Skip to main content

Dolomite Crystal Size Distribution

  • Chapter
Carbonate Microfabrics

Part of the book series: Frontiers in Sedimentary Geology ((SEDIMENTARY))

Summary

Crystal size distributions (CSD) in dolomites carry information concerning nucleation and growth. CSDs of Recent to Cambrian age dolomites were determined by point counting crystals in thin section and scanning electron photomicrographs. Mean crystal sizes range from approximately 0.4 μm for Recent dolomites from Belize, to 70 μm for the Saluda Formation (Ordovician), Ohio, to 500 μm for epigenetic dolomites from the Trenton Limestone (Ordovician), Michigan, and Bonneterre Dolomite (Cambrian), Missouri. The CSDs of the Belize dolomites and nonplanar Bonneterre dolomites closely fit a log-normal distribution. All samples are unimodal and normal to coarsely skewed. In some cases, the variation in skewness among samples from the same location is as large as the variation between samples from different locations.

Large variations of mean size and skewness occur between clasts in a dolomitized conglomerate from the Trenton Limestone. This indicates that the substrate has a large effect on the CSD. There is no simple nucleation and growth law that explains the CSD of most of the ancient dolomites studied. However, a qualitative model of continuous nucleation and flux-limited growth is consistent with the data. In flux-limited growth, crystals near macropores grow faster, and therefore larger, than crystals surrounded by micropores where solute transport occurs by diffusion. The log-normal CSDs of Recent dolomites from Belize and ancient nonplanar dolomites from the Bonneterre are consistent with surface energy driven recrystallization (Ostwald ripening).

This is a preview of subscription content, log in via an institution to check access.

Access this chapter

eBook
USD 16.99
Price excludes VAT (USA)
  • Available as EPUB and PDF
  • Read on any device
  • Instant download
  • Own it forever

Tax calculation will be finalised at checkout

Purchases are for personal use only

Institutional subscriptions

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

Similar content being viewed by others

References

  • Baker, P. and S. Burns, 1985. Occurrence and formation of dolomite in organic-rich continental margin sediments. American Association of Petroleum Geologists, v. 69, p. 1917–1930.

    Google Scholar 

  • Barronet, A., 1982. Ostwald ripening in solution. The case of calcite and mica. In: Rodrigues Clemente, R. and I. Sunagawa (eds.), Crystal Growth Processes in Sedimentary Environments, v. 38, p. 185–198.

    Google Scholar 

  • Bathurst, R.G., 1975. Carbonate Sediments and Their Diagenesis. Elsevier, Amsterdam, 658 p.

    Google Scholar 

  • Bauer, R.M., K.L. Shelton, and J.M. Gregg, 1989. Fluid inclusion studies of regionally extensive epigenetic dolomites, Bonneterre Dolomite, S. E. Missouri: Evidence for multiple fluids during Pb-Zn ore mineralization. Abstract, Geological Society of America Annual Meetings, v. 21, p. A3.

    Google Scholar 

  • Blatt, H., G. Middleton, and R. Murray, 1980. Origin of Sedimentary Rocks. Prentice-Hall Englewood Cliffs, New Jersey, 782 p.

    Google Scholar 

  • Carlson, W.D., 1989. The significance of intergranular diffusion to the mechanisms and kinetics of porphyroblast crystallization. Contributions to Mineralogy Petrology, v. 103, p. 1–24.

    Article  Google Scholar 

  • Cashman, K.V. and B.D. Marsh, 1988. Crystal size distribution (CSD) in rocks and the kinetics and dynamics of crystallization II-Makaopuhi lava lake. Contributions to Mineralogy Petrology, v. 99, p. 292–305.

    Article  Google Scholar 

  • Chayes, E, 1950. On the bias of grain-size measurements made in thin-section. Journal of Geology, v. 58, p. 156–160.

    Article  Google Scholar 

  • Colbeck, S.C., 1987. Theory of particle coarsening with lognormal distribution. Acta Metallurgica, v. 35, p. 1583–1588.

    Article  Google Scholar 

  • Compton, J.S., 1986. Degree of supersaturation and precipitation of organogenic dolomite. Geology, v. 16, p. 318–321.

    Article  Google Scholar 

  • DeHoff, R.T. and F.N. Rines, 1968. Quantitative Microscopy. McGraw-Hill, New York, 422 p.

    Google Scholar 

  • Dunham, R.J., 1960. Classification of carbonate rocks according to depositional texture. In: Ham, W.E. (ed.), Classification of Carbonate rocks. American Association of Petroleum Geologists, p. 108–121.

