Abstract
The development of laboratory hydration rates is considered to be the most promising approach for the chronometric dating of obsidian artifacts. The technical aspects of accelerated hydration, hydration rim measurement, and the determination of effective hydration temperature and soil relative humidity are reviewed. It is proposed that glass hydration is controlled primarily by the amount of intrinsic water contained within the unhydrated obsidian and that rates of hydration may be estimated once the concentration level is known. The ability of the intrinsic water model to produce age determinations compatible with other chronometric methods is examined with a case example from Xaltocan, Mexico.
Access this chapter
Tax calculation will be finalised at checkout
Purchases are for personal use only
Preview
Unable to display preview. Download preview PDF.
References
Abrajano, T., Bates, J., and Mazer, J. 1989 Aqueous corrosion of natural and nuclear waste glasses; II. Mechanisms of vapor hydration of nuclear waste glasses. Journal of Non-Crystalline Solids 8: 269–288.
Ackerly, N., and R. Giese 1993 Status report at Tortugas Mountains, Dona Ana County, New Mexico. Report to the Office of the President, The New Mexico State University, Las Cruces, NM.
Aiello, P. 1969 The chemical composition of rhyolitic obsidian and its effect on hydration rate: some rchaeological evidence. Masters Thesis, Department of Anthropology, UCLA.
Ambrose, W. 1976 Intrinsic hydration rate dating of obsidian. In: R. E. Taylor, ed., Advances in Obsidian Glass Studies, Park Ridge, New Jersey, Noyes Press: 81–105.
Bartholomew, R., Tick, P, and Stookey, S. 1980 Water/glass reactions at elevated temperatures and pressures. Journal of Non-Crystalline 39: 637–642.
Bates, J., Abrajano, T., Ebert, W., Mazer, J., and Gerding, T. 1988 Experimental hydration studies on natural and synthetic glasses. In: E. Sayre, P. Vandiver, E. Drusick, and C. Stevenson, eds., Materials Issues in Art and Archaeology. Proceedings of the Materials Research Society: 237–244.
Bergland, E., McAlister, J., and Stevenson, C. 1993 An induced hydration rate for Obsidian Cliffs glass. In: P. W. Baxter, ed., Contributions to the Archaeology of Oregon, 1990–1994. Association of Oregon Archaeologists, Occasional Papers No. 5: 1–13.
Cleland, J. 1990 Induced hydration at Coso: Part Ill. Paper presented at the 24th Annual Meeting of the Society for California Archaeology. Foster City, California.
Dean, J. 1978 Independent dating in archaeological analysis. In: Schiffer, M.B. ed., Advances in Archaeological Method and Theory, Volume 1. New York, Academic Press: 223–255.
Dyson, J. 1960 Precise measurement by image-splitting. Journal of the Optical Society of America 50: 754–757.
Ericson, J. 1975 New results in obsidian hydration dating. World Archaeology 7: 151–159.
Ericson, J. 1977 Evaluation of prehistoric exchange systems: results of obsidian dating and tracing. Ph.D. Dissertation, UCLA.
Ericson, J. 1988 Obsidian hydration rate development. In: E. Sayre, P. Vandiver, E. Drusick, and C. Stevenson, eds., Materials Issues in Art and Archaeology. Materials Research Society Proceedings, Volume 123: 215–224.
Ericson, J., Mackenzie, J., and Berger, R. 1976 Physics and chemistry of the hydration process in obsidians, II: experiments and measurements. In: Taylor, R.E., ed., Advances in Obsidian Glass Studies. Park Ridge, New Jersey, Noyes Press: 46–62.
Findlow, E, Bennett, V, Ericson, J., and De Ailey, S. 1975 A new obsidian hydration rate for certain obsidians in the American Southwest. American Antiquity 40: 344–348.
