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Magnesium chloride — ethanol adducts

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Abstract

Some 60 addition compounds of the type MgCl2·nEtOH (6 ⩽ n ⩽ 1.4), formed between magnesium chloride and ethanol, have been prepared and were characterized by means of X-ray powder diffraction. The spectra were interpreted on the basis of a subset of nine characteristic diffraction patterns, and a range of (partially) new products, MgCl2·nEtOH with n=6, 4.5, 4, 3.33, 2.5, 1.67, 1.50 and 1.25, is described. MgCl2 adducts with alcohols can be converted to active olefin polymerization catalyst supports through the elimination of the alcohol molecules from the adducts by thermal desolvation.

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  1. Department of Industrial Chemistry, University of Messina, 98166, Messina, Italy

    J. C. J. Bart

  2. DSM Research, P.O. Box 18, 6160, MD Geleen, The Netherlands

    W. Roovers

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Bart, J.C.J., Roovers, W. Magnesium chloride — ethanol adducts. JOURNAL OF MATERIALS SCIENCE 30, 2809–2820 (1995). https://doi.org/10.1007/BF00349648

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