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Self oscillations and surface concentration waves in the CO oxidation reaction over Pt(100) and Pd(110): stochastic modelling

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Abstract

The manuscript describes the most interesting results, which were obtained during the mathematical simulation of the CO oxidation reaction over Pt(100) and Pd(110) single crystals. In both cases, a narrow reaction zone with a maximal reaction rate appears when the oxygen wave propagated over the surface. Furthermore, the influence of anisotropic COads diffusion over the kinetic dependencies haze been revealed.

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Acknowledgments

I am very thankful to all my friends and coauthors—Vladimir Gorodetskii, Evgenii Latkin, Andrei Matveev, Evgenii Kovalyov, Anatolii Vishnevskii, Johan Bakker and Bernard Nieuwenhuys. Many thanks and congratulations to my friend Prof. Slobodan Anic for his friendship and hospitality.

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Authors and Affiliations

  1. Boreskov Institute of Catalysis, Siberian Branch of the Russian Academy of Sciences, Prosp. Acad. Lavrentieva, 5, Novosibirsk-90, Russia, 630090

    Vladimir Elokhin

  2. Novosibirsk State University, Novosibirsk-90, Russia, 630090

    Vladimir Elokhin

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  1. Vladimir Elokhin
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Correspondence to Vladimir Elokhin.

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Elokhin, V. Self oscillations and surface concentration waves in the CO oxidation reaction over Pt(100) and Pd(110): stochastic modelling. Reac Kinet Mech Cat 118, 87–97 (2016). https://doi.org/10.1007/s11144-016-1020-y

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  • DOI: https://doi.org/10.1007/s11144-016-1020-y

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