublished

  81. H. Brune, J. Wintterlin, R.J. Behm, G. Ertl: Phys. Rev. B51, 13592 (1995)

    Google Scholar 

  82. H. Over, W. Moritz, G. Ertl: Phys. Rev. Lett.70, 315 (1993)

    Google Scholar 

  83. V. Fritzsche: Phys. Rev. B50, 1922 (1994)

    Google Scholar 

  84. W. Moritz, J. Landskron: Surf. Sci. (in press)

  85. U. Löffler, U. Muschiol, P. Bayer, K. Heinz, V. Fritzsche, J.B. Pendry: Surf. Sci. (in press)

  86. J.N. Andersen, H.B. Nielsen, L. Petersen, D.L. Adams: J. Phys. C17, 173 (1984)

    Google Scholar 

  87. D. Fisher, S. Chandavarker, I.R. Collins, R.D. Diehl, P. Kaukasoina, M. Lindroos: Phys. Rev. Lett.68, 2786 (1992)

    Google Scholar 

  88. H. Over, H. Bludau, M. Skotte-Klein, G. Ertl, W. Moritz, C.T. Cambell: Phys. Rev. B45, 8638 (1992)

    Google Scholar 

  89. R. Stumpf, M. Scheffler: Phys. Rev. Lett.72, 254 (1994)

    Google Scholar 

  90. E. Lundgren, R. Nyholm, J. Burchhardt, D. Heskett, J.N. Andersen: Surf. Sci. (submitted)

  91. L.H. Germer: Phys. Today, 19 (July 1964)

  92. J. Kudrnovský, S.K. Bose, V. Drchal: Phys. Rev. Lett.69, 308 (1992) and references therein

    Google Scholar 

  93. M. Wuttig, Y. Gauthier, S. Blügel: Phys. Rev. Lett.70, 3619 (1993)

    Google Scholar 

  94. L.P. Nielsen, F. Besenbacher, I. Stensgaard, E. Lægsgaard, C. Engdahl, P. Stoltze, K.W. Jakobsen, J.K. Norskov: Phys. Rev. Lett.71, 754 (1993)

    Google Scholar 

  95. P. Villars, L.D. Calvert:Pearson's Handbook of Crystallographic Data, for Intermetallic Phases (ASM, Materials Park, OH 1991)

    Google Scholar 

  96. W.B. Pearson:The Crystal Chemistry and Physics of Metals and Alloys (Wiley, New York 1972)

    Google Scholar 

  97. R. Hultgren, P.D. Desai, D.T. Hawkins, M. Gleiser, K.K. Kelly:Selected Values of the Thermodynamic Properties of Binary Alloys (American Society for Metals, Metals Park, OH 1973)

    Google Scholar 

  98. Pearson (Ref. [94]) notes that: “originally, the CsCI structure was thought of as an ionic structure, but now that several hundred metallic phases have been found to have the structure, it must be regarded essentially as a metallic structure”. A listing of these phases in Ref. [93] includes over 50 binary and ternary Al alloys

  99. J.V. Barth, H. Brune, R. Schuster, G. Ertl, R. J. Behm: Surf. Sci.292, L769 (1993)

    Google Scholar 

  100. R.H. Bergmans, A.L.G.P. Brands, A.W. Denier van der Gon. W.C.A.N. Ceelen, H.H. Brongersma: Surf. Sci. (submitted)

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Adams, D.L. New phenomena in the adsorption of alkali metals on Al surfaces. Appl. Phys. A 62, 123–142 (1996). https://doi.org/10.1007/BF01575710

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