Abstract
A high temperature calorimetric solution method involving the use of a sodium and lithium metaborate (NaBO2+LiBO2) molten bath at 1,180 K, has been developed in order to measure the enthalpy of formation of the forsterite-fayalite (Mg2SiO4-Fe2SiO4) system. The samples used for these measurements have been obtained by synthesis. They have been carefully controlled by chemical and X-ray analysis and Mössbauer spectroscopy. The results obtained for forsterite and fayalite agree closely with the data commonly found in the literature. Owing to the uncertainty of the experimental results, it is not possible to determine conclusively whether an enthalpy of mixing exists in this system.
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Amossé J, Mathieu JC (1974) Calorimétrie de dissolution en sels fondus. Mise au point de la méthode de détermination de l'enthalpie de formation de NiWO4 à partir de WO3 et NiO. C R Acad Sci 279:871–873
Amossé J, Mathieu JC (1980) The enthalpies of formation of FeWO4, MnWO4 and their solid solution. J Chem Thermodyn 12:683–689
Ariya SM, Bohrysheva NP, Brach BYa, Enden NM (1972) The structure of the non-stoichiometric lower oxide of iron. Zh Fiz Khim 46:1519–1521
Bowen NL, Schairer JF (1935) The system MgO-FeO-SiO2. Am J Sci 29:151–217
Bush WR, Hafner SS, Virgo D (1970) Some ordering of iron and magnesium at the octahedrally coordinated site in a magnesiumrich olivine. Nature 227:1339–1341
Deneuvillè JL (1975) Comparison entre microcalorimétrie classique et microcalorimétrie différentielle appliquées aux alliages métalliques liquides et solides. Thèse de Docteur-Ingénieur, Grenoble
Hewitt DA (1978) A redetermination of the fayalite-magnetite-quartz equilibrium between 650° C and 850° C. Am J Sci 278:715–724
Hultgren R, Desai PD, Hawkins DT, Gleiser M, Kelley KK (1973) Selected values of thermodynamic properties of elements. American Society for metals, Metals Park, Ohio 44073
Janaf (1971) Thermochemical Tables, 2nd edn. Nat Stand Ref Data Ser Nat Bur Stand (US) June
Johnson NL, Leone FC (1977) Statistics and experimental design in Engineering and the physical sciences, vol I, 2nd edn. John Wiley and Sons, New York London Sydney Toronto
King EG (1952) Heat of formation of manganous metasilicate (rhodonite) and ferrous orthosilicate (fayalite). J Am Chem Soc 74:4446–4448
Kitayama K, Katsura T (1968) Activity measurements in orthosilicate and mesosilicate solid solution. I. Mg2SiO4-Fe2SiO4 and MgSiO3-FeSiO3 at 1204° C. Bull Chem Soc Jpn 41:1146–1151
Kleppa OJ (1972) Oxide melt solution calorimetry. Coll Int CNRS. N° 201, Thermochimie: 119–127
Medaris LG Jr (1969) Partitioning of Mg2+-Fe2+ between coexisting synthetic olivine and orthopyroxène. Am J Sci 267:945–968
Navrotsky A, Kleppa OJ (1968) Thermodynamics of formation of single spinels. J Inorg Nucl Chem 30:479–498
Navrotsky A (1977) Progress and new directions in high temperature calorimetry. Phys Chem Minerals 2:89–104
Nazfiger RH (1973) High-temperature activity-composition relation of equilibrium spinels, olivines and pyroxene in the system Mg-Fe-O-SiO2. Am Mineral 58:457–465
Nitzan U (1974) Stability field of olivine with respect to oxidation and reduction. J Geophys Res 79:706–711
Obata M, Banno S, Mori T (1974) The iron-magnesium partitioning between naturally occurring coexisting olivine and Ca-rich pyroxene: an application of the simple mixture model to olivine solid solution. Bull Soc Fr Min Cristallogr 97:101–107
Orr RL (1953) High temperature heat content of magnesium orthosilicate and ferrous orthosilicate. J Am Chem Soc 75:528–529
Robie RA, Hemingway BS, Fisher JR (1978) Thermodynamic properties of minerals and related substances at 298.15 K and 1 bar (105 Pascal) pressure and at high temperature. US Geol Surv Bull 1452, Washington
Shearer JA, Kleppa OJ (1973) The enthalpies of formation of MgAl2O4, MgSiO3, Mg2SiO4, and Al2SiO5, by oxide melt solution calorimetry. J Inorg Nucl Chem 35:1073–1078
Schröcke H (1960) Isomorphiebeziehungen in der Wolframitgruppe. Beitr Mineral Petrogr 7:166–206
Tarte P, Preudhomme J, Jeannot F, Evrard O (1969) Spectre infrarouge et presence de fer trivalent tétracoordiné dans la structure du protoxide de fer. C R Acad Sci 269:1529–1532
Torgeson DR, Sahama ThG (1948) A hydrofluoric acid solution calorimeter and the determination of the heat of formation of Mg2SiO4, MgSiO3, and CaSiO3. Am Chem Soc 70:2156–2160
Yoder HS Jr, Sahama ThG (1957) Olivine X-ray determination curve. Am Mineral 42:475–491
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Thierry, P., Chatillon-Colinet, C., Mathieu, J.C. et al. Thermodynamic properties of the forsterite-fayalite (Mg2SiO4-Fe2SiO4) solid solution. determination of heat of formation. Phys Chem Minerals 7, 43–46 (1981). https://doi.org/10.1007/BF00308200
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DOI: https://doi.org/10.1007/BF00308200