Skip to main content
SpringerLink
Log in

The Study of Kinetic Oscillations in the Catalytic CO-Oxidation on Single Crystal Surfaces

  • Chapter
Optimal Structures in Heterogeneous Reaction Systems

Part of the book series: Springer Series in Synergetics ((SSSYN,volume 44))

Abstract

In the past decade the study of non-equilibrium systems has attracted a great deal of interest as more and more mathematical tools and theoretical concepts have been developed to try to understand the complex dynamical behavior of these systems. Although the prototype of such a chemical reaction system is still the Belousov-Zabotinskii (BZ)-reaction which takes place in the homogeneous fluid phase, there have also been numerous investigations of kinetic oscillations in heterogeneously catalyzed reactions amongst which the catalytic CO-oxidation has attracted most interest [1,2]. This can be attributed to the simplicity of the chemistry CO+1/2O2→CO2: However, despite numerous studies, reviewed recently by Schmitz [2] there still exists no commonly accepted mechanism among the different models which have been proposed.

This is a preview of subscription content, log in via an institution to check access.

Access this chapter

Log in via an institution
eBook
USD 16.99
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
Softcover Book
USD 16.99
Price excludes VAT (USA)
  • Compact, lightweight edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info

Tax calculation will be finalised at checkout

Purchases are for personal use only

Institutional subscriptions

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

Similar content being viewed by others

References

  1. P. Hugo: Ber. Bunsenges. Phys. Chem. 74 (1970) 121

    CAS  Google Scholar 

  2. H. Beusch, P. Fieguth, E. Wicke: Chem. Ing. Techn. 44 (1972) 445

    Article  CAS  Google Scholar 

  3. L. F. Razón, R. A. Schmitz: Catal. Rev. Sci. Eng. 28 (1986) 89

    Article  Google Scholar 

  4. D. J. Kaul, E. E. Wolf: J. Catal. 91 (1985) 216

    Article  CAS  Google Scholar 

  5. D. J. Kaul, E. E. Wolf: J. Catal. 93 (1985) 321

    Article  CAS  Google Scholar 

  6. T. H. Lindstrom, T. T. Tsotsis: Surf. Sci. 150 (1985) 487

    Article  CAS  Google Scholar 

  7. V. A. Burrows, S. Sundaresan, Y. J. Chabal, S. B. Christman: I: Surf. Sci. 160 (1985) 122, II: Surf. Sci, 180 (1987) 110

    Google Scholar 

  8. N. A. Collins, S. Sundaresan, Y. J. Chabal: Surf. Sci. 180 (1987) 136

    Article  CAS  Google Scholar 

  9. R. Sant, E. E. Wolf: J. Catal. 110 (1988) 249

    Article  CAS  Google Scholar 

  10. F. Schüth, Thesis, Univ. Münster (1988)

    Google Scholar 

  11. J. E. Turner, B C. Sales, M. B. Maple: Surf. Sci. 103 (1981) 54

    Article  CAS  Google Scholar 

  12. Experimental details can be found in refs. 23 and 24. The general background of the experimental techniques used in surface chemistry is described in refs. 11 and 12.

    Google Scholar 

  13. G. Ertl, J. Uppers, Low Energy Electrons and Surface Chemistry, Verlag Chemie, Berlin 1985

    Google Scholar 

  14. See, e.g. R. P. H. Gasser, An Introduction to Chemisorption and Catalysis by Metals, Clarendon Press, Oxford 1985

    Google Scholar 

  15. H. Niehus, G. Comsa: Surf. Sci. 102 (1981) L14

    Article  CAS  Google Scholar 

  16. R. C. Yeates, J. E. Turner, A. J. Gellman, G. A. Somorjai: Surf. Sci. 149 (1985) 175

    Article  CAS  Google Scholar 

  17. T. Engel, G. Ertl: Advan. Catal. 28 (1979) 1

    Article  CAS  Google Scholar 

  18. M. A. Van Hove, R. J. Koestner, P. C. Stair, J. P. Bibérian, L. L. Kesmodel, I. Bartot, G. A. Somorjai: Surf. Sci. 103 (1981) I 189; II 218

