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Absorption spectra of hexachlorobenzene adsorbed on SiO2 powders

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Summary

Photoacoustic spectra of hexachlorobenzene adsorbed on SiO2 powders of different particle sizes were investigated. A comparison of the measured PA spectra with the calculated optical absorption lengths μβ led to the conclusion that only absorption bands for which μβ is much larger than the particle size, i.e. in the case of carrier transparency, appear in the PA spectrum. This indicates that the particle diameter determines the thickness of the sample. Compared to their solution spectra the PA spectra of HCB on the silica carriers do not show a red shift of the various absorption bands as was claimed in the literature.

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Authors and Affiliations

  1. Fraunhofer-Institut für Toxikologie und Aerosolforschung, Nikolai-Fuchs-Strasse 1, W-3000, Hannover 61, Federal Republic of Germany

    A. Alebić-Juretić & C. Zetzsch

  2. Institut für Meteorologie und Klimaforschung, Kernforschungszentrum Karlsruhe/Universität Karlsruhe, W-7500, Karlsruhe, Federal Republic of Germany

    H. Güsten

Authors
  1. A. Alebić-Juretić
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  2. H. Güsten
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  3. C. Zetzsch
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Permanent address: Institute of Public Health, B. Kidriča, 52a, YU-51000 Rijeka, Yugoslavia

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Alebić-Juretić, A., Güsten, H. & Zetzsch, C. Absorption spectra of hexachlorobenzene adsorbed on SiO2 powders. Fresenius J Anal Chem 340, 380–383 (1991). https://doi.org/10.1007/BF00321586

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  • DOI: https://doi.org/10.1007/BF00321586

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