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Chlorine-free iron-ruthenium catalyst for the water-gas shift reaction

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Abstract

We present results of studies on the activity of chlorine-free iron-ruthenium catalysts in the water-gas shift reaction. The catalysts were prepared by impregnation of calcination products of α-, β-, γ-, δ-iron oxide-hydroxides with Ru3(CO)12. For two iron oxides (from α- and δ-FeOOH) the reaction rate constants are considerably higher than those of reactions with other catalysts based on RuCl3. Among the catalysts used, those obtained by impregnation of δ-FeOOH calcination product with Ru3(CO)12 appeared to be the most active.

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Authors and Affiliations

  1. Department of Kinetics and Catalysis, Faculty of Chemistry, Adam Mickiewicz University, ul. Grunwaldzka6, 60-780, Poznań, Poland

    Anna Basińska & Florian Domka

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  1. Anna Basińska
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  2. Florian Domka
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Basińska, A., Domka, F. Chlorine-free iron-ruthenium catalyst for the water-gas shift reaction. Catal Lett 22, 327–331 (1993). https://doi.org/10.1007/BF00807240

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