Abstract
Amino-functionalized latex particles were obtained batchwise by emulsion copolymerization of styrene and vinylbenzylamine hydrochloride (VBAH) in the presence of 2-2′-Azobis(2-amidinopropane) HCl (V50). Size monodispersity of the particles was improved by using divinylbenzene (DVB) as a third monomer at a 2% molar ratio. Surface amino group titration was performed spectrometrically with N-succinimidyl 3-(2 pyridyldithio)propionate (SPDP). The yields of functional monomer incorporation were up to 85%.
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References
Bangs LB, “Uniform Latex Particles”, Technical notes Seradyn.
Rhône-Poulenc Estapor “Diagnostic” booklet, and references there in.
Sanderson CJ, Wilson DV (1971) Immunology 20:1061
Charreyre MT, Razafindrakoto V, Véron L, Delair Th, Pichot Ch (1994) Die Makromolekulare chem. (in press)
French patent (1991) 91:06068, inv. Th. Delair.
Delair Th, Pichot C, Mandrand B (1994) Colloid Polym Sci (in press).
Kobayashi K, Sumitomo H, Ina Y (1983) Polymer Journal 15:667
Ngo TT (1986) Journal of Biochemical and Biophysical Methods 12:349
Juang MS, Krieger IM (1976) J Polym Sci, Polym Chem Edn. 14:2089
Liu LJ, Krieger IM (1981) J Polym Sci, Polym Chem Edn. 19:3013
Ohtsuka Y, Kawaguchi H, Hagashi S (1981) Polymer 22:658
Brouwer WM, Van Der Vegt M, Van Haeren P (1990) Eur Polym J 26:35
Kim JH, Chainey M, El-Aasser M, Vanderhoff JW (1989) J Polym Sci A27:3187
Goodwin JW, Ottewill RH, Pelton R (1979) Colloid Polym Sci 257:61
Fitch RM, (1973) Br Polym J, 5:467
Graillat C, Pichot C, Guyot A (1991) Colloids and Surfaces, 56:189
Verrier-Charleux B, Graillat C, Chevalier Y, Pichot C, Revillon A (1991) Colloid Polym Sci 269:398
Ford WT, Yu H, Lee JJ, El-Hamshary H (1993) Langmuir, 9:1698
Van Streun KH, Belt WJ, Piet P, German AL (1991) Eur Polym J, 27:931
Guthrie WH, (1985) PhD Dissertation, Lehigh University
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Delair, T., Marguet, V., Pichot, C. et al. Synthesis and characterization of cationic amino functionalized polystyrene latexes. Colloid Polym Sci 272, 962–970 (1994). https://doi.org/10.1007/BF00658894
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DOI: https://doi.org/10.1007/BF00658894