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Heterogeneous catalysis intermediates and mechanisms

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Abstract

The present state of information about the intermediate compounds in heterogeneous catalysis is examined. It is shown that to obtain reliable data on the intermediate compounds it is necessary to use the kinetic data obtained by physical methods in situ and, primarily, IR spectroscopy and also NMR spectroscopy.

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Authors and Affiliations

  1. N. N. Semenov Institute of Chemical Physics, Russian Academy of Sciences, 117977, Moskva, Ul. Kosygina, 4

    O. V. Krylov

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Dedicated to the centenary of the birth of A. I. Brodskii.

Translated from Teoreticheskaya i Éksperimental'naya Khimiya, Vol. 31, No. 4, pp. 212–222, July–August, 1995.

The author thanks V. A. Matyshak and V. V. Rozanov for close and fruitful collaboration and also the International Scientific Fund (ISF) for partial financial support (Grant MDD OOO).

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Krylov, O.V. Heterogeneous catalysis intermediates and mechanisms. Theor Exp Chem 31, 169–179 (1995). https://doi.org/10.1007/BF01195922

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