Skip to main content
SpringerLink
Log in

Determination of cobalt in the presence of high concentrations of zinc by differential pulse polarography

Cobaltbestimmung in Gegenwart hoher Zinkkonzentrationen mit Hilfe der Differential-Puls-Polarographie

  • Original Papers
  • Trace Element Analysis
  • Published:
Fresenius' Zeitschrift für analytische Chemie Aims and scope Submit manuscript

Summary

Cobalt(II) can be determined in 0.1 mol/l Na3citrate + 0.1 mol/l NH4Cl + 0.08% dimethylglyoxime as supporting electrolyte in the presence of a 50 000-fold excess of zinc by differential pulse polarography. The limit of determination is 4.2×10−5 mol/l Co (2.5 mg/l). Linear calibration curves are obtained within the range of 1×10−7 to 5×10−6 mol/l cobalt without zinc and in the presence of 5×10−3 mol/l Zn. The analytical method developed is suitable for the determination of cobalt in zinc plant solutions.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Brainina KZ, Krapivkina TA (1967) Zh Anal Khim 22:1382

    Google Scholar 

  2. Brainina KZ (1972) Stripping voltammetry in chemical analysis. John Wiley and Sons, New York Toronto

    Google Scholar 

  3. Chen H, Neeb R (1983) Fresenius Z Anl Chem 314:657–659

    Google Scholar 

  4. Da Maia RC (1984) Diplomarbeit, Bergakademie Freiberg, GDR

    Google Scholar 

  5. Gei\ler M, Kuhnhardt C, Lehmann R (1966) Reinststoffanalytik. Akademie-Verlag Berlin, pp 593–603

    Google Scholar 

  6. Gei\ler M, Kuhnhardt C (1970) Square-wave-Polarographie. VEB Deutscher Verlag für Grundstoffindustrie, Leipzig, pp 105–106

    Google Scholar 

  7. Gemmer-Colos V, Scollary G, Neeb R (1982) Fresenius Z Anal Chem 312:412–413

    Google Scholar 

  8. Krapivkina TA, Brainina KZ (1970) Zavodsk Laborat 36:3

    Google Scholar 

  9. Meyer A, Neeb R (1983) Fresenius Z Anal Chem 315:118–120

    Google Scholar 

  10. Müller GO (1971) Quantitativ-anorganisches Praktikum, Band III. S. Hirzel Verlag, Leipzig, p 368

    Google Scholar 

  11. Nangniot PJ (1967) J Electroanal Chem 14:197

    Google Scholar 

  12. Pihlar B, Valenta P, Nürnberg HW (1981) Fresenius Z Anal Chem 307:337–346

    Google Scholar 

  13. Pilkington ES, Weeks CH, Bond AM (1976) Anal Chem 48:1665–1669

    Google Scholar 

  14. TGL 8601, Bestimmung des Cobaltgehaltes in Zinksulfat technisch (1986) p 11

  15. Uchida T, Sugawara M, Kambara T (1983) Fresenius Z Anal Chem 315:487–490

    Google Scholar 

  16. Weinzierl J, Umland F (1982) Fresenius Z Anal Chem 312:608–610

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Division of the VEB Mansfeld Kombinat, Research Institute for Non-ferrous Metals, DDR-9200, Freiberg, German Democratic Republic

    Manfred Gei\ler

  2. Academy of Mining, DDR-9200, Freiberg, German Democratic Republic

    Rui Da Maia

Authors
  1. Manfred Gei\ler
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Rui Da Maia
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Gei\ler, M., Da Maia, R. Determination of cobalt in the presence of high concentrations of zinc by differential pulse polarography. Z. Anal. Chem. 330, 624–626 (1988). https://doi.org/10.1007/BF00473780

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF00473780

Keywords

Search

Navigation