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Copper(II) and nickel(II) complexes of 2-formylpyridine 3-piperidinyl-, 3-hexamethyleneiminyl- and 3-azabicyclo[3.2.2]nonylthiosemicarbazones

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Summary

Copper(II) and nickel(II) complexes of 2-formylpyridine 3-piperidinyl-, 3-hexamethyleneiminyl- and 3-azabicyclo-[3.2.2]nonylthiosemicarbazones were prepared and characterized spectroscopically. 1H and 13C n.m.r. spectra of the thiosemicarbazones and a diamagnetic nickel(II) complex are reported, together with i.r., electronic and e.s.r. spectra of the metal complexes. The thiosemicarbazones and their copper(II) and nickel(II) complexes exhibit considerable growth inhibitory activity against Paecilomyces variotii, but show minimal activity against Aspergillus niger.

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References

  1. J. P. Scovill, D. L. Klayman and C. F. Franchino, J. Med. Chem., 25, 1261 (1982).

    Google Scholar 

  2. D. X. West and N. C. Lewis, Transition Met. Chem., 12, 365 (1987); D. X. West, C. S. Carlson, A. C. Whyte and A. E. Liberta, Transition Met. Chem., 15, 43 (1990); D. X. West, R. D. Profilet and J, L. Hines, Transition Met. Chem., 13, 467 (1988); S. K. Jain, B. S. Garg, Y. K. Bhoon, D. L. Klayman and J. P. Scovill, Spectrochim. Acta, 41A, 407 (1985).

    Google Scholar 

  3. S. K. Jain, B. S. Garg and Y. K. Bhoon, Spectrochim. Acta, 42A, 959 (1986); D. X. West and N. C. Lewis, Transition Met. Chem., 13, 277 (1988); Y. K. Bhoon, S. Mitra, J. P. Scovill and D. L. Klayman, Transition Met. Chem., 7, 264 (1982); Y. K. Bhoon, J. P. Scovill and D. L. Klayman, Ind. J. Chem., 22A, 267 (1983); D. X. West, J. P. Scovill, J. V. Silverton and A. Bavoso, Transition Met. Chem., 11, 123 (1986).

    Google Scholar 

  4. D. X. West, R. M. Makeever, J. P. Scovill and D. L. Klayman, Polyhedron, 3, 947 (1984); Y. K. Bhoon, D. L. Klayman and J. P. Scovill, Spectrochim. Acta, 40A, 691 (1984); D. X. West and D. S. Galloway, Transition Met. Chem., 13, 410 (1988); B. S. Garg, M. R. P. Kurup, S. K. Jain and Y. K. Bhoon, Transition Met. Chem., 13, 247 (1988); D. X. West, D. S. Galloway and D. A. Case, Transition Met. Chem., 13, 415 (1988).

    Google Scholar 

  5. D. X. West, C. S. Carlson, C. P. Galloway, A. E. Liberta and C. R. Daniel, Transition Met. Chem., 15, 91 (1990); D. X. West, C. S. Carlson, A. E. Liberta, J. N. Albert and C. R. Daniel, Transition Met. Chem., 15, 341 (1990); D. X. West, T. J. Romack and A. E. Liberta, Transition Met. Chem., 17, 256 (1992) and D. X. West, A. C. Whyte, F. D. Sharif, H. Gebremedhin and A. E. Liberta, Transition Met. Chem., 18, 238 (1993).

    Google Scholar 

  6. D. X. West, C. S. Carlson, K. J. Bouck and A. E. Liberta, Transition Met. Chem., 16, 271 (1991).

    Google Scholar 

  7. A. E. Liberia and D. X. West, Biometals, 5, 121 (1992).

    Google Scholar 

  8. C.F. Bell, K. A. K. Lott and N. Hearn, Polyhedron, 6, 39 (1987).

    Google Scholar 

  9. W. E. Antholine, J. M. Knight and D. H. Petering, Inorg. Chem., 16, 569 (1977); H. Beraldo and L. Tosi, Inorg. Chim. Acta, 125, 173 (1986); A. G. Bingham, H. Bogge, A. Muller, E. W. Ainscough and A. M. Brodie, J. Chem. Soc., Dalton Trans., 493 (1987); H. K. Parwana and G. Singh, Ind. J. Chem., 26A, 581 (1987).

    Google Scholar 

  10. M. A. Malik and D. J. Phillips, J. Inorg. Nucl. Chem., 36, 2229 (1974).

    Google Scholar 

  11. P. S. N. Reddy and B. V. Agarwala, Synth. React. Inorg. Met-org. Chem., 17, 585 (1987).

    Google Scholar 

  12. D. X. West, D. L. Huffman, J. S. Saleda and A. E. Liberta, Transition Met. Chem., 16, 565 (1991).

    Google Scholar 

  13. D. X. West, J. S. Saleda and A. E. Liberta, Transition Met. Chem., 17, 568 (1992).

    Google Scholar 

  14. B. Holmberg and B. Psilanderhielm, J. Prakt. Chem., 82, 440 (1910).

    Google Scholar 

  15. J. P. Scovill, Phosph. Sulf. Silic., 60, 15 (1991).

    Google Scholar 

  16. K. R. Koch, J. Coord. Chem., 22, 289 (1991); D. X. West, B. L. Mokijewski, H. Gebremedhin and T. J. Romack, Transition Met. Chem., 17, 384 (1992).

    Google Scholar 

  17. D. X. West, H. Gebremedhin, R. J. Bulcher, J. P. Jasinski and A. E. Liberta, Polyhedron, 12, 2489 (1993).

    Google Scholar 

  18. D. X. West, M. A. Lockwood, A. E. Liberta, X. Chen and R. D. Willett, Polyhedron, 12, 1887 (1993).

    Google Scholar 

  19. W. J. Geary, Coord. Chem. Rev., 7, 81 (1971).

    Google Scholar 

  20. D. X. West, H. Gebremedhin, R. J. Butcher and J. P. Jasinski, unpublished observations.

  21. M. Biddau, M. Massacesi, R. Pinna and G. Ponticelli, Transition Met. Chem., 3, 153 (1978).

    Google Scholar 

  22. D. X. West, B. L. Mokijewski, H. Gebremedhin and T. J. Romack, Transition Met. Chem., 17, 384 (1983).

    Google Scholar 

  23. D. X. West (1992) unpublished observalions.

  24. W. D. Harrison, D. M. Kennedy, M. Power, R. Sheahan and B. J. Halhaway, J. Chem. Soc., Dalton Trans., 1556 (1981).

  25. D. X. West, S. L. Dietrich, I. Thientanavanich, C. A. Brown and A. E. Liberta, Transition Met. Chem., 19, 195 (1994).

    Google Scholar 

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Authors and Affiliations

  1. Department of Chemistry, Illinois State University, 61761, Normal, IL, USA

    Douglas X. West, Christopher E. Ooms, Jill S. Saleda, H. Gebremedhin & Anthony E. Liberta

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  1. Douglas X. West
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  2. Christopher E. Ooms
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  3. Jill S. Saleda
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  4. H. Gebremedhin
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  5. Anthony E. Liberta
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West, D.X., Ooms, C.E., Saleda, J.S. et al. Copper(II) and nickel(II) complexes of 2-formylpyridine 3-piperidinyl-, 3-hexamethyleneiminyl- and 3-azabicyclo[3.2.2]nonylthiosemicarbazones. Transition Met Chem 19, 553–558 (1994). https://doi.org/10.1007/BF00136373

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  • DOI: https://doi.org/10.1007/BF00136373

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