Skip to main content

Methane, Hydrogen and Helium in Hydrothermal Fluids at 21°N on the East Pacific Rise

  • Chapter
Hydrothermal Processes at Seafloor Spreading Centers

Part of the book series: NATO Conference Series ((MARS,volume 12))

Abstract

Methane in 350°C hydrothermal fluids at 21°N on the East Pacific Rise occurs in concentrations greater than 1.1 cc (STP)/kg. Hydrogen concentrations vary from 8 to 38 cc(STP)/kg, showing a considerable range between different vent fields. Helium concentrations exceed 0.021 cc(STP)/kg. The injection rates of methane and hydrogen into the deep ocean indicate replacement times of the order of 30 years, implying that consumption of methane and hydrogen in the water column must be very rapid. Variations of end-member concentrations of methane, hydrogen and possibly helium, as well as δ13C(CH4), among vent fields suggests either chemical control of reactive gas abundances and/or variations in gas contents of ridge crest basalts. Measurements of methane and helium in basalt glass from the EPR show CH4/3He ratios of 2.5 × 106, compared to 3.5 × 106 in hydrothermal fluid from the same area. Carbon isotope evidence, CO2 CH4 isotope geothermometry, the lack of suitable thermocatalytic sources of organic carbon, and the similarity between CH4/3He ratios in these hydrothermal fluids and mid-ocean ridge basalts, point to an abiogenic origin of hydrothermal methane, extracted directly from basalt by circulating seawater.

This is a preview of subscription content, log in via an institution to check access.

Access this chapter

Chapter
USD 29.95
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
eBook
USD 169.00
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
Softcover Book
USD 219.99
Price excludes VAT (USA)
  • Compact, lightweight edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info
Hardcover Book
USD 219.99
Price excludes VAT (USA)
  • Durable hardcover edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info

Tax calculation will be finalised at checkout

Purchases are for personal use only

Institutional subscriptions

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

References

  • Arnasson, B., and Sigurgeirsson, T., 1968, Deuterium content of water vapor and hydrogen in volcanic gas at Surtsey, Iceland, Geochim. Cosmochim. Acta, 32:797.

    Google Scholar 

  • Ballard, R. D., Francheteau, J., Juteau, T., Rangan, C., and Normark, W., 1981, East Pacific Rise at 21°N: the volcanic, tectonic and hydrothermal processes of the central axis, Earth Planet. Sci. Lett., 55: 1.

    Google Scholar 

  • Chaigneau, M., Hekinian, R., and Cheminee, J. L., 1980, Magmatic gases extracted and analyzed from ocean floor volcanics, Bull. Volcanol. 43:241.

    Google Scholar 

  • Chamberlin, R. T., 1908, The gases in rocks, Carnegie Inst. Wash. Publ., 106: 1.

    Google Scholar 

  • Clarke, W. B., Beg, M. A., and Craig, H., 1969, Excess Hé in the sea: evidence for terrestrial primordial helium, Earth Planet. Sci. Lett., 6: 213.

    CAS  Google Scholar 

  • Claypool, G. E., and Kaplan, I. R., 1974, The origin and distribution of methane in marine sediments, in: “Natural Gases in Marine Sediments”, I. R. Kaplan, ed., Plenum Press, New York.

    Google Scholar 

  • Craig, H., 1953, The geochemistry of the stable carbon isotopes, Geochim. Cosmochim. Acta, 3:53.

    Google Scholar 

  • Craig, H., 1963, The isotopic geochemistry of water and carbon in geothermal areas, in: “Proc. Spoleto Conference on Nuclear Geology”, E. Tongiorgi, ed., Spoleto, Italy.

    Google Scholar 

  • Craig, H., 1981, Hydrothermal plumes and tracer circulation along the East Pacific Rise: 20°N to 20°S, Trans. Am. Geophys. Union (EOS) 62:893.

    Google Scholar 

  • Craig, H., Clarke, W. B., and Beg, M. A., 1975, Exces in deep water on the East Pacific Rise, Earth Planet. Sci. Lett., 26: 125.

    CAS  Google Scholar 

  • Craig, H., and Lupton, J. E., 1976, Primordial neon, helium and hydrogen in oceanic basalts, Earth Planet. Sci. Lett., 31: 369.

