Abstract
Hydroxyapatite modified with lead catalyzes the oxidative dehydrogenation of methane with high selectivity to C2 compounds at reaction temperatures as low as 700 °C. The activity is stabilized after reduction in the surface area of the catalyst during the reaction.
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Y. Amenomiya, V.I. Birss, M. Goledzinowski, J. Galuszka and A.R. Sanger, Catal. Rev.-Sci. Eng. 32 (1984) 163.
G.E. Keller and M.M. Bhasin, J. Catal. 73 (1982) 9.
W. Hinsen, W. Bytyn and M. Baerns,Proc. 8th Int. Congr. on Catalysis, Berlin 1984, Vol. 3 (1984) p. 581.
K. Asami, S. Hashimoto, T. Shikada, K. Fujimoto and H. Tominaga, Chem. Lett. (1986) 1233.
W. Bytyn and M. Baerns, Appl. Catal. 28 (1986) 199.
K. Asami, S. Hashimoto, T. Shikada, K. Fujimoto and H. Tominaga, Ind. Eng. Chem. Res. 26 (1987) 1485.
H.J.F. Doval, O.A. Scelza and A.A. Castro, React. Kinet. Catal. Lett. 34 (1987) 143.
J.P. Bartek, J.M. Hupp, J.F. Brazdil and R.K. Grasselli, Catal. Today 3 (1988) 117.
K. Aika and T. Nishiyama,Proc. 9th Int. Congr. on Catalysis, Calgary 1988, Vol. 2 (1988) p. 907.
K. Fujimoto, S. Hashimoto, K. Asami, K. Omata and H. Tominaga, Appl. Catal. 50 (1989) 223.
K.J. Smith, T.M. Painter and J. Galuszka,Preprints 11th Canadian Symp. on Catalysis, Halifax, July 15–18 (1990) p. 18.
S.K. Agarwal, R.A. Migone and G. Marcelin, J. Catal. 121 (1990) 110.
J.A. Roos, A.G. Bakker, H. Bosch, J.G. van Ommen and J.R.H. Ross, Catal. Today 1 (1987) 133.
J.A.S.P. Carreiro and M. Baerns, React. Kinet. Catal. Lett. 35 (1987) 349.
J.A.S. Bett, L.G. Christner and W.K. Hall, J. Catal. 13 (1969) 332.
C.L. Kibby and W.K. Hall, J. Catal. 29 (1973) 144.
C.L. Kibby and W.K. Hall, J. Catal. 31 (1973) 65.
H. Monma, J. Catal. 75 (1982) 200.
Y. Imizu, M. Kadoya and H. Abe, Chem. Lett. (1982) 415.
Y. Izumi, S. Sato and K. Urabe, Chem. Lett. (1983) 1649.
T. Suzuki, T. Hatsushika and Y. Hayakawa, J. Chem. Soc. Faraday Trans. I 77 (1981) 1059.
T. Suzuki, T. Hatsushika and M. Miyake, J. Chem. Soc. Faraday Trans. I 78 (1982) 3605.
A. Bigi, M. Gandolfi, M. Gazzano, A. Ripamonti, N. Roveri and S.A. Thomas, J. Chem. Soc. Dalton Trans. (1991) 2883.
E. Hayek and H. Newesely, Inorg. Syn. 7 (1963) 63.
J.V. Smith, ed.,Index (Inorganic) to the Powder Diffraction File, ASTM Publication No. PDIS-16i Pa (1966).
J.A.S. Bett, K.G. Christner and W.K. Hall, J. Am. Chem. Soc. 89 (1967) 5335.
H. Monma, S. Ueno and T. Kanazawa, J. Chem. Tech. Biotechnol. 31 (1981) 15.
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Matsumura, Y., Moffat, J.B. Catalytic oxidative coupling of methane over hydroxyapatite modified with lead. Catal Lett 17, 197–204 (1993). https://doi.org/10.1007/BF00766142
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DOI: https://doi.org/10.1007/BF00766142