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Thermodynamics of acrylic esters containing binary liquid mixtures. I. Excess volumes and isentropic compressibilities of alkyl methacrylates +n-hexane, +n-heptane, + carbon tetrachloride, + chlorobenzene, ando-dichlorobenzene at 303.15 K

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Abstract

Excess volumes and isentropic compressibilities of 15 binary liquid mixtures containing methyl methacrylate (MMA). ethyl methacrylate (EMA), and butyl methacrylate (BM) andn-Hexane,n-heptane, carbon tetrachloride chlorobenzene ando-dichlorobenzene are derived from the measured densities and speeds of sound at 303.15 K. The dependence of the excess volumes and the isentropic compressibilities both on the alkyl chain length and on the nature of the solvent shots the dominance of dispersing interactions in the mixtures of aliphatic hydrocarbons and specific interactions im the chlorinated solvent mixtures. The speeds of sound of binary mixtures of MMA were found to be reasonably predicted by free length and collision factor theories. An attempt is also made to estimate the individual contributions of interactional. free volume andP * effects to the overall excess volumes of binary mixtures containing MMA. The results indicate that the three factors are equally responsible for the observed values.

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  1. Department of Chemistry, Sardar Patel University, Vallabh Vidyanagar, 388120, Gujarat, India

    N. V. Sastry & P. N. Dave

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  1. N. V. Sastry
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  2. P. N. Dave
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Sastry, N.V., Dave, P.N. Thermodynamics of acrylic esters containing binary liquid mixtures. I. Excess volumes and isentropic compressibilities of alkyl methacrylates +n-hexane, +n-heptane, + carbon tetrachloride, + chlorobenzene, ando-dichlorobenzene at 303.15 K. Int J Thermophys 17, 1289–1304 (1996). https://doi.org/10.1007/BF01438671

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  • DOI: https://doi.org/10.1007/BF01438671

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