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Applications of 1,1-Diphenylethylene Chemistry in Anionic Synthesis of Polymers with Controlled Structures

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Biopolymers · PVA Hydrogels, Anionic Polymerisation Nanocomposites

Part of the book series: Advances in Polymer Science ((POLYMER,volume 153))

Abstract

The use of 1,1-diphenylethylenes in anionic polymerization is reviewed. The structure and reactivity of 1,1-diphenylethylenes and the corresponding simple and polymeric 1,1-diphenylalkyllithiums are described. The applications of 1,1-diphenylethylene chemistry include:

  1. 1.

    Their use to form initiators

  2. 2.

    End-capping agents to attenuate reactivity for crossover to reactive, polar monomers or for functionalization reactions

  3. 3.

    For chain-end and in-chain functionalization using substituted 1,1-diphenylethylenes and 1,1-diarylethylenes

  4. 4.

    The preparation and applications of non-homopolymerizable 1,1-diphenylethylene-functionalized macromonomers

  5. 5.

    The use of bis(1,1-diphenylethylenes) and tris(1,1-diphenylethylenes) as precursors for hydrocarbon-soluble dilithium and trilithium initiators, respectively

  6. 6.

    The use of bis(1,1-diphenylethylenes) and tris(1,1-diphenylethylenes) as living linking agents to prepare heteroarm (miktoarm) star-branched polymers

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Authors and Affiliations

  1. Maurice Morton Institute of Polymer Science, The University of Akron, Akron, Ohio, 44325-3909, USA

    Roderic P. Quirk, Taejun Yoo & Youngjoon Lee

  2. Division of Polymers, Korea Institute of Science and Technology, P. O. Box Cheongryang 131, Seoul, Korea

    Jungahn Kim

  3. Department of Fine Chemicals Engineering and Chemistry, Chungnam National University, Taejon, 305-764, Korea

    Bumjae Lee

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  1. Roderic P. Quirk
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Quirk, R.P., Yoo, T., Lee, Y., Kim, J., Lee, B. (2000). Applications of 1,1-Diphenylethylene Chemistry in Anionic Synthesis of Polymers with Controlled Structures. In: Biopolymers · PVA Hydrogels, Anionic Polymerisation Nanocomposites. Advances in Polymer Science, vol 153. Springer, Berlin, Heidelberg. https://doi.org/10.1007/3-540-46414-X_3

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  • DOI: https://doi.org/10.1007/3-540-46414-X_3

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