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Chemical interactions between 2-mercaptobenzazoles and π-acceptors

Chemische Wechselwirkungen zwischen 2-Mercaptobenzazolen und π-Akzeptoren

  • Anorganische Und Physikalische Chemie
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Summary

2-Mercaptobenzazoles (1a–c) interact with several π-acceptors such as tetracyanoethylene (TCNE) 2,3-dichloro-5,6-dicyano-1,4-benzoquinone (DDQ), 2,3,5,6-tetrachloro-1,4-benzoquinone (CHL) dicyanomethyleneindane-1,3-dione (CNIND), 2,3-dicyano-1,4-naphthoquinone (DCNQ), 9-dicyanomethylene-2,4,7-trinitrofluorene (DTF), and 2,3-dichloro-1,4-naphthoquinone (DCHNQ)via the formation of charge-transfer (CT) complexes to yield various heterocyclic compounds.

Zusammenfassung

Die 2-Mercaptobenzazole1a–c reagieren mit verschiedenen π-Akzeptoren wie Tetracyanoethylen (TCNE), 2,3-Dichlor-5,6-dicyano-1,4-benzochinon (DDQ), 2,3,5,6-Tetrachlor-1,4-benzochinon (CHL), Dicyanomethylenindan-1,3-dion (CNIND), 2,3-Dicyano-1,4-naphthochinon (DCNQ), 9-Dicyanomethylen-2,4,7-trinitrofluoren (DTF) und 2,3-Dichlor-1,4-naphthochinon (DCHNQ) unter Ausbildung von charge transfer — Komplexen (CT) zu heterocyclischen Verbindungen.

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Authors and Affiliations

  1. Chemistry Department, Faculty of Science, El-Minia University, El-Minia, Egypt

    A. A. Hassan, N. K. Mohamed, B. A. Ali & A. E. Mourad

  2. Chemistry Department, Faculty of Science, Suez Canal University, Ismailia, Egypt

    E. H. El-Tamany

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  1. A. A. Hassan
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  2. N. K. Mohamed
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  3. E. H. El-Tamany
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  4. B. A. Ali
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  5. A. E. Mourad
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Hassan, A.A., Mohamed, N.K., El-Tamany, E.H. et al. Chemical interactions between 2-mercaptobenzazoles and π-acceptors. Monatsh Chem 126, 653–662 (1995). https://doi.org/10.1007/BF00807155

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