Abstract
Crystalline and agglomerated spherical alpha zirconium phosphate nanoparticles hereafter α-ZrP were synthesized by a facile and rapid microwave-hydrothermal (MW-HT) approach within 30 min at 120 °C in the absence of any complexing or structure directing agent (SDA). The material was characterized by Fourier-transform infrared (FT-IR), powdered X-ray diffraction (PXRD), scanning electron microscopy (SEM), energy dispersive spectroscopic analysis (EDS) and surface area analysis (BET). It crystallizes in the monoclinic P121/n1 space group with the following cell parameters: a = 5.288, b = 9.174, c = 15.384 Å and β = 102.384. Crystallite sizes in the range 3–4 nm evaluated using Scherer equation were obtained for α-ZrP. Ion exchange performance of α-ZrP towards removal of Cs+ and Sr2+ ions was examined under noncompetitive batch conditions. Distribution studies indicate higher selectivity of α-ZrP towards Sr2+ uptake (Kd ca. 4.3 × 104) in comparison with Cs+ (Kd ca. 2.4 × 103). This study suggested to agglomerated α-ZrP as potential adsorbent for the removal of radioactive Sr2+ from acidic wastewater.
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Abbreviations
- AAS:
-
Atomic absorption spectroscopy
- BET:
-
Surface area analysis
- CP:
-
Co-precipitation
- DFT:
-
Density functional theory
- EDS:
-
Energy dispersive spectroscopic analysis
- FT-IR:
-
Fourier transform infrared
- IEC:
-
Ion exchange capacity
- K d :
-
Distribution coefficient
- MW-HT:
-
Microwave hydrothermal
- PXRD:
-
Powdered X-ray diffraction
- PZC:
-
Point of zero charge
- SDA:
-
Structure directing agents
- SEM:
-
Scanning electron microscopy
- ZrP:
-
Zirconium Phosphate
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Acknowledgements
We thank the Head Department of Chemistry, the University of Kashmir for providing all the necessary facilities to carry out this work. We would also like to thank Mainak Roy and S. N. Achary, Chemistry Division, BARC, Mumbai for their help with PXRD and FT-IR studies. A. B. would like to thank the Council of Scientific and Industrial Research (CSIR), GOI, for financial assistance in the form of a Junior Research Fellowship (JRF). G. N. thanks the DST, GOI, for a research grant for carrying out this work.
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Bashir, A., Malik, L.A., Dar, G.N., Pandith, A.H. (2019). Microwave-Assisted Hydrothermal Synthesis of Agglomerated Spherical Zirconium Phosphate for Removal of Cs+ and Sr2+ Ions from Aqueous System. In: Inamuddin, Ahamed, M., Asiri, A. (eds) Applications of Ion Exchange Materials in the Environment. Springer, Cham. https://doi.org/10.1007/978-3-030-10430-6_5
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