    CAS  Google Scholar 

  • Craig, H., Welhan, J. A., Kim, K., Poreda, R., and Lupton, J. E., 1980, Geochemical studies of the 21°N EPR hydrothermal fluids, Trans. Am. Geophys. Union (EOS), 61:992.

    Google Scholar 

  • Craig, H., Weiss, R. F., and Clarke, W. B., 1967, Dissolved gases in the equatorial and South Pacific Ocean, J. Geophys. Res., 72: 6165.

    Article  CAS  Google Scholar 

  • DesMarais, D. J., Donchin, J. H., Nehring, N. L., and Truesdell, A. H., 1981, Molecular carbon isotopic evidence for the origin of geothermal hydrocarbons, Nature, 292: 826.

    Article  CAS  Google Scholar 

  • Dubrova, N. V., and Nesmelova, Z. N., 1968, Carbon isotope composition of natural methane, Geochem. Int. 5: 872.

    Google Scholar 

  • East Pacific Rise Study Group, 1981, Crustal processes of the mid-ocean ridge, Science, 213: 31.

    Article  Google Scholar 

  • Edmond, J. M., Measures, C., McDuff, R., Chan, L. H., Collier, R., and Grant, B., 1979, Ridge crest hydrothermal activity and balances of the major and minor elements in the oceans: the Galapagos data, Earth Planet. Sci. Lett., 46: 1.

    CAS  Google Scholar 

  • Gold, T., 1979, Terrestrial sources of carbon and earthquake outgassing, J. Petrol. Geol., 1: 3.

    Article  CAS  Google Scholar 

  • Gunter, B. D., and Musgrave, B. C., 1971, New evidence on the origin of methane in hydrothermal gases, Geochim. Cosmochim. Acta, 35:113.

    Google Scholar 

  • Hekinian, R., Chaigneau, M., and Cheminee, J. L., 1973, Popping rocks and lava tubes from the Mid-Atlantic rift valley at 36°N, Nature, 245: 371.

    Article  CAS  Google Scholar 

  • Hulston, J. R., and McCabe, W. J., 1962, Mass spectrometer measurements in the thermal areas of New Zealand, Part 2. Carbon isotope ratios, Geochim. Cosmochim. Acta, 26:399.

    Google Scholar 

  • Lupton, J. E., and Craig, H., 1975, Excess 3He in oceanic basalts: evidence for terrestrial primordial helium, Earth Planet. Sci. Lett. 26: 133.

    CAS  Google Scholar 

  • Lupton, J. E., Weiss, R. F., and Craig, H., 1977, Mantle helium in hydrothermal plumes in the Galapagos Rift, Nature, 267: 603.

    Article  CAS  Google Scholar 

  • Lupton, J. E., Klinkhammer, G. P., Normark, W. R., Haymon, R., MacDonald, K. C., Weiss, R. F., and Craig, H., 1980, Helium-3 and manganese at the 21°N East Pacific Rise hydrothermal site, Earth Planet. Sci. Lett., 50: 115.

    CAS  Google Scholar 

  • Moore, J. G., Batchelder, J. N., and Cunningham, C. G., 1977, CO2-filled vesicles in mid-ocean basalt, J. Volcanol. Geothermal Res. 2:309.

    Google Scholar 

  • Pineau, F., Javoy, M., and Bottinga, Y., 1976, 13C/ 12C ratios of rocks and inclusions in popping rocks of the Mid-Atlantic Ridge, Earth Planet. Sci. Lett., 29: 413.

    Google Scholar 

  • Richet, P., Bottinga, Y., and Javoy, M., 1977, A review of hydrogen, carbon, nitrogen, oxygen, sulfur, chlorine stable isotope fractionation among gaseous molecules, Ann. Rev. Earth Planet. Sci., 5:65.

    Google Scholar 

  • RISE Project Group, 1980, East Pacific Rise: hot springs and geophysical experiments, Science, 207: 1421.

    Article  Google Scholar 

  • Roedder, E., 1972, The composition of fluid inclusions, U.S. Geol. Survey Prof. Paper 440-JJ.

    Google Scholar 

  • Sackett, W. M., 1978, Carbon and hydrogen isotope effects during thermocatalytic production of hydrocarbons in laboratory simulation experiments, Geochim. Cosmochim. Acta, 42:571.