    Google Scholar 

  • Ebanks, W.J., 1975. Holocene carbonate sedimentation and diagenesis, Ambergris Cay, Belize. In: Wantland, K.F. and W.C. Pusey (eds.), Belize Shelf-Carbonate Sediments, Clastic Sediments, and Ecology. American Association of Petroleum Geologists, Studies in Geology, No. 2, p. 234–296.

    Google Scholar 

  • Eberl, D.D., J. Srodon, M. Kralik, B.E. Taylor, and Z.E. Peterman, 1990. Ostwald ripening of clays and metamorphic minerals. Science, v. 248, p. 474–477.

    Article  Google Scholar 

  • Folk, R.L., 1959. Practical petrographic classification of limestones. Bulletin of the American Association of Petroleum Geologists, v. 43, p. 1–38.

    Google Scholar 

  • Friedman, G.M., 1965. Terminology of crystallization textures and fabrics in sedimentary rocks. Journal of Sedimentary Petrology, v. 35, p. 643–655.

    Google Scholar 

  • Gerdemann, P.E. and H.E. Myers, 1972. Relationships of carbonate facies patterns to ore distribution and ore genesis in the southeast Missouri lead district. Economic Geology, v. 67, p. 426–433.

    Article  Google Scholar 

  • Gregg, J.M., 1985. Regional epigenetic dolomitization in the Bonneterre dolomite (Cambrian), southeastern Missouri. Geology, v. 13, p. 503–506.

    Article  Google Scholar 

  • Gregg, J.M., 1988. Origins of dolomite in the offshore facies of the Bonneterre Formation (Cambrian), Missouri. In: Shukla, V. and P.A. Baker (eds.), Sedimentology and Geochemistry of Dolostones. Society of Economic Paleontologists and Mineralogists Special Publication, v. 43, p. 67–83.

    Google Scholar 

  • Gregg, J.M. and P.E. Gerdemann, 1989. Sedimentary facies, diagenesis, and ore distribution in the Bonneterre Formation (Cambrian) southeast Missouri. In: Gregg. J.M., J.M. Palmer, and V.E. Kurtz (eds.), Field Guide to the Upper Cambrian of Southeastern Missouri: Stratigraphy, Sedimentology and Economic Geology. University of Missouri-Rolla, p. 43–55.

    Google Scholar 

  • Gregg, J.M. and D.F. Sibley, 1984. Epigenetic dolomitization and the origin of xenotopic dolomite texture. Journal of Sedimentary Petrology, v. 54, p. 908–931.

    Google Scholar 

  • Gregg, J.M. and S. Howard, 1990. Crystallographic and mineralogic studies of Recent, peritidal dolomites, Ambergris Cay, Belize. Abstract, Geological Society of America Annual Meetings, v. 22, p. 179.

    Google Scholar 

  • Gregg, J.M. and K.L. Shelton, 1990. Dolomitization and dolomite neomorphism in the back reef facies of the Bonneterre and Davis formations (Cambrian), southeastern Missouri. Journal of Sedimentary Petrology, v. 60, p. 539–562.

    Google Scholar 

  • Griffiths, J.C., 1967. Scientific Method in Analysis of Sediments. McGraw-Hill, New York, 508 p.

    Google Scholar 

  • Haefner, R.J., J.J. Mancusco, J.P. Frizado, K.L. Shelton, and J.M. Gregg, 1988. Crystallization temperatures and stable isotope compositions of Mississippi Valley-type carbonate and sulfides of the Trenton Limestone, Wyandot County, Ohio. Economic Geology, v. 83, p. 1061–1069.

    Article  Google Scholar 

  • Hatfield, C.B., 1968. Stratigraphy and paleoecology of the Saluda Formation (Cincinnatian) in Indiana, Ohio, and Kentucky. Geological Society of America, Special Paper 95, 34 p.

    Google Scholar 

  • Keith, B., 1985. Facies, diagenesis and the upper contact of the Trenton Limestone of northern Indiana. In: Cercone, K.R. and J.M. Budai (eds.), Ordovician and Silurian Rocks of the Michigan Basin. Michigan Basin Geological Society, Special Publication No. 4, p. 15–32.

    Google Scholar 

  • Kretz, R., 1974. Some models for the rate of crystallization of garnet in metamorphic rocks. Lithos, v. 7, p. 123–131.