Findlow, E, Martin, P., and Ericson, J. 1982 An examination of the effects of temperature variation on the hydration characteristics of two California obsidians. North American Archaeologist 3: 37–49
Friedman, I. and Long, W 1976 Hydration rate of obsidian. Science 159: 347–352.
Friedman, I. and Smith, R. 1960 A new dating method using obsidian: part 1, the development of the method. American Antiquity 25: 476–493.
Friedman, I., Trembour, F., Smith, E and Smith, G. 1994 Is obsidian hydration dating affected by relative humidity? Quaternary Research 41: 185–190.
Green, J. 1986 Obsidian hydration measurement: are we getting what we expect? Paper presented at the Great Basin Archaeological Conference, Las Vegas, Nevada.
Hench, D., Clark, D., and Yen-Bower, E. 1980 Corrosion of glasses and glass ceramics. Nuclear and Chemical Waste Managment 1: 59–75.
Hurtato de Mendoza, L. and Jester, W.A. 1978 Obsidian sources in Guatemala: a regional approach. American Antiquity 43: 424–435.
Jackson, R. 1984 Current problems in obsidian hydration analysis. In: R. E. Hughes, ed., Obsidian Studies in the Great Basin. Contributions of the University of California Archaeological Research Facility, Berkeley: 103–116.
Johnson, L. 1969 Obsidian hydration rates for the Klamath Basin of California. Science 165: 1354–1356.
Kondo, Y., and S. Matsui 1992 Application of obsidian hydration dating with the Hitachi Model U-6000 microscopic fourier-transform spectrophometer-Dating of stone implements using a new non-destructive technique. Hitachi Scientific Instrument News 35: 11–14.
Labs, K. and Harrington, K. 1982 A comparison of ground and above-ground climates for identifying appropriate cooling strategies. Passive Solar Journal 1: 4–11.
Leach, B.F., and Hamel, G.E. 1984 The influence of archaeological soil temperatures on obsidian dating in New Zealand. New Zealand Journal of Science 27: 399–408.
Lee, R. 1969 Chemical temperature integration. Journal of Applied Meteorology 8: 423–430.
Mazer, J., Stevenson, C., Ebert, W., and Bates, J. 1991 The experimental hydration of obsidian as a function of relative humidity and temperature. American Antiquity 56: 504–513.
Mazer, J., Bates, J., Stevenson, C., Bradley, C. 1992 Obsidians and tektites: natural analogues for water diffusion in nuclear waste glass. Materials Research Society Symposium Proceedings. 257: 513–520.
Meighan, C. 1983 Obsidian dating in California: theory and practice. American Antiquity 48: 600–609.
Michels, J., and Tsong, I.S.T. 1980 Obsidian hydration dating: a coming of age. In: M.B. Schiffer, ed., Advances in Archaeological Method and Theory, Volume 3. New York, Academic Press: 405–439.
Michels, J., Tsong, I.S.T., and Smith, G. 1983 Experimentally derived hydration rates in obsidian dating. Archaeometry 25: 107–117.
Nelson, E. 1984 X-ray fluorescence analysis of some western North American obsidians. In: Hughes, R.E., ed., Obsidian Studies in the Great Basin. Contributions of the University of California Archaeological Research Facility, University of California, Berkeley: 27–62.
Newman, S., Stolper, E., and Epstein, S. 1986 Measurement of water in rhyolitic glasses: calibration of an infrared spectroscopic technique. American Mineralogist 71: 1527–1541.
Redfield, A.C. 1965 Terrestrial heat flow through salt-marsh peat. Science 148: 1219–1220.
Riddings, R. 1991 Obsidian hydration dating: the effects of mean exponential ground temperature and depth of artifact recovery. Journal of Field Archaeology 18: 77–85.
Scheetz, B., and Stevenson, C. 1988 The r ole of resolution and sample preparation in hydration rim meas urement; implications for experimentally determined hydration rates. American Antiquity 53: 110–117.
