Skip to main content
Log in

Titanium dioxide plasma treatment

  • Published:
Plasma Chemistry and Plasma Processing Aims and scope Submit manuscript

Abstract

After a review of the literature on titanium production under plasma conditions, the main parameters controlling the reactions (residence time, type and relative quantity of reducer, reaction temperature, etc.) are emphasized. The controlled-atmosphere chamber where the rutile or anatase particles are heated and partly reduced in a crucible by a d.c. plasma torch with Ar-H2 as plasma gas is described. Study of the temperature dependence of the Gibbs free energy allows one to explain, at least qualitatively, the experimental results obtained which correspond at best to 10% (weight) of TiO2 reduced to TiO by carbon.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. R. Ishizuka and K. Akashi, “The reduction of ilmenite in a direct current plasma arc,” Int. Round Table on Stud. Transp. Phenom., Odeillo, France (1975).

    Google Scholar 

  2. W. Trebiatowski and A. Czernichowski, “Décomposition d'ilménite dans un plasma d'azote,”Nukleonika XI, No. 12 (1967).

  3. R. A. S. Brown, “Treatment of ilmenite ore in a plasma jet reactor,”Can. Metall. Q. 10, 47 (1976).

    Google Scholar 

  4. W. Chase and J. L. Skrivan, “Plasma jet process for beneficiation of titaniferous ores,”AIChE Symp. Ser. 75, 38, 186 (1979).

    Google Scholar 

  5. M. B. Ouida, “Traitement thermique à haute température de minerais à base d'ilménite,” Thèse de 3ème cycle, Orsay (1977).

  6. C. Bonet, M. Foex, and M. B. Ouiada, “Traitement thermique de minerais à base d'ilménite dans un four à plasma,” IIIrd Int. Symp. on Plasma Chem. IUPAC, Limoges, France (1977).

    Google Scholar 

  7. A. Czernichowski, J. Jurewicz, and W. Kukielo, “Etude de la réduction du bioxyde de titane dans un plasma contenant de l'hydrogène,” III Symp. Int. Chimie des Plasmas IUPAC, Limoges, France (1977).

    Google Scholar 

  8. McLaughlin, “Plasma reduction of titanium dioxide,” US Patent 3,429,691 (1979).

  9. K. Hartl, “Zur Kauntnis flüchtiger suboxide,”Ber. Dtsch. Keram. Ges. 45, 355 (1968).

    Google Scholar 

  10. Stockes, U.S. Dept. of Commerce, Clearing House for Scientific and Technical Information, A.D. 625,591, 32 p. (1964), 65, 47.85b.

  11. K. Akashi, S. Ohno, R. Ishizuka, and T. Yoshida, “The characteristics of titanium microcrystals formed from a mixture of titanium tetrachloride and hydrogen in an argon plasma jet,” IUPAC, Limoges, France (1977).

    Google Scholar 

  12. K. Akashi, M. Niskimu, and R. Ishizuka, “The vapor phase reaction in plasma jet augmented by an inductive coupling of r.f. power with d.c. arc,” Conf. Proc., 4th Int. Symp. Plasma Chem. Zurich (1979), Vol. 1, p. 224.

  13. N. N. Rykalin, I. D. Kulagin, and A. B. Gugnyak, “Gas induction plasma heating and prospects of its industrial use,” IUPAC, Odeillo (1975).

    Google Scholar 

  14. N. N. Rykalin, “Plasma engineering in metallurgy and inorganic materials technology,”Pure Appl. Chem. 48, 179 (1976).

    Google Scholar 

  15. H. R. P. Schoumaker, “Four à plasma,” Données d'exploitation, application: U.I.E., VII (1972).

  16. H. Takei and U. Ishigami, “Hollow cathode discharge melting of Ti-6A1-4V and Nb-56Ti-3.3.Zr alloys,”J. Vac. Sci. Technol. 8, 123 (1971).