    Article  Google Scholar 

  • Krumbein, 1934. Size frequency distribution of sediments. Journal of Sedimentary Petrology, v. 4, p. 65–77.

    Google Scholar 

  • Larson, K.G., 1977. Sedimentology of the Bonneterre Formation, southeast Missouri. Economic Geology, v. 72, p. 408–419.

    Article  Google Scholar 

  • Lyle, J.R., 1977. Petrology and carbonate diagenesis of the Bonneterre Formation in the Viburnum Trend area, southeast Missouri. Economic Geology, v. 72, p. 420–434.

    Article  Google Scholar 

  • Mahin, KW, K. Hanson, and J.W. Morris, Jr., 1980. Comparative analysis of the cellular and Johnson-Mehl microstructures through computer simulation. Acta Metallurgica, v. 24, p. 443–453.

    Article  Google Scholar 

  • Mazzullo, S.J. and A.M. Reid, 1988. Sedimentary structures of recent Belizean pertidal dolomite. Journal of Sedimentary Petrology, v. 58, p. 479–488.

    Google Scholar 

  • Mazzullo, S.J., A.M. Reid, and J.M. Gregg, 1987. Dolomitization of Holocene Mg-calcite supratidal deposits, Ambergris Cay, Belize. Geological Society of America Bulletin, v. 98, p. 224–231.

    Article  Google Scholar 

  • Miller, M.M., 1988. Dolomitization and Porosity Evolution. Ph.D. Dissertation, Michigan State University, East Lansing, MI, 168 p.

    Google Scholar 

  • Nordeng, S. and D.F. Sibley, D.F. 1990. Diffusion limited growth of dolomite, Saluda Fm. (Ordovician, IN). Abstract, Geological Society of America Annual Meetings, v. 22, p. A178.

    Google Scholar 

  • Pettijohn, F.J., P.E. Potter, and R. Siever, 1972. Sand and Sandstone. Springer-Verlag, New York, 618 p.

    Google Scholar 

  • Pingitore, N.E., Jr., 1982. The role of diffusion during carbonate diagenesis. Journal of Sedimentary Petrology, v. 52, p. 27–40.

    Google Scholar 

  • Saetre, T.O., O. Hunderi, and E. Nes, 1986. Computer simulation of primary recrystallization microstructures: the effects of nucleation and growth kinetics. Acta Metallurgica, v. 24, p. 981–987.

    Article  Google Scholar 

  • Sibley, D.F., 1990. Unstable to stable transformations during dolomitization. Journal of Geology, v. 98, p. 739–748.

    Article  Google Scholar 

  • Sibley, D.F. and J.M. Gregg, 1987. Classification of dolomite rock textures. Journal of Sedimentary Petrology, v. 57, p. 967–975.

    Google Scholar 

  • Taylor, T.R. and D.F. Sibley, 1986. Petrographic and geochemical characteristics of dolomite types and the origin of ferroan dolomite in the Trenton Formation, Ordovician, Michigan Basin, USA. Sedimentology, v. 33, p. 61–86.

    Article  Google Scholar 

  • Underwood, E.E., 1970. Quantitative Stereology. Addison-Wesley, Masschusetts, 274 p.

    Google Scholar 

  • Wilson, J.L. and A. Sengupta, 1985. The Trenton Formation in the Michigan basin and environs: pertinent questions about its stratigraphy and diagenesis. In: Cercone, K.R. and J.M. Budai (eds.), Ordovician and Silurian Rocks of the Michigan Basin. Michigan Basin Geological Society, Special Publication No. 4, p. 1–13.

    Google Scholar 

Download references

Authors

Editor information

Editors and Affiliations

Rights and permissions

Reprints and permissions

Copyright information

© 1993 Springer-Verlag New York, Inc.

About this chapter

Cite this chapter

Sibley, D.F., Gregg, J.M., Brown, R.G., Laudon, P.R. (1993). Dolomite Crystal Size Distribution. In: Rezak, R., Lavoie, D.L. (eds) Carbonate Microfabrics. Frontiers in Sedimentary Geology. Springer, New York, NY. https://doi.org/10.1007/978-1-4684-9421-1_15

Download citation

  • DOI: https://doi.org/10.1007/978-1-4684-9421-1_15

  • Publisher Name: Springer, New York, NY

  • Print ISBN: 978-1-4684-9423-5

  • Online ISBN: 978-1-4684-9421-1

  • eBook Packages: Springer Book Archive

Publish with us

Policies and ethics