Abstract
The studies using NMR and capillary zone electrophoresis clearly reveal that protonated 6A-amino- 6A-deoxy-β-cyclodextrin recognizes the chirality of anionic binaphthyl derivatives such as 1,1′-binaphthyl-2,2′-diyl phosphate and 1,1′-binaphthyl-2,2′-dicarboxylate through electrostatic interaction between the host and the guest and simultaneous inclusion.
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Kano, K., Kitae, T. & Takashima, H. Use of electrostatic interaction for chiral recognition. Enantioselective complexation of anionic binaphthyls with protonated amino-β-cyclodextrin. J Incl Phenom Macrocycl Chem 25, 243–248 (1996). https://doi.org/10.1007/BF01041578
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DOI: https://doi.org/10.1007/BF01041578