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Physico-chemical properties of charge transfer complexes of ferrocene and 1,1′-dimethylferrocene in methanol and cyclohexane

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Summary

In liquid systems, ferrocene and its 1,1′-dimethyl derivative, (MeCp)2Fe, give charge transfer complexes with C(NO2)4 in which the metallocene is an electron donor. The spectral absorption maxima of the complexes were established and the values of their molar extinction coefficients, εCT, equilibrium constants, K, and heats of formation, ΔH∘, were determined.

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Authors and Affiliations

  1. Photochemistry Laboratory, Institute of Chemistry, A. Mickiewicz University, 60-780, Poznań, Poland

    Anna Jaworska-Augustyniak

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  1. Anna Jaworska-Augustyniak
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Jaworska-Augustyniak, A. Physico-chemical properties of charge transfer complexes of ferrocene and 1,1′-dimethylferrocene in methanol and cyclohexane. Transition Met Chem 6, 100–103 (1981). https://doi.org/10.1007/BF00626116

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  • DOI: https://doi.org/10.1007/BF00626116

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