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Crystallization study of Bi5Ge20Se75 glass

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Abstract

Results of thermal analysis performed at different heating rates on the composition Bi5Ge20Se75 are reported and discussed. The values of crystallization temperature (T c) and the peak temperature of the crystallization (T p) were found to be dependent on the heating rates. The activation energy of crystallization E c was evaluated by five different methods. The average value of E c is equal to 119.64+ 6.97 kJ mol−1.

The crystallization data are examined in terms of recent analysis developed for non-isothermal conditions. The results indicate a two-dimensional crystal growth for the investigated composition.

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References

  1. S. R. Ovshinsky, Phys. Rev. Lett. 21 (1968) 1450.

    Article  Google Scholar 

  2. S. A. Keneman, Appl. Phys. Lett. 19 (1971) 205.

    Article  CAS  Google Scholar 

  3. H. Ngai, A. Yoshikawa, Y. Toyoshima, O. Ochi and Y. Mizvshima, Ibid. 28 (1976) 145.

    Article  Google Scholar 

  4. R. A. Street and N. F. Mott, Phys. Rev. Lett. 35 (1975) 1293.

    Article  CAS  Google Scholar 

  5. N. F. Mott, E. A. Davis and R. A. Street, Phil. Mag. 32 (1975) 961.

    Article  CAS  Google Scholar 

  6. N. Tohge, Y. Yamamoto, T. Minamiand and M. Tanakam, Appl. Phys. Lett. 34 (1979) 640.

    Article  CAS  Google Scholar 

  7. N. Tohge, T. Minami, Y. Yamamoto and Tanaka, J. Appl. Phys. 51 (1980) 1048.

    Article  CAS  Google Scholar 

  8. A. K. Agnihotri, A. Kumar and A. N. Nigam, J. Non-Cryst. Solids. 101 (1988) 127.

    Article  CAS  Google Scholar 

  9. V. Damodara Das and P. Jansi Lakshmi, Phys. Rev. B. 37 (1988) 720.

    Article  CAS  Google Scholar 

  10. K. M. Yang, Y. J. Wang and Q. Tang, J. Non-Cryst. Solids. 101 (1988) 65.

    Article  Google Scholar 

  11. M. M. Hafiz, M. M. Ibrahim, M. Dongl and F. H. Hammed, J. Appl. Phys. 54 (1983) 1950.

    Article  Google Scholar 

  12. S. Mahadevan, A. Giridhar and A. K. Singh, J. Non-Cryst. Solids. 88 (1986) 11.

    Article  CAS  Google Scholar 

  13. H. G. Kissinger, Anal. Chem. 29 (1957) 1702.

    Article  CAS  Google Scholar 

  14. N. Rysava, T. Spasov and L. Tichy, J. Thermal Analysis 32 (1987) 1015.

    Article  CAS  Google Scholar 

  15. H. Yinnon and D. R. Uhlmann, J. Non-Cryst. Solids. 54 (1983) 253.

    Article  CAS  Google Scholar 

  16. M. M. Ibrahim, S. M. El-Halawany, M. M. Hafiz and M. N. Abdel-Rahim, Egypt. J. Sol. 8 (1986) 126.

    Google Scholar 

  17. Idem., Ibid. 8 (1986) 116.

    Google Scholar 

  18. M. M. Ibrahim, and M. N. Abdel-Rahim, Physica Scripta 38 (1988) 762.

    Article  CAS  Google Scholar 

  19. M. M. Ibrahim, S. M. El-Halawany, M. M. Hafiz and M. N. Abdel-Rahim, Ind. J. Pure Appl Phys. 28 (1990) 22.

    CAS  Google Scholar 

  20. N. Afify, J. Non-Cryst. Solids 42 (1992) 247.

    Article  Google Scholar 

  21. G. O. Piloyan, I. D. Rybachikov and O. S. Novikov, Nature 212 (1966) 1229.

    Article  CAS  Google Scholar 

  22. H. J. Borchardt, J. Inorg. Nucl. Chem. 12 (1960) 252.

    Article  CAS  Google Scholar 

  23. T. Ozawa, Bull. Chem. Soc. Japan 38 (1965) 1881.

    Article  CAS  Google Scholar 

  24. H. S. Chen, J. Non-Cryst. Solids 27 (1978) 257.

    Article  CAS  Google Scholar 

  25. R. L. Takhor in “Advances in nucleation and crystallization of glasses” (American Ceramics Society, Columbus, 1972) p. 166.

    Google Scholar 

  26. H. E. Kissinger, J. Res. NBS 57 (1956) 217.

    CAS  Google Scholar 

  27. J. A. Augis and J. E. Bennett, J. Thermal Anal. 13 (1978) 283.

    Article  CAS  Google Scholar 

  28. J. Sestak, Phys. Chem. Glasses 15 (1978) 137.

    Google Scholar 

  29. K. Matusita, T. Konatsu and R. Yokota, J. Mater. Sci. 19 (1984) 291.

    Article  CAS  Google Scholar 

  30. J. Colemenero and J. M. Barandiaran, J. Non-Cryst. Solids 30 (1978) 263.

    Article  Google Scholar 

  31. R. F. Speyer and S. H. Risbud, Phys. Chem. Glasses 24 (1987) 26.

    Google Scholar 

  32. N. Tohge, T. Minami and Tanaka, J. Non-Cryst. Solids 37 (1980) 23.

    Article  CAS  Google Scholar 

Download references

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Abdel-Rahim, M.A., Abdel-Latif, A.Y., El-Korashy, A. et al. Crystallization study of Bi5Ge20Se75 glass. JOURNAL OF MATERIALS SCIENCE 30, 5737–5742 (1995). https://doi.org/10.1007/BF00356714

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