Abstract
The ability to routinely observe individual metal atoms adsorbed on metal surfaces using field ion microscopy has made it possible to directly examine atomic events important in the growth of crystals from the vapor. On the atomically smooth (111) plane of iridium, there are now available observations of the binding sites for atoms and of condensation from the vapor, together with measurements of the diffusion of atoms over the surface, as well as studies of their subsequent incorporation at both ascending and descending steps. These results are briefly reviewed, revealing a picture generally more varied and interesting than envisioned in classical theories of crystal growth.
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References
See, for example, M.G. Lagally (ed.): Kinetics of Ordering and Growth at Surfaces (Plenum Press, New York 1990)
A good overview is given by P. Hartman (ed.): Crystal Growth: An Introduction (North-Holland, Amsterdam 1973)
M. Volmer: Kinetik der Phasenbildung (Theodor Steinkopff, Dresden 1939)
O. Knacke, I.N. Stranski: In Progress in Metal Physics, ed. by B. Chalmers, R. King (Pergamon, London 1956) p. 181
A modern view is presented by J.A. Venables: in Microstructural Evolution of Thin Films, ed. by H.A. Atwater, C. Thompson (Academic, Orlando 1992), in press
T.T. Tsong: Atom-probe Field Ion Microscopy (Cambridge Univ. Press, Cambridge 1990)
J.A. Panitz: J. Phys. E 15, 1281 (1982)
E.W. Müller, T.T. Tsong: Field Ion Microscopy Principles and Applications (Elsevier, New York 1969)
A.V. Crewe: Science 221, 325 (1983)
C. Hamann, M. Hietschold: Raster-Tunnel-Mikroskopie (Akademie Verlag, Berlin 1991)
J.A. Golovchenko: Science 232, 48 (1986)
D.M. Eigler, P.S. Weiss, E.K. Schweizer, N.D. Lang: Phys. Rev. Lett. 66, 1189 (1991)
M. Isaacson, D. Kopf, M. Utlaut, N.W. Parker, A.V. Crewe: Proc. Natl. Acad. Sci. USA 74, 1802 (1977)
E. Ganz, S.K. Theiss, I.-S. Hwang, J. Golovchenko: Phys. Rev. Lett. 68, 1567 (1992)
Y.-W. Mo, R. Kariotis, B.S. Swartzentruber, M.B. Webb, M.G. Lagally: J. Vac. Sci. Technol. 8 A, 201 (1990)
Y.W. Mo, J. Kleiner, M.B. Webb, M.G. Lagally: Phys. Rev. Lett. 66, 1998 (1991)
D. Dijkkamp, E.J. v. Loenen, H.B. Elswijk: In Ordering at Surfaces and Interfaces, Springer Ser. Mater. Sci., ed. by A. Yoshomori, T. Shinjo, H. Watanabe (Springer, Berlin, Heidelberg 1992) p. 85
H.B. Elswijk, A.J. Hoeven, E.J. v. Loenen, D. Dijkkamp: J. Vac. Sci. Technol. B 9, 451 (1991)
M.A. Van Howe, W.H. Weinberg, C.-M. Chan: Low-Energy Electron Diffraction — Experiment, Theory and Surface-Structure Determination, Springer Ser. Surf. Sci., Vol. 6 (Springer, Berlin, Heidelberg 1986)
S.C. Wang, G. Ehrlich: Phys. Rev. Lett. 62, 2297 (1989)
S.C. Wang, G. Ehrlich: Surf. Sci. 224, L997 (1989)
S.C. Wang, G. Ehrlich: Surf. Sci. 246, 37 (1991)
S.C. Wang, G. Ehrlich: Phys. Rev. Lett. 68, 1160 (1992)
S.C. Wang, G. Ehrlich: Surf. Sci. 239, 301 (1990)
G. Ehrlich: In Metal Surfaces: Structure, Energetics and Kinetics. (ASM, Metals Park, Ohio, 1963) p. 221
G. Ehrlich: Brit. J. Appl. Phys. 15, 349 (1964)
T. Gurney, F. Hutchinson, R.D. Young: J. Chem. Phys. 42, 3939 (1965)
R.D. Young, D.C. Schubert: J. Chem. Phys. 42, 3943 (1965)
P.G. Flahive, W.R. Graham: Surf. Sci. 91, 463 (1980)
H.-W. Fink: IBM J. Res. Develop. 30, 460 (1986)
W.F. Egelhoff, I. Jacob: Phys. Rev. Lett. 62, 921 (1989)
G. DeLorenzi, G. Ehrlich: Bull. Am. Phys. Soc. 37, 161 (1992) Abstract C8 2
S.C. Wang, G. Ehrlich: J. Chem. Phys. 94, 4071 (1991)
J.D. Wrigley, M.E. Twigg, G. Ehrlich: J. Chem. Phys. 93, 2885 (1990)
G. Ehrlich: Surf. Sci. 246, 1 (1991)
M.F. Lovisa, G. Ehrlich: Bull. Am. Phys. Soc. 37, 190 (1992) Abstract C23 8
H. Bethge: In Kinetics of Ordering and Growth at Surfaces, ed. by M.G. Lagally (Plenum Press, New York 1990) p. 125
R. Kariotis, M.G. Lagally: Surf. Sci. 216, 557 (1989)
P. Bennema, G.H. Gilmer: In Crystal Growth: An Introduction, ed. by P. Hartman (North-Holland, Amsterdam 1973) p. 263
H.-W. Fink, G. Ehrlich: Surf. Sci. 143, 125 (1984)
S.C. Wang, G. Ehrlich: Phys. Rev. Lett. 67, 2509 (1991)
H.J. Kreuzer: In Chemistry and Physics of Solid Surfaces VIII, Springer Ser. Surf. Sci., Vol. 22, ed. by R. Vanselow, R. Howe (Springer, Berlin, Heidelberg 1990) p. 133
R. Kunkel, B. Poelsema, L.K. Verheij, G. Comsa: Phys. Rev. Lett. 65, 733 (1990)
D.W. Bassett: In Surface Mobilities on Solid Materials, ed. by V.T. Binh (Plenum, New York 1983) p. 63
J.K. Nørskov: In Workshop on Self-diffusion at Metal Surfaces, Copenhagen (1991)
J.D. Wrigley, G. Ehrlich: Phys. Rev. Lett. 44, 661 (1980)
S.C. Wang, G. Ehrlich: 52nd Annual Conf. on Physical Electronics, Univ. of California, Irvine, June 1992