    Google Scholar 

  19. W. Moritz, Habilitationsschrift, Univ. München (1984)

    Google Scholar 

  20. R. J. Behm, W. Hösler, E. Ritter, G. Binnig: Phys. Rev. Lett. 56 (1986) 228

    Article  CAS  Google Scholar 

  21. H. Niehus: Surf. Sci. 145 (1984) 407

    Article  CAS  Google Scholar 

  22. T. E. Jackman, J. A. Davies, D. P. Jackson, W. N. Unertl, P. R. Norton: Surf. Sci. 120 (1982) 389

    Article  CAS  Google Scholar 

  23. G. Ertl, P. R. Norton, J. Rüstig: Phys. Rev. Lett. 49 (1982) 177

    Article  CAS  Google Scholar 

  24. P. R. Norton, P. E. Bindner, K. Griffiths, T. E. Jackman, J. A. Davies, J. Rüstig: J. Chem. Phys. 80 (1984) 3859

    Article  CAS  Google Scholar 

  25. M. P. Cox, G. Ertl, R. Imbihl, J. Rüstig: Surf. Sci. 134 (1983) L517

    Article  CAS  Google Scholar 

  26. R. Imbihl, M. P. Cox, G. Ertl, H. Müller, W. Brenig: J. Chem. Phys. 83 (1985) 1578

    Article  CAS  Google Scholar 

  27. M. P. Cox, G. Ertl, R. Imbihl: Phys. Rev. Lett. 54 (1985) 1725

    Article  CAS  Google Scholar 

  28. M. Eiswirth, R. J. Schwankner, G. Ertl: Z. Phys. Chem. N.F. 144 (1985) 59

    Article  CAS  Google Scholar 

  29. R. Imbihl, M. P. Cox, G. Ertl: J. Chem. Phys. 84 (1986) 3519

    Article  CAS  Google Scholar 

  30. P. Möller, K. Wetzl, M. Eiswirth, G. Ertl: J. Chem. Phys. 85 (1986) 5328

    Article  Google Scholar 

  31. R. J. Schwankner, M. Eiswirth, P. Möller, K. Wetzl, G. Ertl: J. Chem. Phys. 87 (1987) 742

    Article  CAS  Google Scholar 

  32. R. F. S. Andradé, G. Devel, P. Borckmans: to be published

    Google Scholar 

  33. T. Fink, R. Imbihl, G. Ertl: submitted to J. Chem. Phys.

    Google Scholar 

  34. M. Eiswirth, G. Ertl: Surf. Sci. 177 (1986) 90

    Article  CAS  Google Scholar 

  35. M. Eiswirth, Thesis, Univ. Munich (1987)

    Google Scholar 

  36. S. Ladas, R. Imbihl, G. Ertl: Surf. Sci. 197 (1988) 153

    Article  CAS  Google Scholar 

  37. S. Ladas, R. Imbihl, G. Ertl: Surf. Sci. 198 (1988) 42

    Article  CAS  Google Scholar 

  38. M. Eiswirth, G. Ertl: Phys. Rev. Lett. 60 (1988) 1526

    Article  CAS  Google Scholar 

  39. M. Eiswirth, K. Krischer, G. Ertl: Surf. Sci. 202 (1988) 565

    Article  CAS  Google Scholar 

  40. M. Eiswirth, P. Möller, K. 90 (1989) 510

    CAS  Google Scholar 

  41. M. Eiswirth, P. Möller, G. Ertl: Surf. Sci. 208 (1989) 13

    Article  CAS  Google Scholar 

  42. M. Eiswirth, G. Ertl: Appl. Phy. A47 (1988) 91

    Article  CAS  Google Scholar 

  43. a) R. Imbihl, M. Sander, G. b) A. L. Vishnevskii, V. I (1989) 187

    Google Scholar 

  44. M. Ehsasi, J. H. Block, K.Christmann, W. Hirschwald: J. Vac. Sci. Technol. A5 (1987) 821

    Google Scholar 

  45. M. Ehsasi, Thesis, FU Berlin (1989).

    Google Scholar 

  46. M. Ehsasi, C. Seidel, H. Ruppender, W. Drachsel, J. H. Block, K. Christmann: Surf. Sci. 210 (1989) L198

    Article  CAS  Google Scholar 

  47. S. Ladas, R. Imbihl, G. Ertl: Surf. Sci., in press S. B. Schwartz, L. D. Schmidt: Surf. Sci. 183 (1987) L269

    Google Scholar 

  48. S. B. Schwartz, L. D. Schmidt: Surf, Sci. 206 (1988) 169

    Article  CAS  Google Scholar 

  49. R. J. Behm, P. A. Thiel, P. R. Norton, G. Ertl: J. Chem. Phys. 78 (1983) 7437; 7448

    Google Scholar 

  50. J.-P. Dath, J.-P. Dauchot: J. Catal. 97 (1986) 100

    Article  CAS  Google Scholar 

  51. G. Pirug, G. Brodén, H. P. Bonzel: Proc. 7th Int. Vacuum Congr. Vienna (1977), p. 907; Chem. Phys. Lett. 73 (1980) 306

    Google Scholar 

  52. P. R. Norton, K. Griffiths, P. E. Bindner: Surf. Sci. 138 (1984) 125

    Article  CAS  Google Scholar 

  53. N. Freyer, M. Kiskinova, G. Pirug, H. P. Bonzel: Surf. Sci. 166 (1986) 206

    Article  CAS  Google Scholar 

  54. M. Flytzani-Stephanopoulos, L. D. Schmidt: Progr. Surf. Sci. 9 (1979) 83

    Article  CAS  Google Scholar 

  55. C. E. Smith, J. P. Biberian, G. A. Somorjai: J. Catal. 57 (1979) 426

    Google Scholar 

  56. H. Niehus, G. Comsa: Surf. Sci. 93 (1980) L147

    Article  CAS  Google Scholar 

  57. A. K. Galwey, P. Gray, J. F. Griffiths, S. M. Hasko: Nature 313 (1985) 668

    Article  CAS  Google Scholar 

  58. G. Padberg, E. Wicke: Chem. Eng. Sci. 22 (1967) 1035

    Google Scholar 

  59. N. I. Jaeger, K. Möller, P. J. Plath: J. Chem. Soc. Faraday 82 (1986) 3315

    Google Scholar 

  60. J. R. Brown, G. A. D’Netto, R. A. Schmitz: in Temporal Order (Eds. L. Rensing and N. I. Jaeger), Springer, Heidelberg 1985, p. 86

