Summary
Complex formation of silica, silicic acids and silicates with organic compounds has been investigated with emphasis on six-coordinated silicon. 1,2-Dihydroxyaryl compounds are powerful chelating agents for silicon, forming anionic complexes. Even quartz can he reacted directly to these compounds. Cationic chelate complexes are formed with 1,3-diketones, 2-hydroxypyridine-N-oxide and tropolones. A β-isopropyltropolone-silicon-complex (=β-thujaplicine-complex) ((thpl)3Si)+ has been isolated from Thuja plicata. The natural complex has been compared with the synthetic compounds
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Weiss, A., Herzog, A. (1978). Isolation and Characterization of a Silicon-Organic Complex from Plants. In: Bendz, G., Lindqvist, I., Runnström-Reio, V. (eds) Biochemistry of Silicon and Related Problems. Nobel Foundation Symposia, vol 40. Springer, Boston, MA. https://doi.org/10.1007/978-1-4613-4018-8_5
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DOI: https://doi.org/10.1007/978-1-4613-4018-8_5
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