Silver, L., Ihinger, P., and Stolper, E. 1990 The influence of bulk composition on the speciation of water in silicate glasses. Contributions to Mineralogy and Petrology 104: 142–162.
Smith, T. 1977 Obsidian hydration as an independent dating technique. Masters Thesis, Department of Anthropology, University of Alaska: Fairbanks, Alaska.
Stevenson, C., Freeborn, W, and Scheetz, B. 1987 Obsidian hydration dating: an improved optical technique for measuring the width of the hydration rim. Archaeometry 29: 120–123.
Stevenson, C., and Scheetz, B. 1989 Induced hydration rate development of obsidians from the Coso volcanic field: a comparison of experimental procedures. In: Hughes, R.E., ed., Current Directions in California Obsidian Studies, No. 48. Contributions of the University of California Archaeological Research Facility, Berkeley: 23–30.
Stevenson, C., Carpenter, J., and Scheetz, B. 1989a Recent advances in the experimental determination and application of obsidian hydration rates. Archaeometry 31: 193–206
Stevenson, C., Dinsmore, D., and Scheetz, B. 1989b An inter-laboratory comparison of hydration rim measurements. International Association for Obsidian Studies Newsletter 1.
Stevenson, C., Knaus, E., Mazer, J., and Bates, J. 1993a Homogeneity of water content in obsidian from the Coso volcanic field: Implications for obsidian hydration dating. Geoarchaeology 8: 371–384.
Stevenson, C., Friedman, I., and Miles, J. 1993b The importance of soil temperature and relative humidity in obsidian dating, with case examples from Easter Island. In: Fischer, S.R. ed., Easter Island Studies: Contributions in Memory of William T Mulloy. Oxbow Monograph 32, Oxford: 96–102.
Tremaine, K., and Frederickson, D. 1988 Induced obsidian hydration experiments: an investigation in relative dating. In: Sayre, E., Vandiver, P., Drusick, E., and Stevenson, C. eds., Materials Issues in Art and Archaeology. Proceedings of the Materials Research Society. Volume 123: 271–278.
Trembour, F., Smith, F., and Friedman, I. 1988 Diffusion cells for integrating temperature and humidity over long periods of time. In: Sayre, E., Vandiver, P, Drusick, E., and Stevenson, C., eds., Materials Issues in Art and Archaeology. Proceedings of the Materials Research Society. Volume 123: 245–252.
Van Wilk, W, and Derksen, W. 1966 Sinusoidal soil temperature variation in a layered soil. In: W. Van Wilk, ed, Physics of the Plant Environment, Amsterdam, North Holland Publishing Co.
White, W.B. 1986 Dissolution mechanisms of nuclear waste glass: a review. Advances in Ceramics, Vol. 20: Nuclear Waste Managment 11: 431–442.
White, W.B. 1988 Glass hydration mechanisms with application to obsidian hydration dating. In: Sayre, E., Vandiver, P., Drusick, E., and Stevenson, C., eds., Material Issues in Art and Archaeology. Materials Research Society Symposium Proceedings. Volume 123: 225–236.
Young, J.F. 1967 Humidity control in the laboratory using salt solutions-a review. American Laboratory 17: 241–245.
Author information
Authors and Affiliations
Editor information
Editors and Affiliations
Rights and permissions
Copyright information
© 1998 Springer Science+Business Media New York
About this chapter
Cite this chapter
Stevenson, C.M., Mazer, J.J., Scheetz, B.E. (1998). Laboratory Obsidian Hydration Rates. In: Shackley, M.S. (eds) Archaeological Obsidian Studies. Advances in Archaeological and Museum Science, vol 3. Springer, Boston, MA. https://doi.org/10.1007/978-1-4757-9276-8_8
Download citation
DOI: https://doi.org/10.1007/978-1-4757-9276-8_8
Publisher Name: Springer, Boston, MA
Print ISBN: 978-1-4757-9278-2
Online ISBN: 978-1-4757-9276-8
eBook Packages: Springer Book Archive