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Second-Order Nonlinear Optical Materials Based on Metal Iodates, Selenites, and Tellurites

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Structure-Property Relationships in Non-Linear Optical Crystals I

Part of the book series: Structure and Bonding ((STRUCTURE,volume 144))

Abstract

In this chapter, the syntheses, structures, and Second Harmonic Generation (SHG) properties of metal iodates, selenites, and tellurites all of which contain a lone pair cation in an asymmetric coordination geometry were reviewed. A second asymmetric building unit such as distorted octahedra of the d0 transition-metal (TM) cations such as V5+, Mo6+, other cations with a stereochemically active lone pair such as Pb2+ and Bi3+, and tetrahedral groups such as BO 5−4 and PO 3−4 , can be introduced into metal iodates, selenites, and tellurites. The combination of d0 transition-metal cations with the iodate groups afforded a large number of new metal iodates, a number of which display excellent SHG properties due to the additive effects of polarizations from both types of the asymmetric units. Introducing other lone-pair cations such as Pb2+ and Bi3+ into the metal iodates is also an effective strategy to design new SHG materials. With respect to the metal selenite or tellurite systems, many compounds in the alkali or alkaline earth-d0 TM–Se(IV)/Te(IV)–O systems can also exhibit excellent SHG properties due to the additive effects of polarizations from both types of asymmetric units. Lanthanide or posttransition metal main group element-d0 TM–Se(IV)/Te(IV)–O compounds are usually structurally centrosymmetric and not SHG active, but they can also display abundant structural diversities and interesting magnetic or luminescent properties. Metal tellurites and selenites containing tetrahedral groups of the main group elements such as BO4 and PO4 may also form NCS structures with excellent SHG properties.

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Acknowledgments

This work was supported by the National Natural Science Foundation of China (Grants Nos. 20731006, 20825104, 21001107, and 20821061), NSF of Fujian Province (Grant 2011J05037) and Key Laboratory of Optoelectronic Materials Chemistry and Physics, Chinese Academy of Sciences (Grant No 2008DP173016).

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  1. State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, 350002, People’s Republic of China

    Fang Kong, Chuan-Fu Sun, Bing-Ping Yang & Jiang-Gao Mao

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  1. Fang Kong
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Correspondence to Jiang-Gao Mao .

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  1. , Fujian Institute of Research, Chinese Academy of Sciences, Fuzhou, Fujian, 350002, China, People's Republic

    Xin-Tao Wu

  2. , Fujian Institute of Research, Chinese Academy of Sciences, Fuzhou, Fujian, 350002, China, People's Republic

    Ling Chen

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Kong, F., Sun, CF., Yang, BP., Mao, JG. (2012). Second-Order Nonlinear Optical Materials Based on Metal Iodates, Selenites, and Tellurites. In: Wu, XT., Chen, L. (eds) Structure-Property Relationships in Non-Linear Optical Crystals I. Structure and Bonding, vol 144. Springer, Berlin, Heidelberg. https://doi.org/10.1007/430_2011_65

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