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Chemical ionization mass spectrometry

Application to insect-derived cuticular alkanes

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Abstract

GC-CI-MS is shown to be the method of choice for determining the molecular weight of every component in complex alkane mixtures such as those found on insect cuticle. It also provides branch point information. The technique was applied to a number of normal and methyl-branched synthetic alkanes, as well as to the hydrocarbons from the termiteReticulitermes flavipes (Kollar), the cricketGryllus pennsylvanicus Burmeister, and the beetleLasioderma serricorne (Fabricius).

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References

  • Baker, J.E., Sukkestad, D.R., Nelson, D.R., andFatland, C.L. 1980. Cuticular lipids of larvae and adults of the cigarette beetle,Lasioderma serricorne.Insect Biochem. 9:603–611.

    Google Scholar 

  • Blomquist, G.J., Blailock, T.T., Scheetz, R.W., andJackson, L.L. 1976. Cuticular lipids of insects—VII. Cuticular hydrocarbons of the cricketsAcheta domesticus, Gryllus pennsylvanicus, andNemobius fasciatus.Comp. Biochem. Physiol. 54B:381–386.

    Google Scholar 

  • Field, F.H. 1968. Chemical ionization mass spectrometry.Accounts Chem. Res. 1:42–49.

    Google Scholar 

  • Field, F. H., Munson, M.S.B., andBecker, D.A. 1966. Chemical ionization mass spectrometry. Paraffin hydrocarbons, pp. 167–192in R.F. Gould (ed.), Advances in Chemistry, Series 58. American Chemical Society, Washington, D.C.

    Google Scholar 

  • Gelpi, E., andOró, J. 1967. Chemical ionization mass spectrometry of pristane.Anal. Chem. 39(3):388–389.

    Google Scholar 

  • Howard, R.W., McDaniel, C.A., andBlomquist, G.J. 1973. Cuticular hydrocarbons of the eastern subterranean termiteReticulitermes flavipes (Kollar) (Isoptera: Rhinotermitidae).J. Chem. Ecol. 4(2):233–245.

    Google Scholar 

  • Hunt, D.F., andHarvey, T.M. 1975. Nitric oxide chemical ionization mass spectra of alkanes.Anal. Chem. 47(12):1965–1969.

    Google Scholar 

  • Jackson, L.L., andBlomquist, G.J. 1976. Insect waxes, pp. 201–233, in P.E. Kolattukudy (ed.). Chemistry and Biochemistry of Natural Waxes. Elsevier, Amsterdam.

    Google Scholar 

  • Munson, M.S.B., andField, F.H. 1966. Chemical ionization mass spectrometry. I. General introduction.J. Am. Chem. Soc. 88(12):2621–2630.

    Google Scholar 

  • Nelson, D.R. 1978. Long-chain methyl-branched hydrocarbons: occurrence, biosynthesis, and function.Adv. Insect Physiol. 13:1–33.

    Google Scholar 

  • Nelson, D.R., andSukkestad, D.R. 1975. Normal and branched alkanes from cast skins of the grasshopperSchistocerca vaga (Scudder).J. Lipid Res. 16:12–18.

    PubMed  Google Scholar 

  • Scammells, D.V., andHickmott, B. 1976. Diagnostic trends in the mass spectra of some mono methyl alkanes.Org. Mass Spectrose 11:901–903.

    Google Scholar 

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Mention of company or trade names is solely for identification of material used and does not imply endorsement by the U.S. Department of Agriculture.

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Howard, R.W., McDaniel, C.A., Nelson, D.R. et al. Chemical ionization mass spectrometry. J Chem Ecol 6, 609–623 (1980). https://doi.org/10.1007/BF00987673

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  • DOI: https://doi.org/10.1007/BF00987673

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