Skip to main content
SpringerLink
Log in

Continuous and time-resolved luminescence spectroscopy of sulfonatoporphyrin dopants in sol-gel hosts

Code: FP7

  • Published:
Journal of Sol-Gel Science and Technology Aims and scope Submit manuscript

Abstract

Organic chromophores are of interest for use in remote luminescent chemical sensor applications, as they can be highly sensitive to conditions such as oxygen concentration, pH, temperature, metal ion activity, etc. Small fluctuations in local environmental parameters can lead to substantial perturbations in the optical properties of select organic probe molecules. Lifetime studies were performed on the S1 emission of tetra-4-sulfonatophenylporphyrin and the zinc (II) and cadmium (II) adducts in sol-gel derived aluminosilicate hosts. Vibronically-coupled quenching was observed to occur as a function of the complexed transition metal ion.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Gouterman, M., in The Porphyrins, Physical Chemistry, Part A, ed. D. Dolphin (Academic Press, New York, 1978).

    Google Scholar 

  2. Perry, J.W., Khundkar, L.R., Coulter, D.R., Alvarez, D., Marder, S.R., Jr., Wei, T.H., Sence, M.J., Van Stryland, E.W., and Hagan, D.J., in Optical Molecules for Nonlinear Optics and Photonics, NATO Advanced Study Institute, Ser. E: Applied Sciences Vol. 194, eds. J. Messier, F. Kajzar, and P. Prasad (Kluwer Academic, Dordrecht, 1991) p. 369.

    Google Scholar 

  3. Berezin, B.D., Coordination Compounds of Porphyrins and Pthalocyanines (John Wiley and Sons, Chichester, 1981) p. 59.

    Google Scholar 

  4. Pouxviel, J.C., Boilot, J.P., Dauger, A., and Huber, L., in Better Ceramics Through Chemistry II, eds. C.J. Brinker, D.E. Clark, and D.R. Ulrich (Materials Research Society, Pittsburgh, 1986) p. 270.

    Google Scholar 

  5. Perry, J.W., Khundkar, L.R., Coulter, D.R., Alvarez, D., Marder, S.R., Jr., Wei, T.H., Sence, M.J., Van Stryland, E.W., and Hagan, D.J., in Optical Molecules for Nonlinear Optics and Photonics, NATO Advanced Study Institute, Ser. E: Applied Sciences Vol. 194, eds. J. Messier, F. Kajzar, and P. Prasad (Kluwer Academic, Dordrecht, 1991), p. 376.

    Google Scholar 

  6. Kobayashi, H. and Kaizusin, Y., in Porphyrins: Excited State Dynamics (American Chemical Society, Washington, D.C. 1986) p. 106.

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Department of Chemistry and the University Center for Laser Research, Oklahoma State University, 74078-0447, Stillwater, OK, USA

    L. M. Yates III, X. -J. Wang & E. T. Knobbe

Authors
  1. L. M. Yates III
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. X. -J. Wang
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. E. T. Knobbe
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Yates, L.M., Wang, X.J. & Knobbe, E.T. Continuous and time-resolved luminescence spectroscopy of sulfonatoporphyrin dopants in sol-gel hosts. J Sol-Gel Sci Technol 2, 745–749 (1994). https://doi.org/10.1007/BF00486342

Download citation

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF00486342

Keywords

Search

Navigation