Abstract
The implants containing Al, Ni, Cr, Ti, Mo, and Zr based on stainless steel foil (SSF) were prepared by low-temperature implantation method with one- or two-element (step-by-step) deposition. The synthesized composites were studied by means of traditional XRD and XRD of thin films, SEM, AFM, and XPS methods. The temperature of the surface composites at their heating by electric current was established. The catalytic properties of the samples in hydrogen production from ethanol were determined in traditional catalytic reactor (with reaction mixture heating) and in reactor with catalyst heating by electric current only.
The results of XRD study of the prepared composites show the presence of austenite phase, characteristic of the stainless steel support (SSF) only.
In SEM methods, it was shown that the metal implantation forms a surface layer with thickness about 100 nm. Besides, SEM and AFM methods have demonstrated that the ionic bombardment essentially changes the support surface morphology.
It was shown that at the heating of the samples by electric current, the temperature on the surface of the implanted samples has higher values than in the case of industrial electric heating element or initial support (SSF) used.
Thus, machining of stainless steel by the ionic implantation allows to obtain materials with high thermal and mechanical characteristics. The synthesized materials acquire catalytic properties, and structural characteristics lead to the conclusion that they are promising as carriers. All in all, the foregoing indicates a significant qualitative change in the steel samples and their transition into the category of materials-implants with a set of characteristics that have practical use.
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Acknowledgments
The investigations were realized with partial financial support of NAS of Ukraine Fundamental Programme “Fine Chemicals” Project 20-(14-16).
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Honcharov, V., Zazhigalov, V., Sawlowicz, Z., Socha, R., Gurgol, J. (2017). Structural, Catalytic, and Thermal Properties of Stainless Steel with Nanoscale Metal Surface Layer. In: Fesenko, O., Yatsenko, L. (eds) Nanophysics, Nanomaterials, Interface Studies, and Applications . NANO 2016. Springer Proceedings in Physics, vol 195. Springer, Cham. https://doi.org/10.1007/978-3-319-56422-7_26
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DOI: https://doi.org/10.1007/978-3-319-56422-7_26
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