    Google Scholar 

  61. H. U. Onken, Thesis, Univ. Münster (1987)

    Google Scholar 

  62. H. U. Onken, E. Wicke: Ber. Bunsenges. 93 (1989) 191

    Google Scholar 

  63. R. J. Behm, P. A. Thiel, P. R. Norton, P. E. Bindner: Surf. Sci. 147 (1984) 143

    Article  CAS  Google Scholar 

  64. J.-P. Dath, J.-P. Dauchot: J. Catal., J. Catal. 115 (1989) 593

    CAS  Google Scholar 

  65. R. J. Field, H. Burger (Eds.), Oscillations and Travelling Waves in Chemical Systems, John Wiley, New York 1985

    Google Scholar 

  66. J. Tilden: J. Chem. Phys. 60 (1974) 3349

    Article  CAS  Google Scholar 

  67. G. A. D’Netto, J. R. Brown, R. A. Schmitz: IChemE Symp. Ser. 87 (1984) 247

    Google Scholar 

  68. P. K. Tsai, M. B. Maple, R. K. Herz: J. Catal. 113 (1988) 453

    Article  CAS  Google Scholar 

  69. L. F. Razón, S.-M. Chang, R. A. Schmitz, Chem. Eng. Sci. 41 (1986) 1561

    Article  Google Scholar 

  70. N. I. Jaeger, P. J. Plath, P. Svensson, in Spatial Inhomogeneities and Transient Behavior in Chemical Kinetics, (Ed. G. Nicolis), in press

    Google Scholar 

  71. M. Gerhardt, Thesis, Univ. Bremen (1987)

    Google Scholar 

  72. H. Schuster, Thesis, Univ. Bremen (1987)

    Google Scholar 

  73. A. K. Dewdney: Scientific American 259 (1988) 86

    Google Scholar 

  74. See, e.g. a) H. Haken; Advanced Synergetics, Springer Series in Synergetics, Vol. 20, Springer-Verlag, Berlin, Heidelberg 1983

    Google Scholar 

  75. J. M. T. Thompson, H. B. Stewart; Non-linearDynamics and Chaos,Wiley, New York, 1986

    Google Scholar 

  76. T. Kai, K. Tomita: Progr. Theor. Phys. 61 (1979) 54

    Article  Google Scholar 

  77. F. W. Schneider: Ann. Rev. Chem. 36 (1985) 347

    Article  CAS  Google Scholar 

  78. M. Marek, in Temporal Order (Eds. L. Rensing and N. I. Jaeger) Springer, Berlin (1985), p. 105

    Google Scholar 

  79. H. U. Onken, E. Wicke: Ber. Bunsenges. Phys. Chem. 90 (1986) 976

    CAS  Google Scholar 

  80. S. C. Capsaskis, C. N. Kenney: J. Phys. Chem. 90 (1986) 4631

    Article  CAS  Google Scholar 

  81. D. T. Lynch, G. Emig, S. Wanke: J. Catal. 97 (1986) 456

    Article  CAS  Google Scholar 

  82. W. Hösier, E. Ritter, R. J. Behm: Ber. Bunsenges. Phys. Chem. 90 (1986) 205

    Google Scholar 

  83. J. Falta, R. Imbihl, M. Henzler: submitted to Phys. Rev. Lett.

    Google Scholar 

  84. R. Imbihl, S. Ladas, G. Ertl: Surf. Sci. 215 (1989) L307

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Fritz-Haber-Institut der Max-Planck-Gesellschaft, Faradayweg 4-6, D-1000, Berlin 33, Germany

    R. Imbihl

Authors
  1. R. Imbihl
    View author publications

    You can also search for this author in PubMed Google Scholar

Editor information

Editors and Affiliations

  1. Institut für Angewandte und Physikalische Chemie, Universität Bremen, Bibliothekstrasse, D-2800, Bremen 33, Fed. Rep. of Germany

    Peter J. Plath

Rights and permissions

Reprints and permissions

Copyright information

© 1989 Springer-Verlag Berlin Heidelberg

About this chapter

Cite this chapter

Imbihl, R. (1989). The Study of Kinetic Oscillations in the Catalytic CO-Oxidation on Single Crystal Surfaces. In: Plath, P.J. (eds) Optimal Structures in Heterogeneous Reaction Systems. Springer Series in Synergetics, vol 44. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-83899-6_2

Download citation

  • DOI: https://doi.org/10.1007/978-3-642-83899-6_2

  • Publisher Name: Springer, Berlin, Heidelberg

  • Print ISBN: 978-3-642-83901-6

  • Online ISBN: 978-3-642-83899-6

  • eBook Packages: Springer Book Archive

Publish with us

Policies and ethics

Search

Navigation