    Google Scholar 

  • Schoell, M., 1980, The hydrogen and carbon isotopic composition of methane from natural gases of various origins, Geochim. Cosmochim. Acta, 44:649.

    Google Scholar 

  • Seiler, W., and Schmidt, U., 1974, Dissolved nonconservative gases in seawater, in: “The Sea”, Volume 5, E. D. Goldberg, ed., J. Wiley and Sons, New York.

    Google Scholar 

  • Stahl, W. J., 1977, Carbon and nitrogen isotopes in hydrocarbon research and explora-tion, Chem. Geology 20: 121.

    Article  CAS  Google Scholar 

  • Styrt, M. M., Brackmann, A. J., Holland, H. D., Clark, B. C., Pisutha-Arnond, V., Elridge, C. S., and Ohmoto, H., 1981, The mineralogy and the isotope composition of sulfur in hydrothermal sulfide/sulfate deposits on the East Pacific Rise, 21°N latitude, Earth Planet. Sci. Lett., 53: 382.

    CAS  Google Scholar 

  • Weiss, R. F., 1970, The solubility of nitrogen, oxygen and argon in water and seawater, Deep Sea Res., 17: 721.

    CAS  Google Scholar 

  • Weiss, R. F., 1971, Solubility of helium and neon in water and seawater, J. Chem. Eng. Data 16:235.

    Google Scholar 

  • Weiss, R. F., Lonsdale, P., Lupton, J. E., Bainbridge, A. E., and Craig, H., 1977, Hydrothermal plumes in the Galapagos Rift, Nature, 267: 600.

    Article  Google Scholar 

  • Welhan, J. A., 1980, Gas concentrations and isotope ratios at the 21°N EPR hydrothermal site, Trans. Am. Geophys. Union (EOS), 61:996.

    Google Scholar 

  • Welhan, J. A., 1981, Carbon and hydrogen gases in hydrothermal systems: the search for a mantle source, Ph.D. thesis, University of California at San Diego, 195 pp.

    Google Scholar 

  • Welhan, J. A., and Craig, H., 1979, Methane and hydrogen in East Pacific Rise hydrothermal fluids, Geophys. Res. Lett., 6:829.

    Google Scholar 

  • Welhan, J. A., and Craig, H., 1982, Abiogenic methane in mid-ocean ridge hydrothermal fluids, in: “Proc. Deep Source Gas Workshop”, W. J. Gwilliam, ed., Morgantown, West Virginia.

    Google Scholar 

  • Welhan, J. A., Poreda, R., Lupton, J. E., and Craig, H., 1980, Gas chemistry and helium isotopes at Cerro Prieto, Geothermics 8: 241.

    Google Scholar 

  • Williams, P. M., Smith, K. L., Druffel, E. M., and Linick, T. W., 1981, Dietary carbon sources of mussels and tubeworms from Galapagos hydrothermal vents determined from tissue 14C activity, Nature, 292: 448.

    Article  CAS  Google Scholar 

  • Zolotarev, G. I., Voytov, I. S., Sarkisyan, I. S., and Cherevichnaya, L. F., 1981, Doklady Akad. Nauk SSSR, Earth Sci. Sec., 243: 207.

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Editor information

Editors and Affiliations

Rights and permissions

Reprints and permissions

Copyright information

© 1983 Springer Science+Business Media New York

About this chapter

Cite this chapter

Welhan, J.A., Craig, H. (1983). Methane, Hydrogen and Helium in Hydrothermal Fluids at 21°N on the East Pacific Rise. In: Rona, P.A., Boström, K., Laubier, L., Smith, K.L. (eds) Hydrothermal Processes at Seafloor Spreading Centers. NATO Conference Series, vol 12. Springer, Boston, MA. https://doi.org/10.1007/978-1-4899-0402-7_17

Download citation

  • DOI: https://doi.org/10.1007/978-1-4899-0402-7_17

  • Publisher Name: Springer, Boston, MA

  • Print ISBN: 978-1-4899-0404-1

  • Online ISBN: 978-1-4899-0402-7

  • eBook Packages: Springer Book Archive

Publish with us

Policies and ethics