Abstract
A series of glass specimens was prepared from TeO2 glass and from the binary tungsten tellurite glasses (TeO2-WO3) and their densities, optical absorption edges and infrared absorption spectra were measured. It was found that the fundamental absorption edge is a function of glass composition, and absorption in this region is due to indirect electronic transitions in k-space. The main infrared absorption bands in the TeO2-WO3 glasses are related to those characteristics of the TeO2 component.
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References
F. Urbach,Phys. Rev. 92 (1953) 1324.
J. Tauc, R. Grigorovici andA. Vancu,Phys. Status Solidi 15 (1966) 627.
E. A. Davis andN. F. Mott,Phil. Mag. 22 (1970) 903.
G. R. Moridi andC. A. Hogarth, Proceedings of 7th International Conference on Amorphous and Liquid Semiconductors, Edinburgh, 1977, edited by W. E. Spear (University of Edinburgh Centre for Industrial Consultancy and Liaison, 1977) p. 688.
N. F. Mott andE. A. Davis, “Electronic Processes in Non-Crystalline Materials”, 2nd edn (Claredon Press, Oxford 1979).
C. A. Hogarth andM. Y. Nadeem,Phys. Status Solidi (a) 68 (1981) K181.
S. K. Deb,Phil. Mag. 27 (1973) 801.
A. Mansingh, M. Sayer andJ. B. Webb,J. Non-Cryst. Solids 28 (1978) 123.
J. Berzelius,Ann. Phys. Chem. 32 (1834) 577.
N. V. Ovcharenko andA. K. Yakhkind,Sov. J. Opt. Technol. 38 (1971) 163.
A. K. Yakhkind,J. Amer. Ceram. Soc. 49 (1966) 670.
M. J. Redman andJ. H. Chen,ibid 50 (1967) 523.
T. Yano,J. Appl. Phys. 42 (1974) 3674.
E. F. Lambson, G. A. Saunders, B. Bridge andR. A. El-Mallawany,J. Non. Cryst. Solids. in press.
C. A. Hogarth andE. Assadzadehkashani,J. Mater. Sci 18 (1983) 1255.
V. P. Cheremisinov andV. P. Zlomanov,Optica Spectroskopya 12 (1962) 110.
V. Kozhukharov, M. Marinov andG. Grigorova,J. Non-Cryst. Solids 28 (1978) 429.
J. D. Dow andD. Redfield,Phys. Rev. B 5 (1972) 594.
J. Tauc, in “The Optical Properties of Solids”, edited by F. Abeles (North-Holland, Amsterdam, 1970) p. 277.
I. G. Austin, M. Sayer andR. S. Sussman, “Amorphous and Liquid Semiconductors” Proceedings of the 5th International Conference, Garmisch-Partkenkirchen, Germany, 1973, edited by J. Stuke and W. Brenig (Taylor and Francis, London 1973) p. 1343.
J. Tauc andA. Menth,J. Non. Cryst. Solids 8–10 (1972) 569.
J. M. Stevels, Proceedings of the 11th International Congress on Pure and Applied Chemistry, Vol 5 (1953) p. 519.
W. H. Zachariasen,J. Amer. Chem. Soc. 54 (1932) 3841.
Y. O. S. Bobovich andA. K. Yakhkind,J. Struct. Chem. 4 (1963) 851.
Z. Zeng,Kuei Suan Yen Hsuch Pao 9 (2) (1982) 228.
N. N. Moshida, K. Takahashi, K. Nakata andS. Shibusawa,Yogyo Kyokai Shi 86 (1978) 316.
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Al-Ani, S.K.J., Hogarth, C.A. & El-Malawany, R.A. A study of optical absorption in tellurite and tungsten-tellurite glasses. J Mater Sci 20, 661–667 (1985). https://doi.org/10.1007/BF01026540
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DOI: https://doi.org/10.1007/BF01026540