Summary
The high-alumina metapelites and the orthogneisses of the lower tectonic unit of East Rhodope underwent high P/T metamorphism followed by partial reequilibration during decompression under epidote-amphibolite/amphibolite facies to greenschist facies conditions. The high P/T mineral paragenesis in the orthogneisses is: quartz + albite + microcline + phengite (Simax = 7 atoms p.f.u.) + biotite and in the high alumina metapelites: garnet + chloritoid + chlorite + phengite (Simax. = 6.85 atoms p.f u.) + paragonite + quartz. Pressures between 14 and 15.5 kbar, for Tmin = 550°C, are estimated for the high P/T metamorphism. During continuing uplift, staurolite + chlorite, staurolite + biotite and finally andalusite + Fe-ripidolite are grown at the expense of chloritoid in metapelites, while in the orthogneisses oligoclase, still coexisting with albite, is formed; in both rock types the Si content of white K-mica decreases considerably from almost pure phengite to pure muscovite.
Zusammenfassung
Die Aluminium-reichen Metapelite und die Orthogneise der unteren tektonischen Einheit der östlichen Rhodope-Zone wurde unter hohen Drucken und Temperaturen metamorphosiert. Darauf folgte eine teilweise Reequilibration unter Druck-Entlastung bei Bedingungen der Epidot-Amphibolit/Amphibolit bis Grünschiefer Fazies. Die Hoch-P/T Mineral-Assoziation in den Orthogneisen besteht aus: Quarz + Albit + Mikroklin + Phengit (Simax = 7 atoms p.f.u.) + Biotit und in den Aluminium-reichen Metapeliten: Granat + Chloritoid + Chlorit + Phengit (Simax = 6.85 atoms p.f.u.) + Paragonit + Quarz. Drucke zwischen 14 and 15.5 kbar für Tmin = 550°C wurden für die Hoch- P/T Metamorphose berechnet. Während andauernder Anhebung bildeten sich Staurolit + Chlorit, Staurolit + Biotit und schließlich Andalusit + Fe-Ripidolit auf Kosten von Chloritoid in den Metapeliten, während in den Orthogneisen Oligoklas der noch mit Albit koexistiert, gebildet wurde; in beiden Gesteinstypen nimmt der Si-Gehalt heller Kaliglimmer von fast reinem Phengit bis zu reinem Muskowit ab.
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References
Chatterjee ND (1972) The upper stability limit of the assemblage paragonite + quartz and its natural occurrences. Contrib Mineral Petrol 34: 288–303
Chopin C, Maluski H (1980)40Ar-39Ar dating of high pressure metamorphic micas from the Gran Paradiso Area (Western Alps): evidence against the blocking temperature concept. Contrib Mineral Petrol 74: 109–122
Cimmino F, Messiga B (1979) I calcescisti del Gruppo di Voltri (Liguria Occidentale) le variationi compositionali delle miche bianche in rapporto alla evoluzione tettonicometamorfica alpina. Ofioliti 4(3): 269–294
Enami M (1983) Petrology of pelitic schists in the oligoclase-biotite zone of the Sanbagawa metamorphic terrain, Japan: phase equilibria in the highest grade zone of the highpressure intermediate type of metamorphic belt. J Metam Geol 1: 141–161
Evans, WB, Patrick BE (1987) Phengite-3T in high-pressure metamorphosed granitic orthogneisses, Seward Peninsula, Alaska. Can Mineral 25: 141–158
Franz F, Thomas S, Smith DC (1986) High pressure phengite decomposition in the Weissenstein eclogite, Münchberger Gneiss Massiv, Germany. Contrib Mineral Petrol 92: 71–85
Frey M, Hunziker Jc, Jäger E, Stern WB (1983) Regional distribution of white K-mica polymorphs and their phengite content in the Central Alps. Contrib Mineral Petrol 83: 185–197
