Abstract
Selective oxidations of organic substrates catalyzed by transition metal complexes capable of activating oxygen have been of interest since Glaser observed1 more than a hundred years ago that phenylacetylene underwent smooth aerial oxidation to diphenylacetylene when cuprous chloride in ammonia was used as a catalyst. This reaction has since been applied to a wide variety of organic compounds possessing the ethynyl grouping. The Glaser cop-per-amine system has been used in various modifications for many years up to the 1950s when two independant groups found a breakthrough in the oxidation of phenols using a copper-amine complex as a catalyst.2
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de Jonge, C.R.H.I. (1986). Oxidations of Organic Compounds Catalyzed by Copper- and Cobalt-Amine Complexes. In: Mijs, W.J., de Jonge, C.R.H.I. (eds) Organic Syntheses by Oxidation with Metal Compounds. Springer, Boston, MA. https://doi.org/10.1007/978-1-4613-2109-5_7
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DOI: https://doi.org/10.1007/978-1-4613-2109-5_7
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