Skip to main content
SpringerLink
Log in

Contribution to the thermodynamics of emulsions

  • Corrections
  • Colloid Science
  • Published:
Colloid and Polymer Science Aims and scope Submit manuscript

Summary

In this paper there are derived equations for thermodynamically stable emulsions of phase II in phase I in the presence of surfactants.

Zusammenfassung

In dieser Arbeit werden Gleichungen für thermodynamisch stabile Emulsionen einer Phase II in Phase I in Gegenwart oberflächenaktiver Stoffe abgeleitet.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

Abbreviations

A :

interfacial area between phase I and phase II

σ:

interfacial tension between phase I and phase II

σ0 :

interfacial tension without presence of a surfactant

n i :

number of moles = amount of componenti

C 3 :

concentration of the surfactant = component 3 in phase I in mol/cm3

References

  1. Derjaguin, B., Acta Psysicochim. URSS10, 333 (1939); Trans. Faraday Soc.36, 203 (1940),B. Derjaguin andL. Landau, Acta Psysicochim. URSS14, 633 (1941).

    Google Scholar 

  2. Verwey, E. J. W. andJ. T. G. Overbeek, Theory of the Stability of Lyophobic Colloids (New York 1948).

  3. Bikerman, J. J., Surface Chemistry, 2nd edition, p. 165 (New York 1958).

  4. Kitchner, J. A. andP. R. Musselwhite in: Emulsion Science, ed. byP. Sherman, pp. 77f. (New York 1968).

  5. Donnan, F. G., Z. physik. Chemie31, 42 (1899);37, 735 (1901);46, 197 (1903).

    Google Scholar 

  6. von Raschewsky, N., Z. Physik46, 598 (1937).

    Google Scholar 

  7. von Stackelberg, M., E. Klockner andP. Mohrhauer, Kolloid-Z.115, 53 (1949).

    Google Scholar 

  8. Davies, J. T. andE. K. Rideal, Interfacial Phenomena, pp. 362ff. (New York 1961).

  9. Davies, J. T. andD. A. Haydon, Proc. 2nd Internat. Congress Surface Activity1, 417 (London 1957).

  10. Kling, W. andH. Lange, Proc. 2nd Internat. Congress Surface Activity1, 295 (London 1957).

  11. van Vorst Vadder, F., Trans. Faraday Soc.56, 1067, 1078 (1960).

    Google Scholar 

  12. Schulman, J. H. andE. G. Cockbain, Trans. Faraday Soc.36, 651 (1940).

    Google Scholar 

  13. Hartung, H. A. andO. K. Rice, J. Colloid Sci.10, 436 (1955).

    Google Scholar 

  14. Lewis, G. N. andM. Randall, Thermodynamics. p. 479 (New York 1961).

  15. Wagner, C., Nachr. Akad. Wiss. Göttingen, II. Math. Phys. Klasse1973, 37.

  16. Hartley, G. S., Trans. Faraday Soc.37, 130 (1941).

    Google Scholar 

  17. Klevens, H. B., Chem. Rev.47, 1 (1950).

    Google Scholar 

  18. Winsor, P. A., Solvent Properties of Amphilic Compounds (London 1954).

  19. McBain, M. E. L. andE. Hutchinson, Solubilization and Related Phenomena (New York 1955).

  20. Stauff, J., Kolloidchemie, pp. 5679. (Berlin 1960).

Download references

Author information

Authors and Affiliations

  1. Max-Planck-Institut für biophysikalische Chemie (Karl-Friedrich-Bonhoeffer-Institut), Göttingen

    Carl Wagner

  2. Charlottenburger Straße 19 Wohnstift C 309, 3400, Göttingen-Geismar

    Carl Wagner

Authors
  1. Carl Wagner
    View author publications

    You can also search for this author in PubMed Google Scholar

Additional information

With 1 figure and 2 tables

Rights and permissions

Reprints and permissions

About this article

Cite this article

Wagner, C. Contribution to the thermodynamics of emulsions. Colloid & Polymer Sci 254, 400–408 (1976). https://doi.org/10.1007/BF01382122

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF01382122

Keywords

Search

Navigation