Skip to main content
Log in

An atomic view of crystal growth

  • Surface Physics 1992
  • Published:
Applied Physics A Aims and scope Submit manuscript

Abstract

The ability to routinely observe individual metal atoms adsorbed on metal surfaces using field ion microscopy has made it possible to directly examine atomic events important in the growth of crystals from the vapor. On the atomically smooth (111) plane of iridium, there are now available observations of the binding sites for atoms and of condensation from the vapor, together with measurements of the diffusion of atoms over the surface, as well as studies of their subsequent incorporation at both ascending and descending steps. These results are briefly reviewed, revealing a picture generally more varied and interesting than envisioned in classical theories of crystal growth.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. See, for example, M.G. Lagally (ed.): Kinetics of Ordering and Growth at Surfaces (Plenum Press, New York 1990)

    Google Scholar 

  2. A good overview is given by P. Hartman (ed.): Crystal Growth: An Introduction (North-Holland, Amsterdam 1973)

    Google Scholar 

  3. M. Volmer: Kinetik der Phasenbildung (Theodor Steinkopff, Dresden 1939)

    Google Scholar 

  4. O. Knacke, I.N. Stranski: In Progress in Metal Physics, ed. by B. Chalmers, R. King (Pergamon, London 1956) p. 181

    Google Scholar 

  5. A modern view is presented by J.A. Venables: in Microstructural Evolution of Thin Films, ed. by H.A. Atwater, C. Thompson (Academic, Orlando 1992), in press

    Google Scholar 

  6. T.T. Tsong: Atom-probe Field Ion Microscopy (Cambridge Univ. Press, Cambridge 1990)

    Google Scholar 

  7. J.A. Panitz: J. Phys. E 15, 1281 (1982)

    Google Scholar 

  8. E.W. Müller, T.T. Tsong: Field Ion Microscopy Principles and Applications (Elsevier, New York 1969)

    Google Scholar 

  9. A.V. Crewe: Science 221, 325 (1983)

    Google Scholar 

  10. C. Hamann, M. Hietschold: Raster-Tunnel-Mikroskopie (Akademie Verlag, Berlin 1991)

    Google Scholar 

  11. J.A. Golovchenko: Science 232, 48 (1986)

    Google Scholar 

  12. D.M. Eigler, P.S. Weiss, E.K. Schweizer, N.D. Lang: Phys. Rev. Lett. 66, 1189 (1991)

    Google Scholar 

  13. M. Isaacson, D. Kopf, M. Utlaut, N.W. Parker, A.V. Crewe: Proc. Natl. Acad. Sci. USA 74, 1802 (1977)

    Google Scholar 

  14. E. Ganz, S.K. Theiss, I.-S. Hwang, J. Golovchenko: Phys. Rev. Lett. 68, 1567 (1992)

    Google Scholar 

  15. Y.-W. Mo, R. Kariotis, B.S. Swartzentruber, M.B. Webb, M.G. Lagally: J. Vac. Sci. Technol. 8 A, 201 (1990)

    Google Scholar 

  16. Y.W. Mo, J. Kleiner, M.B. Webb, M.G. Lagally: Phys. Rev. Lett. 66, 1998 (1991)

    Google Scholar 

  17. D. Dijkkamp, E.J. v. Loenen, H.B. Elswijk: In Ordering at Surfaces and Interfaces, Springer Ser. Mater. Sci., ed. by A. Yoshomori, T. Shinjo, H. Watanabe (Springer, Berlin, Heidelberg 1992) p. 85

    Google Scholar 

  18. H.B. Elswijk, A.J. Hoeven, E.J. v. Loenen, D. Dijkkamp: J. Vac. Sci. Technol. B 9, 451 (1991)

    Google Scholar 

  19. M.A. Van Howe, W.H. Weinberg, C.-M. Chan: Low-Energy Electron Diffraction — Experiment, Theory and Surface-Structure Determination, Springer Ser. Surf. Sci., Vol. 6 (Springer, Berlin, Heidelberg 1986)

