Skip to main content
Log in

Relationship between activation energies for the thermal oxidation of metals and the semiconductivity of the oxides

  • Papers
  • Published:
Journal of Materials Science Aims and scope Submit manuscript

Abstract

The activation energies for the thermal oxidation of metals appear to be inversely related to the band gaps, heats of formation per equivalent and the electronic conductivity of the oxides formed. An attempt is made to develop the theoretical significance of these correlations in the context of a general discussion of some fundamental aspects of the thermal and the anodic oxidation of metals.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. E. K. Rideal andO. H. Wansbrough-Jones,Proc. Roy. Soc. (London) A123 (1929) 202.

    Google Scholar 

  2. A. F. H. Ward andN. R. Bharucha,Rec. Trav. Chim. Pays-Bas 72 (1953) 735.

    Google Scholar 

  3. A. K. Vijh, “Electrochemistry of Metals and Semiconductors” (Marcel Dekker, New York, 1973).

    Google Scholar 

  4. Idem, in “Oxides and Oxide Films”, Vol. 2, edited by J. W. Diggle (Marcel Dekker, New York, 1973).

    Google Scholar 

  5. L. Young, “Anodic Oxide Films” (Academic Press, New York, 1961).

    Google Scholar 

  6. T. P. Hoar, in “Modern Aspects of Electrochemistry”, Vol. 2, edited by J. O'M. Bockris (Butterworths, London, 1959).

    Google Scholar 

  7. J. W. Diggle, T. C. Downie andC. W. Goulding,Chem. Rev. 69 (1969) 365.

    Google Scholar 

  8. F. J. Burger andL. Young, in “Progress in Dielectrics”, Vol. 5 (Heywood, London, 1962).

    Google Scholar 

  9. A. K. Vijh,J. Mater. Sci. 5 (1970) 379.

    Google Scholar 

  10. J. L. Ord andF. C. Ho,J. Electrochem. Soc. 118 (1971) 46.

    Google Scholar 

  11. A. K. Vijh,J. Mater. Sci. 8 (1973) 1669.

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Rights and permissions

Reprints and permissions

About this article

Cite this article

Vijh, A.K. Relationship between activation energies for the thermal oxidation of metals and the semiconductivity of the oxides. J Mater Sci 9, 985–988 (1974). https://doi.org/10.1007/BF00570393

Download citation

  • Received:

  • Accepted:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF00570393

Keywords

Navigation