Abstract
Carbon fiber reinforced polymer composites have low density and high tensile strengths. However, their compressive strengths are much lower than their corresponding tensile strengths due to fiber micro-buckling and interface failure between fiber and matrix. To address this issue, we report a method for fabricating carbon nanotube (CNT) sheet scrolled carbon fibers or fiber tows to improve the interfacial shear strengths. A CNT sheet is drawn from a drawable carbon nanotube forest grown on a silicon substrate, it is used to wrap around individual carbon fibers. The CNT wrapped carbon fiber is subsequently impregnated into a polymer to form a composite. Scanning electron micrograph shows that the wettability of CNT wrapped carbon fiber composite increases drastically in comparison with the composite without CNT, indicating significantly increased bonding between carbon fiber and polymer due to the addition of aligned CNT at the interphase. Fiber push-out and push-in nanoindentation characterization indicates increased interfacial shear strengths, consistently at over 80% with the use of wrapped aligned CNT sheet. The results from scrolling CNT sheet around individual carbon fibers to enhance compressive strengths indicate the potential performance enhancement of composites when this approach is scaledĀ up.
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References
Tang, L.G., Kardos, J.L.: A review of methods for improving the interfacial adhesion between carbon fiber and polymer matrix. Polym. Compos. 18(1), 100ā113 (1997)
Williams, J.C., Starke Jr., E.A.: Progress in structural materials for aerospace systems. Acta Mater. 51(19), 5775ā5799 (2003)
Soutis, C.: Carbon fiber reinforced plastics in aircraft construction. Mater. Sci. Eng. A. 412(1ā2), 171ā176 (2005)
Liao, K., Schultesiz, C.R., Hunston, D.L., Brinson, L.C.: Long-term durability of fiber-reinforced polymer-matrix composite materials for infrastructure applications: a review. J. Adv. Mater. 30(4), 3ā40 (1998)
Talreja, R.: Matrix and fiberāmatrix interface cracking in composite materials. In: Modeling Damage, Fatigue and Failure of Composite Materials, pp. 87ā96. Woodhead Publishing (2016)
Lu, H., Baughman, R.H., Haque, M.H., Fang, S.D.: Method of fabricating carbon nanotube sheet scrolled fiber reinforced polymer composites and compositions and uses thereof. US Patent 9,758,628, 12 Sept 2017
Swadener, J.G., Liechti, K.M., De Lozanne, A.L.: The intrinsic toughness and adhesion mechanisms of a glass/epoxy interface. J. Mech. Phys. Solids. 47(2), 223ā258 (1999)
Vodenitcharova, T., Zhang, L.C.: Bending and local buckling of a nanocomposite beam reinforced by a single-walled carbon nanotube. Int. J. Solids Struct. 43(10), 3006ā3024 (2006)
Pantano, A., Parks, D.M., Boyce, M.C.: Mechanics of deformation of single-and multi-wall carbon nanotubes. J. Mech. Phys. Solids. 52(4), 789ā821 (2004)
Penumadu, D., Dutta, A., Pharr, G.M., Files, B.: Mechanical properties of blended single-wall carbon nanotube composites. J. Mater. Res. 18(8), 1849ā1853 (2003)
Moniruzzaman, M., Winey, K.I.: Polymer nanocomposites containing carbon nanotubes. Macromolecules. 39(16), 5194ā5205 (2006)
Godara, A., Gorbatikh, L., Kalinka, G., Warrier, A., Rochez, O., Mezzo, L., et al.: Interfacial shear strength of a glass fiber/epoxy bonding in composites modified with carbon nanotubes. Compos. Sci. Technol. 70(9), 1346ā1352 (2010)
Yumitoril, S., Araoz, Y., Tanakaz, T., Naito, K., Tanaka, K., Katayama, T.: Increasing the interfacial strength in carbon fiber/polypropylene composites by growing CNTs on the fibers. Comput. Methods Exp. Meas. XVI. 55, 275 (2013)
Sager, R.J., Klein, P.J., Lagoudas, D.C., Zhang, Q., Liu, J., Dai, L., Baur, J.W.: Effect of carbon nanotubes on the interfacial shear strength of T650 carbon fiber in an epoxy matrix. Compos. Sci. Technol. 69(7ā8), 898ā904 (2009)
Frankland, S.J.V., Caglar, A., Brenner, D.W., Griebel, M.: Molecular simulation of the influence of chemical cross-links on the shear strength of carbon nanotubeā polymer interfaces. J. Phys. Chem. B. 106(12), 3046ā3048 (2002)
Lv, P., Feng, Y.Y., Zhang, P., Chen, H.M., Zhao, N., Feng, W.: Increasing the interfacial strength in carbon fiber/epoxy composites by controlling the orientation and length of carbon nanotubes grown on the fibers. Carbon. 49(14), 4665ā4673 (2011)
Bekyarova, E., Thostenson, E.T., Yu, A., Kim, H., Gao, J., Tang, J., et al.: Multiscale carbon nanotubeā carbon fiber reinforcement for advanced epoxy composites. Langmuir. 23(7), 3970ā3974 (2007)
Bekyarova, E., Thostenson, E.T., Yu, A., Itkis, M.E., Fakhrutdinov, D., Chou, T.W., Haddon, R.C.: Functionalized single-walled carbon nanotubes for carbon fiberā epoxy composites. J. Phys. Chem. C. 111(48), 17865ā17871 (2007)