    Google Scholar 

  20. S.C. Wang, G. Ehrlich: Phys. Rev. Lett. 62, 2297 (1989)

    Google Scholar 

  21. S.C. Wang, G. Ehrlich: Surf. Sci. 224, L997 (1989)

  22. S.C. Wang, G. Ehrlich: Surf. Sci. 246, 37 (1991)

    Google Scholar 

  23. S.C. Wang, G. Ehrlich: Phys. Rev. Lett. 68, 1160 (1992)

    Google Scholar 

  24. S.C. Wang, G. Ehrlich: Surf. Sci. 239, 301 (1990)

    Google Scholar 

  25. G. Ehrlich: In Metal Surfaces: Structure, Energetics and Kinetics. (ASM, Metals Park, Ohio, 1963) p. 221

    Google Scholar 

  26. G. Ehrlich: Brit. J. Appl. Phys. 15, 349 (1964)

    Google Scholar 

  27. T. Gurney, F. Hutchinson, R.D. Young: J. Chem. Phys. 42, 3939 (1965)

    Google Scholar 

  28. R.D. Young, D.C. Schubert: J. Chem. Phys. 42, 3943 (1965)

    Google Scholar 

  29. P.G. Flahive, W.R. Graham: Surf. Sci. 91, 463 (1980)

    Google Scholar 

  30. H.-W. Fink: IBM J. Res. Develop. 30, 460 (1986)

    Google Scholar 

  31. W.F. Egelhoff, I. Jacob: Phys. Rev. Lett. 62, 921 (1989)

    Google Scholar 

  32. G. DeLorenzi, G. Ehrlich: Bull. Am. Phys. Soc. 37, 161 (1992) Abstract C8 2

    Google Scholar 

  33. S.C. Wang, G. Ehrlich: J. Chem. Phys. 94, 4071 (1991)

    Google Scholar 

  34. J.D. Wrigley, M.E. Twigg, G. Ehrlich: J. Chem. Phys. 93, 2885 (1990)

    Google Scholar 

  35. G. Ehrlich: Surf. Sci. 246, 1 (1991)

    Google Scholar 

  36. M.F. Lovisa, G. Ehrlich: Bull. Am. Phys. Soc. 37, 190 (1992) Abstract C23 8

    Google Scholar 

  37. H. Bethge: In Kinetics of Ordering and Growth at Surfaces, ed. by M.G. Lagally (Plenum Press, New York 1990) p. 125

    Google Scholar 

  38. R. Kariotis, M.G. Lagally: Surf. Sci. 216, 557 (1989)

    Google Scholar 

  39. P. Bennema, G.H. Gilmer: In Crystal Growth: An Introduction, ed. by P. Hartman (North-Holland, Amsterdam 1973) p. 263

    Google Scholar 

  40. H.-W. Fink, G. Ehrlich: Surf. Sci. 143, 125 (1984)

    Google Scholar 

  41. S.C. Wang, G. Ehrlich: Phys. Rev. Lett. 67, 2509 (1991)

    Google Scholar 

  42. H.J. Kreuzer: In Chemistry and Physics of Solid Surfaces VIII, Springer Ser. Surf. Sci., Vol. 22, ed. by R. Vanselow, R. Howe (Springer, Berlin, Heidelberg 1990) p. 133

    Google Scholar 

  43. R. Kunkel, B. Poelsema, L.K. Verheij, G. Comsa: Phys. Rev. Lett. 65, 733 (1990)

    Google Scholar 

  44. D.W. Bassett: In Surface Mobilities on Solid Materials, ed. by V.T. Binh (Plenum, New York 1983) p. 63

    Google Scholar 

  45. J.K. Nørskov: In Workshop on Self-diffusion at Metal Surfaces, Copenhagen (1991)

  46. J.D. Wrigley, G. Ehrlich: Phys. Rev. Lett. 44, 661 (1980)

    Google Scholar 

  47. S.C. Wang, G. Ehrlich: 52nd Annual Conf. on Physical Electronics, Univ. of California, Irvine, June 1992

Download references

Author information

Authors and Affiliations

Authors

Rights and permissions

Reprints and permissions

About this article

Cite this article

Ehrlich, G. An atomic view of crystal growth. Appl. Phys. A 55, 403–410 (1992). https://doi.org/10.1007/BF00348327

Download citation

  • Received:

  • Accepted:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF00348327

PACS

Navigation