Grambling JA (1984) Coexisting paragonite and quartz in sillimanitic rocks from New Mexico. Amer Mineral 69: 79–87
Guidotti CV (1984) Micas in metamorphic rocks. In: Bailey SW (ed) Micas Mineral Soc Amer, Rev Mineral 13: 357–468
Heinrich CA (1982) Kyanite eclogite to amphibolite facies evolution of hydrous maflc and pelitic rocks, Adula Nappe, Central Alps. Contrib Mineral Petrol 81: 30–38
Holdaway MJ (1971) Stability of andalusite and the aluminumsilicate phase diagram. Amer J Sci 271: 97–131
Holland TJB (1978) The reaction: albite = jadeite + quartz determined experimentally in the range 600°–1200°C. Amer Mineral 65: 129–134
Lardeaux JM, Gosso G, Kienast JR, Lombardo B (1983) Chemical variations in phengitic micas of successive foliations within the eclogitic micaschist complex, Sesia-Lanzo Zone (Italy, Western Alps). Bull Mineral 106: 673–689
Liati A, Mposkos E (1989) Petrological evolution of the eclogites of Rhodope, N. Greece. Third Intern. Eclogite Conference, Würzburg (Abstract)
Massonne JH, Schreyer W (1987) Phengite geobarometry based on the limiting assemblage with K-feldspar, phlogopite and quartz. Contrib Mineral Petrol 96: 212–224
Mather JD (1970) The biotite isograde and the lower greenschist facies in the Dalradian rocks of Scotland. J Petrol 11: 253–275
Miyashiro A, Shido F (1985) Tschermak substitution in low and middle-grade pelitic schists. J Petrology 26: 449–487
Mposkos E (1987) Polymetamorphism in Central and East Rhodope Massif. Proceedings, First Bulgarian-Greek Symposium on the Geology and Physical Geography of the Rhodope Massif (in press)
—(1988) The chloritoid-staurolite schists of the lower tectonic unit in East Rhodope. Bull Geol Soc Greece (in press) (in Greek with English summary)
—(1989) Metamorphic evolution of the lower tectonic unit of E Rhodope (N Greece), based on metabasite petrology. XIV Carpatho-Balkan Congress, Sofia (Abstract)
—Perdikatsis V (1987) Eclogite-amphibolites in East Rhodope Massif. Proceedings, First Bulgarian-Greek Symposium on the Geology and Physical Geography of the Rhodope Massif (in press)
——,Papadopoulos P, Perdikatsis V (1986) The Rhodope crystalline basement east of Komotini. Bull Geol Soc Greece, XX (2): 259–273 (in Greek with English summary)
Richardson SW, Gilbert MC, Bell PM (1969) Experimental determination of kyaniteandalusite und andalusite-sillimanite equilibria: the aluminosilicate triple point. Amer J Sci 267: 259–272
Schliestedt M (1980) Phasengleichgewichte in Hochdruckgesteinen von Sifnos, Griechenland. Unpubl. Dissertation, Techn. Univ. Braunschweig
Thompson JB (1979) The Tschermak substitution and reactions in pelitic schists. In:Zharikov VA, Fonorev VI, Korikovski JP (eds) Problems in physicochemical petrology. Academy of Sciences, Moscow, pp 146–159.
Velde B (1965) Phengite micas: Synthesis, stability and natural occurrence. Amer J Sci 263: 886–913
Vuichard JP, Ballevre M (1988) Garnet-chloritoid equilibria in eclogitic pelitic rocks from the Sesia Zone (Western Alps): their bearing on phase relations in high pressure metapelites. J Metam Geol 6: 135–157
Wise WS, Eugster HP (1964) Celadonite: synthesis, thermal stability and occurrence. Amer Mineral 49: 1031–1083
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Mposkos, E. High-pressure metamorphism in gneisses and pelitic schists in the East Rhodope zone (N. Greece). Mineralogy and Petrology 41, 25–39 (1989). https://doi.org/10.1007/BF01164808
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DOI: https://doi.org/10.1007/BF01164808