Fan, Z., Santare, M.H., Advani, S.G.: Interlaminar shear strength of glass fiber reinforced epoxy composites enhanced with multi-walled carbon nanotubes. Compos. A: Appl. Sci. Manuf. 39(3), 540ā554 (2008)
Kim, B.W., Nairn, J.A.: Observations of fiber fracture and interfacial debonding phenomena using the fragmentation test in single fiber composites. J. Compos. Mater. 36(15), 1825ā1858 (2002)
Thostenson, E.T., Li, W.Z., Wang, D.Z., Ren, Z.F., Chou, T.W.: Carbon nanotube/carbon fiber hybrid multiscale composites. J. Appl. Phys. 91(9), 6034ā6037 (2002)
Chandra, N., Ghonem, H.: Interfacial mechanics of push-out tests: theory and experiments. Compos. A: Appl. Sci. Manuf. 32(3ā4), 575ā584 (2001)
Miller, B., Muri, P., Rebenfeld, L.: A microbond method for determination of the shear strength of a fiber/resin interface. Compos. Sci. Technol. 28(1), 17ā32 (1987)
Nishikawa, M., Okabe, T., Hemmi, K., Takeda, N.: Micromechanical modeling of the microbond test to quantify the interfacial properties of fiber-reinforced composites. Int. J. Solids Struct. 45(14ā15), 4098ā4113 (2008)
Xu, T., Luo, H., Xu, Z., Hu, Z., Minary-Jolandan, M., Roy, S., Lu, H.: Evaluation of the effect of thermal oxidation and moisture on the interfacial shear strength of unidirectional IM7/BMI composite by Fiber push-in nanoindentation. Exp. Mech. 58(1), 111ā123 (2018)
Xu, Z., Chen, L., Huang, Y., Li, J., Wu, X., Li, X., Jiao, Y.: Wettability of carbon fibers modified by acrylic acid and interface properties of carbon fiber/epoxy. Eur. Polym. J. 44(2), 494ā503 (2008)
Wang, C., Li, Y., Tong, L., Song, Q., Li, K., Li, J., et al.: The role of grafting force and surface wettability in interfacial enhancement of carbon nanotube/carbon fiber hierarchical composites. Carbon. 69, 239ā246 (2014)
Song, W., Gu, A., Liang, G., Yuan, L.: Effect of the surface roughness on interfacial properties of carbon fibers reinforced epoxy resin composites. Appl. Surf. Sci. 257(9), 4069ā4074 (2011)
Aliev, A.E., Oh, J., Kozlov, M.E., Kuznetsov, A.A., Fang, S., Fonseca, A.F., et al.: Giant-stroke, superelastic carbon nanotube aerogel muscles. Science. 323(5921), 1575ā1578 (2009)
Xu, T.: Characterization and Modeling of Mechanical Behavior of Polymers and Composites at Small Scales by Nanoindentation. The University of Texas at Dallas (2017)
Minnicino, M.A., Santare, M.H.: Modeling the progressive damage of the microdroplet test using contact surfaces with cohesive behavior. Compos. Sci. Technol. 72(16), 2024ā2031 (2012)
Zidi, M., Carpentier, L., Chateauminois, A., Sidoroff, F.: Quantitative analysis of the micro-indentation behaviour of fibre-reinforced composites: development and validation of an analytical model. Compos. Sci. Technol. 60(3), 429ā437 (2000)
RodrĆguez, M., Molina-AldareguĆa, J.M., GonzĆ”lez, C., LLorca, J.: A methodology to measure the interface shear strength by means of the fiber push-in test. Compos. Sci. Technol. 72(15), 1924ā1932 (2012)
Molina-AldareguĆa, J.M., RodrĆguez, M., GonzĆ”lez, C., LLorca, J.: An experimental and numerical study of the influence of local effects on the application of the fibre push-in test. Philos. Mag. 91(7ā9), 1293ā1307 (2011)
Medina, C., Molina-AldareguĆa, J.M., GonzĆ”lez, C., Melendrez, M.F., Flores, P., LLorca, J.: Comparison of push-in and push-out tests for measuring interfacial shear strength in nano-reinforced composite materials. J. Compos. Mater. 50(12), 1651ā1659 (2016)
Mandell, J.F., Chen, J.H., McGarry, F.J.: A microdebonding test for in situ assessment of fibre/matrix bond strength in composite materials. Int. J. Adhes. Adhes. 1(1), 40ā44 (1980)
Marshall, D.B., Oliver, W.C.: Measurement of interfacial mechanical properties in fiber-reinforced ceramic composites. J. Am. Ceram. Soc. 70(8), 542ā548 (1987)
Kokkada, P., Roy, S., Unnikrishnan, V., Lu, H.: A Multiscale Model to Study the Enhancement in the Compressive Strength of Multi-walled CNT Sheet Overwrapped Carbon Fiber Composites, accepted for publication in Composite Structures (2019)
Acknowledgements
The authors would like to acknowledge the support of this research by the Low Density Materials Program at AFOSR, Grant No. FA9550-14-1-0227 and NSF CMMI-1636306, CMMI-1661246, and CMMI-1726435.
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Wang, X. et al. (2021). The Interfacial Shear Strength of Carbon Nanotube Sheet Modified Carbon Fiber Composites. In: Silberstein, M., Amirkhizi, A. (eds) Challenges in Mechanics of Time Dependent Materials, Volume 2. Conference Proceedings of the Society for Experimental Mechanics Series. Springer, Cham. https://doi.org/10.1007/978-3-030-59542-5_4
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DOI: https://doi.org/10.1007/978-3-030-59542-5_4
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