Skip to main content
Log in

Segregant-enhanced fracture in magnesium oxide

  • Published:
Journal of Materials Science Aims and scope Submit manuscript

Abstract

The fracture toughness of MgO has been studied as a function of the concentration of an intergranular LiF phase, added to enhance densification. The fracture toughness increases as lithium and fluorine are volatilized from the MgO while the fracture morphology changes from intergranular to transgranular. The data are interpreted with respect to competing embrittlement and crack-deflection toughening mechanisms, and a scheme is proposed for determining conditions for embrittlement and toughening.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. J. H. Westbrook andD. L. Wood,Nature 192 (1961) 1280.

    Google Scholar 

  2. C. J. McMahon Jr,Mater. Sci. Engng 42 (1980) 215.

    Google Scholar 

  3. M. H. Leipold,J. Amer. Ceram. Soc. 49 (1966) 498.

    Google Scholar 

  4. J. R. H. Black andW. D. Kingery,ibid. 62 (1979) 176.

    Google Scholar 

  5. Y. M. Chiang, A. F. Henriksen andW. D. Kingery,ibid. 64 (1981) 385.

    Google Scholar 

  6. H. L. Marcus andM.E. Fine,ibid. 55 (1972) 568.

    Google Scholar 

  7. W. C. Johnson andD. F. Stein,ibid. 58 (1975) 485.

    Google Scholar 

  8. A. W. Funkenbusch andD. W. Smith,Metall. Trans. 6A (1975) 2299.

    Google Scholar 

  9. R. S. Jupp, D. F. Stein andD. W. Smith.J. Mater. Sci. 15 (1980) 96.

    Google Scholar 

  10. G. Dewith andN. Hattu,ibid. 16 (1981) 841.

    Google Scholar 

  11. A. G. Evans, D. Gilling andR. W. Davidge,ibid. 5 (1970) 187.

    Google Scholar 

  12. R. W. Rice,Proc. Br. Ceram. Soc. 20 (1972) 329.

    Google Scholar 

  13. K. T. Faber andA. G. Evans,Acta Metall. 31 (1983) 565.

    Google Scholar 

  14. Idem,,J. Amer. Ceram. Soc. 66 (1983) C-94.

    Google Scholar 

  15. D. W. Johnson Jr., E. M. Vogel andB. B. Ghate, in “Ferrites”, edited by H. Watanabe, S. Iida and M. Sugimoto (Center for Academic Publications, Japan, 1980) p. 285.

    Google Scholar 

  16. G. K. Bansal andA. H. Heuer, in “Fracture Mechanics of Ceramics”, Vol. 2, edited by R. C. Bradt, D. P. H. Hasselman and F. F. Lange (Plenum, New York, 1974) p. 677.

    Google Scholar 

  17. M. I. Mendelson andM. E. Fine,J. Amer. Ceram. Soc. 57 (1974) 154.

    Google Scholar 

  18. R. W. Rice,Proc. Br. Ceram. Soc. 12 (1969) 99.

    Google Scholar 

  19. G. D., Miles et al., Trans. Br. Ceram. Soc. 66 (1967) 319.

    Google Scholar 

  20. M. W. Benecke, N. E. Olson andJ. A. Pask,J. Amer. Ceram. Soc. 50 (1967) 365.

    Google Scholar 

  21. P. E. Hart, R. B. Atkin andJ. A. Pask,ibid. 53 (1970) 83.

    Google Scholar 

  22. P. Chantikul et al., ibid. 64 (1981) 539.

    Google Scholar 

  23. D. B. Marshall, T. Noma andA. G. Evans,ibid. 65 (1982) C-175.

    Google Scholar 

  24. J. M. Haussonne et al., ibid. 66 (1983) 801.

    Google Scholar 

  25. W. C. Johnson, D. F. Stein andR. W. Rice,ibid. 57 (1974) 342.

    Google Scholar 

  26. L. Navias,ibid. 19 (1936) 1.

    Google Scholar 

  27. B. Henderson andJ. E. Wertz,Adv. Phys. 17 (1968) 749.

    Google Scholar 

  28. A. G. Evans andR. W. Davidge,Phil. Mag. 20 (1969) 373.

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Rights and permissions

Reprints and permissions

About this article

Cite this article

Conner, C.L., Faber, K.T. Segregant-enhanced fracture in magnesium oxide. J Mater Sci 25, 2737–2742 (1990). https://doi.org/10.1007/BF00584873

Download citation

  • Received:

  • Accepted:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF00584873

Keywords

Navigation