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Impedance spectroscopic studies of mixed alkali tellurite glasses

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Abstract

The mixed alkali tellurite glasses for the glass system 0.70TeO2·(0.30 − x)Na2O·xK2O (x = 0.0 and 0.05) were prepared by conventional melt-quench method. The investigated glasses are characterized by impedance spectroscopic technique. The impedance behavior included the contribution of bulk or glassy matrix was found at lower temperatures and a few electrode contributions at higher temperatures. Scaling analysis of the complex modulus showed excellent temperature superposition indicated that the ion transport mechanism remains the same throughout the measured range of temperatures. Some deviations from scaling at higher frequencies are observed due to local structural disorder caused by structural transition in the tellurite glass network.

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Acknowledgments

The authors are gratefully acknowledging to the CSIR, New Delhi, (India) for financial support under Project No. 03(1300)/13/EMR-II. The authors are very thankful to Dr. Sevi Murgavel for providing impedance measurement facility.

Conflict of interest

The authors declare that there is no conflict of interests regarding the publication of this paper.

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Authors and Affiliations

  1. Department of Physics, Indian Institute of Technology, Banaras Hindu University, Varanasi, 221005, India

    Avadhesh Kumar Yadav & Prabhakar Singh

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  1. Avadhesh Kumar Yadav
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  2. Prabhakar Singh
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Correspondence to Prabhakar Singh.

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Yadav, A.K., Singh, P. Impedance spectroscopic studies of mixed alkali tellurite glasses. J Mater Sci: Mater Electron 26, 9443–9450 (2015). https://doi.org/10.1007/s10854-015-3375-7

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  • DOI: https://doi.org/10.1007/s10854-015-3375-7

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