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Analysis of the displacement vectors of antiphase domain boundaries in anorthites (CaAl2Si2O8)

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Abstract

As part of an electron microscopic study of plagioclase, displacement vectors for b- and c-domains have been determined from contrast experiments and calculations. In lunar anorthite from breccia 15459 (An 94.9), b-domains could be imaged in dark field with b-reflections and c-domains with c-reflections. The vector corresponding to these contrast conditions is 1/2[110] for b-domains and 1/2[111] for c-domains. The face centering vector 1/2 [110] relates two domains with a reverse Al/Si arrangement. The body-centering vector 1/2[111] relates domains of identical Al/Si distribution but different atomic coordinates. Fringe patterns for c-domains have been obtained for Pasmeda anorthite. Calculated intensity profiles applying multi-beam dynamic theory and a 1/2[111] displacement vector are in agreement with the observations.

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References

  • Amelinckx, S.: The study of planar interfaces by means of electron microscopy. In: Modern diffraction and imaging techniques in material science (S. Amelinckx, R. Gevers, G. Remaut, J. Van Landuyt, eds.), p. 257–294. Amsterdam-London: North Holland Publ. Co. 1970.

    Google Scholar 

  • Barber, D. J.: Thin foil of non-metals made for electron microscopy by sputter-etching. J. Mat. Sci. 5, 1–8 (1970).

    Google Scholar 

  • Bouchard, M., Worthington, W. L., Jurica, D. J., Swann, P. R.: A high angle tilting stage for the 650 kV Hitachi microscope. Rev. Sci. Instr. (1973, in press).

  • Christie, J. M., Lally, J. S., Heuer, A. H., Fisher, R. M., Griggs, D. T., Radcliffe, S. V.: Comparative electron petrography of Apollo 11, Apollo 12 and terrestrial rocks. Proc. Second Lunar Sci. Conf. Geochim. Cosmochim. Acta, Suppl. 2, 1, 69–89 (1971).

    Google Scholar 

  • Czank, M., Schulz, H., Laves, F., Gross, W.: Investigation of domains in anorthite by electron microscopy. Naturwissenschaften 59, 77–78 (1972).

    Google Scholar 

  • Czank, M., Van Landuyt, J., Schulz, H., Laves, F., Amelinckx, S.: Temperature dependence of domains in anorthite. Naturwissenschaften 59, 646 (1972).

    Google Scholar 

  • Gay, P.: The structures of plagioclase feldspars: III. An X-ray study of anorthites and bytownites. Mineral Mag. 30, 169–177 (1953).

    Google Scholar 

  • Goldsmith, J. R., Laves, F.: Cation order in anorthite (CaAl2Si2O8) as revealed by Gallium and Germanium substitutions. Z. Krist. 106, 213–226 (1955).

    Google Scholar 

  • Heuer, A. H., Lally, J. S., Christie, J. M., Radcliffe, S. V.: On phase transformations and exsolution in lunar and terrestrial plagioclases. Phil. Mag. 26, 465–482 (1972).

    Google Scholar 

  • Hirsch, P. B., Howie, A., Nicholson, R. B., Pashley, D. W., Whelan, M. J.: Electron microscopy of thin crystals. London: Butterworths 1965.

    Google Scholar 

  • Kemster, C. J. E., Megaw, H. D., Radoslovich, E. W.: The structure of anorthite, CaAl2Si2O8. I. Structure analysis. Acta Cryst. 15, 1005–1017 (1962).

    Google Scholar 

  • Lally, S., Fisher, R. M., Christie, J. M., Griggs, D. T., Heuer, A. H., Nord, G. L., Jr., Radcliffe, S. V.: Electron petrography of Apollo 14 and 15 rocks. Proc. Third Lunar Science Conf. Geochim. Cosmochim. Acta, Suppl. 3, 1, 401–422 (1972).

    Google Scholar 

  • Landuyt, J. van, Gevers, R., Amelinckx, R.: Fringe patterns at antiphase boundaries with α=π observed in the electron microscope. Phys. Stat. Sol. 7, 519–546 (1964).

    Google Scholar 

  • Laves, F., Goldsmith, J. R.: Long-range short range order in calcic plagioclases as a continuous and reversible function of temperature. Acta Cryst. 7, 465–472 (1954).

    Google Scholar 

  • Laves, F., Goldsmith, J. R.: The effect of temperature and composition on the Al-Si distribution in anorthite. Z. Krist. 106, 227–235 (1955).

    Google Scholar 

  • Marcinkowski, J. M.: Theory and direct observation of antiphase boundaries and dislocations in supperlattices. In: Electron microscopy and strength of materials (G. Thomas and J. Washburn, eds.), p. 330–440. New York: Interscience Publishers 1963.

    Google Scholar 

  • Megaw, H. D.: Order and disorder in feldspars. Norsk. Geol. Tidsskr. 42/2, 104–137 (1962).

    Google Scholar 

  • Megaw, H. D., Kempster, C. J. E., Radoslovich, E. W.: The structure of anorthite CaAl2Si2O8. II. Description and discussion. Acta Cryst. 15, 1017–1035 (1962).

    Google Scholar 

  • Müller, W. F., Wenk, H. R.: Changes in the domain structure of anorthites induced by heating. Neues Jahrb. Mineral. Mh., 17–26 (1973).

  • Müller, W. F., Wenk, H. R., Thomas, G.: Structural variations in anorthites. Contr. Mineral. and Petrol. 34, 304–314 (1972).

    Google Scholar 

  • Ribbe, P. H., Colville, A. A.: Orientation of the boundaries of out-of-step domains in anorthite. Mineral. Mag. 36, 814–819 (1968).

    Google Scholar 

  • Smith, J. V., Ribbe, P. H.: Atomic movements in plagioclase feldspars. Contr. Mineral. and Petrol. 21, 157–202 (1969).

    Google Scholar 

  • Taylor, W. H.: The structure of sanidine and other feldspars. Z. Krist. 85, 425–442 (1933).

    Google Scholar 

  • Taylor, W. H., Darbyshire, J. A., Strunz, H.: An X-ray investigation of the feldspars. Z. Krist. 87, 464–498 (1934).

    Google Scholar 

  • Wainwright, J. E., Starkey, J.: A refinement of the structure of anorthite. Z. Krist. 133, 75–80 (1971).

    Google Scholar 

  • Wenk, H. R., Ulbrich, M., Müller, W. F.: Lunar plagioclase (a mineralogical study). Proc. Third Lunar Sci. Conf. Geochim. Cosmochim. Acta, Suppl. 3, 1, 569–579 (1972).

    Google Scholar 

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Müller, W.F., Wenk, H.R., Bell, W.L. et al. Analysis of the displacement vectors of antiphase domain boundaries in anorthites (CaAl2Si2O8). Contr. Mineral. and Petrol. 40, 63–74 (1973). https://doi.org/10.1007/BF00371764

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