Abstract
Onium salt, N1, N1, N1, N5, N5, N5-hexaethylpentane-1,5-diammonium dibromide, was used as a catalyst for the addition of CO2 to epoxides. An influence of insoluble supports on the rate of the process as well as possibility of recycling of the catalytic system are described. In addition, the effects of temperature and CO2 pressure on the yields of products are discussed.
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Dedicated to Academician of the Russian Academy of Sciences I. L. Eremenko on the occasion of his 70th anniversary.
The work was financially supported by the Russian Science Foundation (Project No. 19-43-02031).
Department of Applied Chemistry, Indian Institute of Technology (Indian School of Mines), Dhanbad, 826004, India.
Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 6, pp. 1076–1079, June, 2020.
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Lyubimov, S.E., Zvinchuk, A.A., Davankov, V.A. et al. The use of a diammonium salt in the synthesis of organic carbonates from epoxides and CO2: promoting effect of support. Russ Chem Bull 69, 1076–1079 (2020). https://doi.org/10.1007/s11172-020-2869-5
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DOI: https://doi.org/10.1007/s11172-020-2869-5