    Article  Google Scholar 

  17. S. Kashu, S. Nishino, and S. Hayashi, “Hollow cathode melting,” Trans. Int. Conf. Vac. Metall., Tokyo (1967), p. 771.

  18. T. Fujiward, K. Yamaguchi, K. Ohno and H. Yamada, “Development of a new plasma melting furnace of titanium and other metals,” Central Research Laboratory, Research and Development Division, Daído Steel, Co. Ltd., Negoya, Japan (1980).

    Google Scholar 

  19. J. Yamada, K. Yoshida, and T. Shimiza, “Development of plasma arc melting of titanium,” Proc. 7th ICVM (1982), Tokyo, Japan.

  20. N. N. Rykalin,Pure Appl. Chem. 48, 179 (1976);52, 1801 (1980).

    Google Scholar 

  21. P. Fauchais, E. Bourdin, and J. F. Coudert, “Généralités sur les traitements physiques et chimiques en plasma thermique,”Actual. Chim. 10, 15 (1981).

    Google Scholar 

  22. C. Bonet,Pure Appl. Chem. 52, 1707 (1980).

    Google Scholar 

  23. A. Vardelle, P. Fauchais, and M. Vardelle, “Projection de revêtements protecteurs par plasma,”Actual. Chim. 10, 69 (1981).

    Google Scholar 

  24. K. A. Buting, “Production of titanium by plasma process,” 5th International Symposium on Plasma Chemistry, Edinburgh, England, August (1981), Proceedings, p. 179, B. Waldie, ed., Univ. of Edinburgh.

  25. D. Degout, “Contribution à l'étude du traitement par plasma d'arc des composés TiO2, FeO, TiO2, et TiCl4” Thèse de 3ème cycle, Université de Limoges, December (1982).

  26. L. Landau and E. Lifchitz,Mécanique des fluides, MIR, Moscow (1971).

    MATH  Google Scholar 

  27. M. Vardelle, A. Vardelle, P. Fauchais, and M. I. Boulos,AIChE J. 29, 236 (1983).

    Article  Google Scholar 

  28. E. Bourdin, P. Fauchais, and M. I. Boulos,Int. J. Heat Mass Transfer 26, 567 (1983).

    Article  Google Scholar 

  29. Technique de l'Ingénieur, Volume Métallurgie (Tomes, 1, 2 et 3) mise à jour permanente (1982), 21 rue Canette Paris 6ème (1957).

  30. D. L. Baulch, “High-temperature reaction rates,” Data No. 4, Leeds (1969).

  31. J.A.N.A.F. Thermochemical Tables, Dow Chemical Co., Midland, Michigan (1966).

    Google Scholar 

  32. B. J. McBride and S. Gordon, Fortran IV program for calculation of thermodynamic data,” NASA-TN-D-4097 (1967).

  33. I. Barin and D. Knacke,Thermochemical Properties of Inorganic Substances, Springer Verlag, Berlin (1973).

    Google Scholar 

  34. E. Bourdin, “Contribution à l'étude théorique et expérimentale de nitrures et d'oxynitrures par réaction de jets de plasma d'azote avec des poudres d'aluminium et de silicium,” Thèse de 3éme cycle, Limoges (1976).

  35. J. Amouroux, J. L. Codron, and D. Morvan,Ann. Chim. 3, 59 (1978).

    Google Scholar 

  36. E. Bourdin, J. Aubreton and P. Fauchais, “Equilibrium composition and thermodynamic properties of C-H2, CH4, and CH4-H2 plasmas; computation of their reducing action on iron oxide Fe2O3,” ISPC 3, Limoges, juillet (1977), Proceedings III G.4.2.

Download references

Author information

Authors and Affiliations

Authors

Rights and permissions

Reprints and permissions

About this article

Cite this article

Degout, D., Kassabji, F. & Fauchais, P. Titanium dioxide plasma treatment. Plasma Chem Plasma Process 4, 179–198 (1984). https://doi.org/10.1007/BF00566840

Download citation

  • Received:

  • Revised:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF00566840

Key words

Navigation