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Structural studies on an ORMOCER system containing zirconium

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Abstract

The modified precursor Zr(nOPr)3OOMc (McOOH=methacrylic acid) has been successfully used to synthesize organically modified ceramics (ORMOCERs) via a sol-gel process and via ultraviolet (u.v.) curing. The precursor and the ORMOCERs were investigated by the measurement of X-ray absorption fine structure (XAFS) and by electron microscopy. A model for the structure of the precursor is proposed. In the case of the inorganic synthesis of the ORMOCER, a first indication of a bond of the type Zr-O-Si was found.

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Author notes

  1. A. Helmerich

    Present address: Siemens/Nixdorf AP82 MchP/Pb, Otto-Hahn-Ring 6, W-8000, München 83, FRG

Authors and Affiliations

  1. Fraunhofer-Institut für Silicatforschung, W-8700, Würzburg, Neunerplatz 2, FRG

    A. Helmerich & F. Raether

  2. Institut für Physikalische Chemie, W-8700, Würzburg, Marcusstrasse 9/11, FRG

    D. Peter & H. Bertagnolli

Authors
  1. A. Helmerich
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  2. F. Raether
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  3. D. Peter
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  4. H. Bertagnolli
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Helmerich, A., Raether, F., Peter, D. et al. Structural studies on an ORMOCER system containing zirconium. J Mater Sci 29, 1388–1393 (1994). https://doi.org/10.1007/BF00975093

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  • DOI: https://doi.org/10.1007/BF00975093

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