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Measurements of the compressibility and sound velocity in methane up to 1 GPa, revisited

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Abstract

New density measurements of methane (CH4) at 298.15 K up to 1 GPa are reported. The precision of the measurements is 0.03%, while the estimated accuracy is between 0.05 and 0.1%. Velocities of sound have been remeasured between 148.15 and 298.15 K at intervals of 25 K and at pressures up to 1 GPa, with an estimated accuracy of 0.12% at 100 M Pa, 0.10% at 150 MPa, and 0.08% above 150 MPa. Comparisons with experimental results and equations of state of other workers are presented. The isothermal and the adiabatic compressibility and the ratio of specific heats have been calculated at 298.15 K.

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References

  1. P. J. Kortbeek, S. N. Biswas, and N. J. Trappeniers, Physica 139/140:109 (1986).

    Google Scholar 

  2. N. J. Trappeniers, T. Wassenaar, and J. C. Abels, Physica 98A:289 (1979).

    Google Scholar 

  3. S. L. Robertson and S. E. Babb, Jr., J. Chem. Phys. 51:1357 (1969).

    Google Scholar 

  4. E. C. Morris, Int. J. Thermophys. 5:281 (1984).

    Google Scholar 

  5. L. L. Pitaevskaya and A. V. Bilevich, Russ. J. Phys. Chem. 46:1390 (1972).

    Google Scholar 

  6. A. Lacam, J. Rech. Centre Natt. Rech. Sci. 34:25 (1956).

    Google Scholar 

  7. U. Setzmann and W. Wagner, A preliminary fundamental equation for methane. Private communication (1988).

  8. S. N. Biswas, N. J. Trappeniers, P. J. Kortbeek, and C. A. ten Seldam, Rev. Sci. Instr. 9:103 (1988).

    Google Scholar 

  9. S. N. Biswas, J. J. van de Ridder, and C. A. ten Seldam, Rev. Sci. Instr., in press.

  10. J. A. Schouten, J. P. J. Michels, C. Prins, P. van der Gulik, and N. J. Trappeniers, Development of an Equation of State for the University of Amsterdam, The Netherlands (May 1984).

  11. R. Kleinrahm, W. Duschek, W. Wagner, and M. Jaeschke, J. Chem. Thermodyn. 20:621 (1988).

    Google Scholar 

  12. P. J. Kortbeek, M. J. P. Muringer, N. J. Trappeniers, and S. N. Biswas, Rev. Sci. Instr. 56:1269 (1985).

    Google Scholar 

  13. P. J. Kortbeek, N. J. Trappeniers, and S. N. Biswas, Int. J. Thermophys. 9:103 (1988).

    Google Scholar 

  14. P. J. Kortbeek, J. J. van de Ridder, S. N. Biswas, and J. A. Schouten, Int. J. Thermophys. 9:425 (1988).

    Google Scholar 

  15. P. J. Kortbeek, S. N. Biswas, and J. A. Schouten, Int. J. Thermophys. 9:803 (1988).

    Google Scholar 

  16. R. Verbrugge, J. A. Schouten, W. J. Schuijlenburg, and P. J. Kortbeek, Rev. Sci. Instr. 60:1345 (1989).

    Google Scholar 

  17. B. A. Younglove and J. F. Ely, J. Phys. Chem. Ref. Data 16:577 (1987).

    Google Scholar 

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Kortbeek, P.J., Schouten, J.A. Measurements of the compressibility and sound velocity in methane up to 1 GPa, revisited. Int J Thermophys 11, 455–466 (1990). https://doi.org/10.1007/BF00500838

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  • DOI: https://doi.org/10.1007/BF00500838

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